2-BENZYLOXY-5-BROMOPYRIDINE
- Product Name
- 2-BENZYLOXY-5-BROMOPYRIDINE
- CAS No.
- 83664-33-9
- Chemical Name
- 2-BENZYLOXY-5-BROMOPYRIDINE
- Synonyms
- 5-BROMO-2-BENZYLOXYPYRIDINE;2-BENZYLOXY-5-BROMOPYRIDINE;6-Benzyloxy-3-bromopyridine;5-bromo-2-(phenylmethoxy)pyridine;Pyridine,5-bromo-2-(phenylmethoxy)-;2-BENZYLOXY-5-BROMOPYRIDINE ISO 9001:2015 REACH
- CBNumber
- CB3841507
- Molecular Formula
- C12H10BrNO
- Formula Weight
- 264.12
- MOL File
- 83664-33-9.mol
2-BENZYLOXY-5-BROMOPYRIDINE Property
- Melting point:
- 45-48°C
- Boiling point:
- 178-178.5 °C(Press: 14 Torr)
- Density
- 1.438±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 1.56±0.22(Predicted)
- color
- White to Light yellow
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B5905
- Product name
- 2-Benzyloxy-5-bromopyridine
- Packaging
- 1G
- Price
- $54
- Updated
- 2025/07/31
- Product number
- B5905
- Product name
- 2-Benzyloxy-5-bromopyridine
- Packaging
- 5G
- Price
- $215
- Updated
- 2025/07/31
- Product number
- B291535
- Product name
- 2-Benzyloxy-5-bromopyridine
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 4H07-9-01
- Product name
- 2-Benzyloxy-5-bromopyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $110
- Updated
- 2021/12/16
- Product number
- FB08615
- Product name
- 2-Benzyloxy-5-bromopyridine
- Packaging
- 2g
- Price
- $117.2
- Updated
- 2021/12/16
2-BENZYLOXY-5-BROMOPYRIDINE Chemical Properties,Usage,Production
Synthesis
624-28-2
100-51-6
83664-33-9
2,5-dibromopyridine (20.0 g, 84.4 mmol), dibenzo-18-crown-6 (1.5 g, 4.2 mmol), benzyl alcohol (11.9 g, 11.4 mL, 109.8 mmol), and potassium hydroxide (11.4 g, 202.6 mmol) were mixed in toluene (200 mL) and assembled with a Dean-Stark distributor, and the reaction was refluxed for 1.5 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was diluted with water and extracted with chloroform. The organic phase was separated, dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane/ethyl acetate, 98:2, v/v) and subsequently recrystallized from hexane to give 2-benzyloxy-5-bromopyridine (20.6 g, 92% yield) as a colorless solid.
References
[1] Journal of Organic Chemistry, 1995, vol. 60, # 5, p. 1408 - 1412
[2] Polyhedron, 2013, vol. 52, p. 755 - 760
[3] Patent: WO2004/43926, 2004, A1. Location in patent: Page 150
[4] Patent: WO2004/69805, 2004, A1. Location in patent: Page 55
[5] Patent: US2009/82403, 2009, A1. Location in patent: Page/Page column 66
2-BENZYLOXY-5-BROMOPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-BENZYLOXY-5-BROMOPYRIDINE manufacturers
- Product
- 2-BENZYLOXY-5-BROMOPYRIDINE 83664-33-9
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-08-23
- Product
- 2-Benzyloxy-5-broMopyridine 83664-33-9
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 500 MT
- Release date
- 2020-05-12