3,8-Dibromo-1,10-phenanthroline
- Product Name
- 3,8-Dibromo-1,10-phenanthroline
- CAS No.
- 100125-12-0
- Chemical Name
- 3,8-Dibromo-1,10-phenanthroline
- Synonyms
- 3,8-dibromo;3,8-Dibromophenanthr;3,8-dibromopheroline;8-Dibromophenanthroline;3,8-Dibromophenthroline;3,8-Dibromophenanthroline;3,8-dibromo-1,7-phenanthroline;3,8-dibromo-1,10-phenathroline;3,8-Dibromo-1,10-phenanthroline;1,10-Phenanthroline,3,8-dibroMo-
- CBNumber
- CB41012646
- Molecular Formula
- C12H6Br2N2
- Formula Weight
- 338
- MOL File
- 100125-12-0.mol
3,8-Dibromo-1,10-phenanthroline Property
- Melting point:
- 221-222 °C
- Boiling point:
- 428.9±40.0 °C(Predicted)
- Density
- 1.915
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 3.90±0.10(Predicted)
- color
- White to Light yellow
- λmax
- 352nm(DMF)(lit.)
- InChI
- InChI=1S/C12H6Br2N2/c13-9-3-7-1-2-8-4-10(14)6-16-12(8)11(7)15-5-9/h1-6H
- InChIKey
- IDWJREBUVYSPKS-UHFFFAOYSA-N
- SMILES
- N1C2C(=CC=C3C=2N=CC(Br)=C3)C=C(Br)C=1
Safety
- HS Code
- 29339900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D3209
- Product name
- 3,8-Dibromo-1,10-phenanthroline
- Purity
- >96.0%(HPLC)(T)
- Packaging
- 200mg
- Price
- $79
- Updated
- 2024/03/01
- Product number
- D3209
- Product name
- 3,8-Dibromo-1,10-phenanthroline
- Purity
- >96.0%(HPLC)(T)
- Packaging
- 1g
- Price
- $267
- Updated
- 2024/03/01
- Product number
- D428003
- Product name
- 3,8-Dibromo-1,10-phenanthroline
- Packaging
- 500mg
- Price
- $150
- Updated
- 2021/12/16
- Product number
- 073348
- Product name
- 3,8-Dibromo-1,10-phenanthroline
- Purity
- 95+%
- Packaging
- 1g
- Price
- $150
- Updated
- 2021/12/16
- Product number
- CS-W004457
- Product name
- 3,8-Dibromo-1,10-phenanthroline
- Purity
- ≥98.0%
- Packaging
- 5g
- Price
- $178
- Updated
- 2021/12/16
3,8-Dibromo-1,10-phenanthroline Chemical Properties,Usage,Production
Synthesis
Commercially available 1,10-phenanthroline monohydrochloride monohydrate reacts with bromine, giving 3,8-dibromo-1,10-phenanthroline as major products in a one-step reaction.
In a typical procedure, a solution of 1,10-phenanthroline monohydrochloride monohydrate (10 g, 43 mmol) in nitrobenzene (20 ml) was heated to 130-140 ℃ in a 250 ml 3-neck flask. Bromine (3.3 ml, 64 mmol in 9.3 ml nitrobenzene) was added dropwise throughout 1 h. The raw material was added to the solution after adding bromine. After stirring for 3 h at the same temperature, the reaction mixture was cooled to room temperature, treated with concentrated ammonium hydroxide, and extracted with dichloromethane. The combined organic layers were washed with water and dried (MgSO4). Concentration in a vacuum afforded a suspension of the products in nitrobenzene. The nitrobenzene was removed by dissolving the suspension in dichloromethane (I0 ml) and filtering it through silica gel (300 ml) using dichloromethane as the eluent. After the nitrobenzene eluted out, the products were recovered by gradually increasing the polarity of the eluent up to 10% MeOH in CH2C12. Flash column chromatography afforded production (2.4 g, 17 % yield) as white powders[1].
References
[1] Dimitrios Tzalis. “Simple one-step synthesis of 3-bromo- and 3,8-dibromo-1,10-phenanthroline: Fundamental building blocks in the design of metal chelates.” Tetrahedron Letters 36 1 (1995): 3489–3490.
3,8-Dibromo-1,10-phenanthroline Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3,8-Dibromo-1,10-phenanthroline manufacturers
- Product
- 3,8-Dibromophenanthroline 100125-12-0
- Price
- US $40.00/g
- Min. Order
- 1g
- Purity
- 97%
- Supply Ability
- 10kg
- Release date
- 2020-07-09
- Product
- 3,8-Dibromo-1,10-phenanthroline 100125-12-0
- Price
- US $57.00-257.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2024-04-12
- Product
- 3,8-Dibromophenanthroline 100125-12-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10