5-BROMO-2-METHYL-PYRIMIDINE

Product Name: 5-BROMO-2-METHYL-PYRIMIDINE
CAS No.: 7752-78-5
Chemical Name: 5-BROMO-2-METHYL-PYRIMIDINE
Synonyms: 5-BROMO-2-METHYL-PYRIMIDINE;5-bromo-2-methyl-pyrimidi...;5-Bromo-2-methyl-1,3-diazine;PyriMidine, 5-broMo-2-Methyl-;2-methyl-5-bromo-1,3-pyrimidine;5-BROMO-2-METHYL-PYRIMIDINE ISO 9001：2015 REACH
CBNumber: CB3818370
Molecular Formula: C5H5BrN2
Formula Weight: 173.01
MOL File: 7752-78-5.mol

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5-BROMO-2-METHYL-PYRIMIDINE Property

Melting point:: 80.0 to 85.0 °C
Boiling point:: 195.2±13.0 °C(Predicted)
Density: 1.596±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
solubility: soluble in Methanol
pka: 0.46±0.22(Predicted)
form: Solid
color: Light yellow to Brown
λmax: 266nm(EtOH)(lit.)
InChI: InChI=1S/C5H5BrN2/c1-4-7-2-5(6)3-8-4/h2-3H,1H3
InChIKey: NEDJTEXNSTUKHW-UHFFFAOYSA-N
SMILES: C1(C)=NC=C(Br)C=N1

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Safety

Hazard Codes: Xi
HS Code: 2933599590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B5266
Product name: 5-Bromo-2-methylpyrimidine
Purity: >98.0%(GC)
Packaging: 1g
Price: $42
Updated: 2025/07/31

TCI Chemical

Product number: B5266
Product name: 5-Bromo-2-methylpyrimidine
Purity: >98.0%(GC)
Packaging: 5g
Price: $137
Updated: 2025/07/31

TRC

Product number: B685595
Product name: 5-Bromo-2-methylpyrimidine
Packaging: 2.5g
Price: $1320
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0030234
Product name: 5-BROMO-2-METHYLPYRIMIDINE
Purity: 95.00%
Packaging: 2.5G
Price: $2035
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0030234
Product name: 5-BROMO-2-METHYLPYRIMIDINE
Purity: 95.00%
Packaging: 250MG
Price: $750.75
Updated: 2021/12/16

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5-BROMO-2-METHYL-PYRIMIDINE Chemical Properties,Usage,Production

Uses

5-BROMO-2-METHYL-PYRIMIDINE is a disubstituted pyrimidine derivative with strong insecticidal effects on house flies.

Synthesis

100707-39-9

7752-78-5

General procedure for the synthesis of 5-bromo-2-methylpyrimidine from 2-methyl-5-bromopyrimidine-4-carboxylic acid: 5-bromo-2-methylpyrimidine-4-carboxylic acid (350 mg, 1.6 mmol) was dissolved in xylene (5 mL), and the reaction was carried out at reflux for 2 hours. After the reaction was completed, the reaction mixture was cooled to room temperature and directly sampled onto a silica gel column. Gradient elution with petroleum ether and petroleum ether solution containing 5% (v/v) ethyl acetate was carried out sequentially, and the target fraction was collected to give 5-bromo-2-methylpyrimidine (170 mg, 61% yield) as a white solid.LC-MS (m/z): 173 [M + H]+. 1H NMR (400 MHz, DMSO-d6) δ: 2.59 (s, 3H), 8.87 ( s, 2H).

References

[1] Patent: WO2011/130628, 2011, A1. Location in patent: Page/Page column 176
[2] Patent: US2013/102595, 2013, A1. Location in patent: Paragraph 0366
[3] Patent: JP2015/187145, 2015, A. Location in patent: Paragraph 0320
[4] Patent: WO2014/131855, 2014, A1. Location in patent: Page/Page column 56
[5] Collection of Czechoslovak Chemical Communications, 1949, vol. 14, p. 223,228

5-BROMO-2-METHYL-PYRIMIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-METHYL-PYRIMIDINE Suppliers

Americas 1 Canada 2 China 221 Europe 1 Germany 2 India 14 Japan 1 United Kingdom 7 United States 25 Global 274

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
Advantage: 75

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View Lastest Price from 5-BROMO-2-METHYL-PYRIMIDINE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 5-BROMO-2-METHYL-PYRIMIDINE 7752-78-5
Price: US $10.00/KG
Min. Order: 100KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-26

Hebei Chuanghai Biotechnology Co,.LTD

Product: 5-Bromo-2-methylpyrimidine 7752-78-5
Price: US $10.70/KG
Min. Order: 10KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-20

R&D Scientific Inc.

Product: 2-Methyl-5-bromopyrimidine 7752-78-5
Price: US $1590.00/Kg
Min. Order: 1Kg
Purity: 98
Supply Ability: 500 Kg
Release date: 2024-09-01

7752-78-5, 5-BROMO-2-METHYL-PYRIMIDINERelated Search:

5-BROMOPYRIMIDINE-2-CARBOXYLIC ACID (5-Bromopyrimidin-2-yl)acetic acid ethyl ester ETHYL 2-(5-BROMOPYRIMIDIN-2-YL)-2-CYANOACETATE 5-Bromopyrimidine-2-carbonitrile 5-BROMO-2-METHYL-PYRIMIDINE 5-bromo-2-(trifluoromethyl)pyrimidine 5-Bromo-2-methyl-4-pyrimidinecarboxylic acid 5-bromo-2-phenylpyrimidin-4-ol 2-(5-BROMOPYRIMIDIN-2-YL)MALONIC ACID DIETHYL ESTER 2-tert-Butyl-5-bromopyrimidine 5-BROMO-2-METHYL-4(1H)-PYRIMIDINONE 5-BROMO-4-CHLORO-2-PHENYLPYRIMIDINE 5-BROMO-2-METHYL-PYRIMIDIN-4-YLAMINE 5-BROMO-4-HYDRAZINO-2,6-DIPHENYLPYRIMIDINE 5-BROMO-2,4-DITERT-BUTYL-6-HYDRAZINOPYRIMIDINE 4,5-DIBROMO-2,6-DIPHENYLPYRIMIDINE 5-BROMO-4,6-DICHLORO-2-METHYLPYRIMIIDNE

5-bromo-2-methyl-pyrimidi...

5-BROMO-2-METHYL-PYRIMIDINE

PyriMidine, 5-broMo-2-Methyl-

5-Bromo-2-methyl-1,3-diazine

2-methyl-5-bromo-1,3-pyrimidine

5-BROMO-2-METHYL-PYRIMIDINE ISO 9001：2015 REACH

7752-78-5

Aromatics

Heterocycles

Pyridines, Pyrimidines, Purines and Pteredines

Heterocycle-Pyrimidine series

Intermediates & Fine Chemicals

Pharmaceuticals