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Methyl 1H-pyrrole-3-carboxylate

Product Name
Methyl 1H-pyrrole-3-carboxylate
CAS No.
2703-17-5
Chemical Name
Methyl 1H-pyrrole-3-carboxylate
Synonyms
Methyl Pyrrole-3-carboxylate;EOS-61577;Methyl 3-pyrrolecarboxylate;Methyl1H-pyrrole-3-carboxylat;3-(Methoxycarbonyl)-1H-pyrrole;Methyl 1H-pyrrole-3-carboxylate;Methyl 1H-pyrrole-3-carboxylate, 95+%;Pyrrole-3-carboxylic acid methyl ester;1,1-dibromo-2-(chloromethyl)cyclopropane;1H-Pyrrole-3-carboxylic acid methyl ester
CBNumber
CB41086094
Molecular Formula
C6H7NO2
Formula Weight
125.13
MOL File
2703-17-5.mol
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Methyl 1H-pyrrole-3-carboxylate Property

Melting point:
85-89 °C
Boiling point:
284℃
Density 
1.184
Flash point:
126℃
storage temp. 
Inert atmosphere,Room Temperature
form 
solid
pka
15.42±0.50(Predicted)
color 
Off-white to light yellow
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C6H7NO2/c1-9-6(8)5-2-3-7-4-5/h2-4,7H,1H3
InChIKey
WLBNVSIQCFHAQB-UHFFFAOYSA-N
SMILES
N1C=CC(C(OC)=O)=C1
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-37-60
WGK Germany 
3
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
685399
Product name
Methyl 1H-pyrrole-3-carboxylate
Purity
97%
Packaging
1g
Price
$72.6
Updated
2024/03/01
Sigma-Aldrich
Product number
685399
Product name
Methyl 1H-pyrrole-3-carboxylate
Purity
97%
Packaging
250mg
Price
$63.8
Updated
2023/06/20
Alfa Aesar
Product number
H54340
Product name
Methyl pyrrole-3-carboxylate, 97%
Packaging
1g
Price
$118.65
Updated
2024/03/01
Alfa Aesar
Product number
H54340
Product name
Methyl pyrrole-3-carboxylate, 97%
Packaging
5g
Price
$463.65
Updated
2024/03/01
Alfa Aesar
Product number
H54340
Product name
Methyl pyrrole-3-carboxylate, 97%
Packaging
250mg
Price
$37
Updated
2021/12/16
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Methyl 1H-pyrrole-3-carboxylate Chemical Properties,Usage,Production

Uses

Methyl pyrrole-3-carboxylate is used as an organic chemical synthesis intermediate.

Application

A solution of methyl 1H-pyrrole-3-carboxylate (4.48 g, 35.8 mmol) in THF (70 mL) was cooled to -78 °C, N-bromosuccinimide (6.30 g, 35.4 mmol) was added, pyridine (five drops) was added, and the mixture was left standing in a freezer (-20 °C) for 3 days. The reaction mixture was concentrated under reduced pressure. Water was added to the residue, and the mixture was extracted using EtOAc. The extract was washed with brine, dried over Na2SO4, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (hexane-EtOAc = 9/1-1/1) to give Methyl 5-bromo-1H-pyrrole-3-carboxylate (3.59 g, 49percent) as a pale-yellow solid.

Research

Pyrrole and Methyl 1H-Pyrrole-3-Carboxylate could be used to prepare the Soft Actuators by Electrochemical Copolymerization. In specific, a counter electrode (Ti), a reference electrode (Ag/AgCl), and a working electrode (Ti) were immersed into methyl benzoate solutions of 0.25 M of pyrrole and methyl 1-H pyrrole-3-carboxylate with 100:0, 98:2, 95:5, 80:20 mol ratios and 0.2 M N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl) imide. The thickness of the prepared films was measured to be approximately 100 μm using a micrometer. The PPy actuator was used as the working electrode in the 1 M LiTFSI aqueous electrolyte solutions. The Py copolymer film, fabricated from pyrrole solution containing 2 and 5 mol% of methyl 1-H pyrrole-3-carboxylate, showed a reduced actuating strain of approximately 2%, but the creep strain was reduced to less than 1%[1].

References

[1] Yamasaki, Jun et al. “Soft Actuators Prepared by Electrochemical Copolymerization of Pyrrole and Methyl 1H-Pyrrole-3-Carboxylate.” 2013. 0.

Methyl 1H-pyrrole-3-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 1H-pyrrole-3-carboxylate Suppliers

A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
Biokemix
Tel
--
Fax
--
Email
biokemix@yes-boss.com
Country
India
ProdList
486
Advantage
50
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View Lastest Price from Methyl 1H-pyrrole-3-carboxylate manufacturers

Career Henan Chemical Co
Product
1H-Pyrrole-3-carboxylic acid, methyl ester (9CI) 2703-17-5
Price
US $8.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10tons
Release date
2018-12-25

2703-17-5, Methyl 1H-pyrrole-3-carboxylateRelated Search:


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