BOC-D-ALA-NH2

Product Name: BOC-D-ALA-NH2
CAS No.: 78981-25-6
Chemical Name: BOC-D-ALA-NH2
Synonyms: Boc-D-alamine;N-Boc-D-alanine amide;N-Boc-D-aminopropanamide;(R)-2-(Boc-amino)propanamide;(Tert-Butoxy)Carbonyl D-Ala-NH2;N-(tert-Butoxycarbonyl)-D-alaninamide;N-tert-Butoxycarbonyl-D-alanine amide;tert-butyl N-[(1R)-1-carbamoylethyl]carbamate;(R)-tert-Butyl (1-amino-1-oxopropan-2-yl)carbamate;N-(tert-Butoxycarbonyl)-D-alaninamideButoxycarbonyl-D-alanine amide
CBNumber: CB41091108
Molecular Formula: C8H16N2O3
Formula Weight: 188.22
MOL File: 78981-25-6.mol

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BOC-D-ALA-NH2 Property

Melting point:: 120-121 °C
Boiling point:: 343.1±25.0 °C(Predicted)
Density: 1.081±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 11.38±0.46(Predicted)
Appearance: White to yellow Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Iris Biotech GmbH

Product number: BAA5300
Product name: Boc-D-Ala-NH2
Packaging: 5G
Price: $108
Updated: 2021/12/16

AK Scientific

Product number: 2349AC
Product name: Boc-D-Ala-NH2
Packaging: 5g
Price: $111
Updated: 2021/12/16

AK Scientific

Product number: 2349AC
Product name: Boc-D-Ala-NH2
Packaging: 25g
Price: $253
Updated: 2021/12/16

Iris Biotech GmbH

Product number: BAA5300
Product name: Boc-D-Ala-NH2
Packaging: 25g
Price: $432
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AAA0008745
Product name: BOC-D-ALA-NH2
Purity: 95.00%
Packaging: 5MG
Price: $504.97
Updated: 2021/12/16

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BOC-D-ALA-NH2 Chemical Properties,Usage,Production

Synthesis

15761-38-3

78981-25-6

GENERAL STEPS: To a stirred solution of N-tert-butoxycarbonyl-L-alanine (5.0 g, 26.4 mmol) in anhydrous tetrahydrofuran (THF) at -10 °C were sequentially added triethylamine (3 mL, 21.12 mmol) and ethyl chloroformate (2.5 mL, 26.4 mmol). The reaction mixture was stirred continuously at this temperature for 1 hour, followed by the passage of ammonia (NH3) for 1.5 hours. After completion of ammonia pass-through, the reaction mixture was transferred to room temperature conditions and continued stirring overnight. At the end of the reaction, the THF solvent was removed by distillation under reduced pressure. Subsequently, aqueous sodium chloride solution (40 mL) was added to the residue and extracted several times with ethyl acetate (EtOAc, 5 x 40 mL). The organic phases were combined, washed sequentially with 0.5 M hydrochloric acid (2 × 30 mL), dried with anhydrous sodium sulfate (Na2SO4), filtered, and the solvent was removed by vacuum evaporation to finally obtain the target product, N-Boc-D-alaninamide.

References

[1] Tetrahedron, 1999, vol. 55, # 42, p. 12301 - 12308
[2] Tetrahedron Letters, 2007, vol. 48, # 4, p. 603 - 607
[3] Synthetic Communications, 2013, vol. 43, # 7, p. 993 - 1006
[4] Bulletin of the Chemical Society of Japan, 1988, vol. 61, # 7, p. 2647 - 2648
[5] Tetrahedron Asymmetry, 2013, vol. 24, # 24, p. 1572 - 1575

BOC-D-ALA-NH2 Preparation Products And Raw materials

Raw materials

Preparation Products

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BOC-D-ALA-NH2 Suppliers

China 53 India 1 United States 2 Global 56

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

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Email: info@hanhongsci.com
Country: China
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Advantage: 64

AF Biochem Co., Ltd.

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Country: China
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AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: 15928766785 15928766785
Fax: QQ961458712
Email: wupengcheng@astatech.cn
Country: China
ProdList: 1987
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
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Wuxi Zhongkun Biochemical Technology Co., Ltd.

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Country: China
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Sichuan Ampebiochem Co., Ltd.

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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

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SanoChem (Chengdu) Tech. Co., Ltd.

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Shanghai GL Peptide Ltd.

Tel: +86-21-61263340; 17609490614 13764994101
Fax: 021-61263399
Email: fisherwang@glschina.com
Country: China
ProdList: 8258
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View Lastest Price from BOC-D-ALA-NH2 manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Boc-D-Ala-NH2 78981-25-6
Price: US $2.00-6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-30

78981-25-6, BOC-D-ALA-NH2Related Search:

D-1-N-Boc-prolinamide BOC-D-PHE-PRO-ARG-OH BOC-D-PRO-GLY-OH BOC-D-PRO-PHE-OH BOC-D-GLU-NH2 BOC-D-ASP-NH2 BOC-D-PRO-D-PHE-OH BOC-D-PHE-PRO-OH BOC-D-MET-GLY-OH 1-T-BOC-PIPERIDINE-4-SPIRO-5'-[1',3'-BIS-T-BOC]-HYDANTOIN (R)-3-(BOC-AMINO)-2-OXO-1-PYRROLIDINE-ACETIC ACID BOC-D-PHE-PRO-OSU (R)-3-(BOC-AMINO)-2-OXO-1-AZEPINE-ACETIC ACID BOC-DARG-GLY-ARG-CHO N-T-BOC-D-PHE-ALA-NLE P-NITROANILIDE BOC-ALA-D-GLU(OBZL)-NH2 BOC-D-LEU-GLY-GLY-OH N-ALPHA-T-BOC-D-VAL-L-LEU-NE-CBZ-L-LYS

(R)-tert-Butyl (1-amino-1-oxopropan-2-yl)carbamate

N-tert-Butoxycarbonyl-D-alanine amide

N-(tert-Butoxycarbonyl)-D-alaninamideButoxycarbonyl-D-alanine amide

(Tert-Butoxy)Carbonyl D-Ala-NH2

N-(tert-Butoxycarbonyl)-D-alaninamide

N-Boc-D-aminopropanamide

N-Boc-D-alanine amide

tert-butyl N-[(1R)-1-carbamoylethyl]carbamate

Carbamic acid, N-[(1R)-2-amino-1-methyl-2-oxoethyl]-, 1,1-dimethylethyl ester

(R)-2-(Boc-amino)propanamide

Boc-D-alamine

78981-25-6