ChemicalBook > CAS DataBase List > (3-acrylamidophenyl)boronic acid
(3-acrylamidophenyl)boronic acid
- Product Name
- (3-acrylamidophenyl)boronic acid
- CAS No.
- 99349-68-5
- Chemical Name
- (3-acrylamidophenyl)boronic acid
- Synonyms
- (m-AcryL;amidophenyL;3-(Propenamido);Boronic acid acrylamide;Phenylboronate acrylamide;(3-Acrylamidophenyl)boronicaci;3-Acrylamidobenzeneboronic Acid;(M-ACRYLAMIDOPHENYL)BORONIC ACID;3-(Propenamido)phenylboronic acid;3-(AcrylaMido)phenylboronic acid 98%
- CBNumber
- CB3837283
- Molecular Formula
- C9H10BNO3
- Formula Weight
- 190.99
- MOL File
- 99349-68-5.mol
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(3-acrylamidophenyl)boronic acid Property
- Melting point:
- 129-146°C
- Density
- 1.22±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 8.05±0.10(Predicted)
- form
- powder to crystal
- color
- White to Amber
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 771465
- Product name
- 3-(Acrylamido)phenylboronic acid
- Purity
- 98%
- Packaging
- 1g
- Price
- $151
- Updated
- 2025/07/31
TCI Chemical
- Product number
- A3199
- Product name
- 3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $128
- Updated
- 2025/07/31
TCI Chemical
- Product number
- A3199
- Product name
- 3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $379
- Updated
- 2025/07/31
TRC
- Product number
- A191315
- Product name
- 3-(Acrylamido)phenylboronic acid
- Packaging
- 500mg
- Price
- $100
- Updated
- 2021/12/16
TRC
- Product number
- A191315
- Product name
- 3-(Acrylamido)phenylboronic acid
- Packaging
- 2.5g
- Price
- $330
- Updated
- 2021/12/16
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(3-acrylamidophenyl)boronic acid Chemical Properties,Usage,Production
Uses
suzuki reaction
Uses
This acrylamide monomer contains a glucose sensitive boronic acid commonly used for intelligent polymers solutions and gels;for drug delivery systems;sensors;actuator systems;and bioreactors.
Synthesis
30418-59-8
814-68-6
99349-68-5
General procedure for the synthesis of 3-acrylamidophenylboronic acid from 3-aminophenylboronic acid and acryloyl chloride: 3-aminophenylboronic acid (0.566 g, 3.65 mmol) and Na2CO3 (0.67 g, 80.3 mmol) were added to 20 mL of a 1:1 (v/v) solvent mixture of tetrahydrofuran and water and the mixture was cooled to 0 °C. Acryloyl chloride (960 mg, 8.06 mmol) was slowly added dropwise under stirring conditions. After the dropwise addition, the mixture was allowed to warm up naturally to room temperature and stirring was continued for 2 hours. Upon completion of the reaction, 10 mL of water was added to terminate the reaction, followed by extraction of the reaction mixture with ethyl acetate (20 mL x 3). The organic phases were combined, washed with saturated NaCl solution (10 mL) and finally the organic layer was dried with anhydrous Na2SO4. After concentrating the organic layer, it was purified by column chromatography to give the light yellow solid product 3-acrylamidophenylboronic acid (0.32 g, 40.1% yield).
References
[1] Journal of Medicinal Chemistry, 2017, vol. 60, # 11, p. 4636 - 4656
[2] Soft Matter, 2014, vol. 10, # 6, p. 911 - 920
[3] Journal of the American Chemical Society, 2011, vol. 133, # 49, p. 19832 - 19838
[4] Patent: CN104945411, 2018, B. Location in patent: Paragraph 0077; 0078; 0079
[5] New Journal of Chemistry, 2012, vol. 36, # 2, p. 438 - 451
(3-acrylamidophenyl)boronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (3-acrylamidophenyl)boronic acid manufacturers
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
- Product
- 3-Acrylamidophenylboronic acid 99349-68-5
- Price
- US $2.00-6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-07-29
Qingdao RENAS Polymer Material Co., Ltd.
- Product
- (3-acrylamidophenyl)boronic acid 99349-68-5
- Price
- US $0.00/kg
- Min. Order
- 20kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2025-04-09
Shaanxi Dideu New Materials Co. Ltd
- Product
- (M-ACRYLAMIDOPHENYL)BORONIC ACID 99349-68-5
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-03-05
99349-68-5, (3-acrylamidophenyl)boronic acidRelated Search:
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