ChemicalBook > CAS DataBase List > 1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane

Product Name
1,3-Bis(diphenylphosphino)propane
CAS No.
6737-42-4
Chemical Name
1,3-Bis(diphenylphosphino)propane
Synonyms
DPPP;1,3-bis(diphenyphosphino)propane;Bis(1,3-diphenylphosphino)propane;1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;98% DPPP;1,3-Bis(diphenyL;phosphino)propane;PH2PCH2 CH2CH2PPH2;1,3-BIS(DIPHENYPHOSPHINO);1,3-bis-(diphosphino)propane
CBNumber
CB4132404
Molecular Formula
C27H26P2
Formula Weight
412.45
MOL File
6737-42-4.mol
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1,3-Bis(diphenylphosphino)propane Property

Melting point:
63-65 °C (lit.)
Boiling point:
529.7±33.0 °C(Predicted)
Flash point:
235°C
storage temp. 
Inert atmosphere,Room Temperature
form 
Granules or Powder
color 
White to light yellow-beige
Water Solubility 
insoluble
Sensitive 
Air Sensitive
BRN 
2821785
InChI
InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey
LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES
P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference
6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System
Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-36
WGK Germany 
3
10-23
TSCA 
Yes
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
262048
Product name
1,3-Bis(diphenylphosphino)propane
Purity
97%
Packaging
1g
Price
$35.4
Updated
2024/03/01
Sigma-Aldrich
Product number
262048
Product name
1,3-Bis(diphenylphosphino)propane
Purity
97%
Packaging
5g
Price
$65.3
Updated
2024/03/01
TCI Chemical
Product number
B1138
Product name
1,3-Bis(diphenylphosphino)propane
Purity
>98.0%(GC)
Packaging
5g
Price
$34
Updated
2024/03/01
TCI Chemical
Product number
B1138
Product name
1,3-Bis(diphenylphosphino)propane
Purity
>98.0%(GC)
Packaging
25g
Price
$79
Updated
2024/03/01
Alfa Aesar
Product number
A12931
Product name
1,3-Bis(diphenylphosphino)propane, 97%
Packaging
5g
Price
$76.9
Updated
2024/03/01
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1,3-Bis(diphenylphosphino)propane Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

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1,3-Bis(diphenylphosphino)propane Suppliers

Carbosynth
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Melrob Ltd (part of Nordmann)
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View Lastest Price from 1,3-Bis(diphenylphosphino)propane manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,3-Bis(diphenylphosphino)propane 6737-42-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-06
Shanghai UCHEM Inc.
Product
1,3-Bis(diphenylphosphino)propane 6737-42-4
Price
US $10.00-178.00/g
Min. Order
25g
Purity
0.98
Supply Ability
100kg
Release date
2023-10-20
Hebei Weibang Biotechnology Co., Ltd
Product
1,3-Bis(diphenylphosphino)propane 6737-42-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-31

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