2,5-Dihydroxy-1,4-dithiane
- Product Name
- 2,5-Dihydroxy-1,4-dithiane
- CAS No.
- 40018-26-6
- Chemical Name
- 2,5-Dihydroxy-1,4-dithiane
- Synonyms
- 1,4-DITHIANE-2,5-DIOL;DITHIANE;p-Dithiane-2,5-diol;FEMA 3826;1,4-Dithiane-2,5-dio;1,4-dithane-2,5-diol;MERCATOACETALDEHYDE DIMER;NSC 106280;4-dithiane;5-Dihydroxy-1
- CBNumber
- CB4141273
- Molecular Formula
- C4H8O2S2
- Formula Weight
- 152.24
- MOL File
- 40018-26-6.mol
2,5-Dihydroxy-1,4-dithiane Property
- Melting point:
- 130 °C (dec.) (lit.)
- Boiling point:
- 244.73°C (rough estimate)
- Density
- 1.224 (estimate)
- vapor pressure
- 0Pa at 25℃
- refractive index
- 1.5200 (estimate)
- FEMA
- 3826 | 2,5-DIHYDROXY-1,4-DITHIANE
- storage temp.
- 2-8°C
- solubility
- H2O: 0.39% at 20 °C
- form
- Crystalline Powder
- pka
- 12.04±0.40(Predicted)
- color
- White to yellow
- PH
- 4.9 (3.9g/l, H2O)
- Odor
- at 0.10 % in propylene glycol. sulfury meaty toasted bread broth egg tomato
- Odor Type
- sulfurous
- Water Solubility
- 3.9 g/L (20 ºC)
- JECFA Number
- 550
- BRN
- 104402
- InChIKey
- YUIOPHXTILULQC-UHFFFAOYSA-N
- LogP
- -0.276 at 22.8℃ and pH6.3
- CAS DataBase Reference
- 40018-26-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-41-43-52/53-36/37/38
- Safety Statements
- 26-36/37/39-61-37/39-24-36
- RIDADR
- UN2811
- WGK Germany
- 2
- F
- 1-8-10-13
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29349990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H317May cause an allergic skin reaction
H330Fatal if inhaled
H373May cause damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 183954
- Product name
- 1,4-Dithiane-2,5-diol
- Purity
- 97%
- Packaging
- 50g
- Price
- $52.5
- Updated
- 2023/01/07
- Product number
- 183954
- Product name
- 1,4-Dithiane-2,5-diol
- Purity
- 97%
- Packaging
- 250g
- Price
- $115
- Updated
- 2023/01/07
- Product number
- D1761
- Product name
- 2,5-Dihydroxy-1,4-dithiane
- Purity
- >96.0%(GC)
- Packaging
- 25g
- Price
- $27
- Updated
- 2024/03/01
- Product number
- D1761
- Product name
- 2,5-Dihydroxy-1,4-dithiane
- Purity
- >96.0%(GC)
- Packaging
- 500g
- Price
- $320
- Updated
- 2024/03/01
- Product number
- A14620
- Product name
- 2,5-Dihydroxy-1,4-dithiane, 96%
- Packaging
- 50g
- Price
- $27.65
- Updated
- 2024/03/01
2,5-Dihydroxy-1,4-dithiane Chemical Properties,Usage,Production
Chemical Properties
2,5-Dihydroxy-1,4-dithiane has a sulfurous, meaty, toasted bread-like odor
Chemical Properties
white to yellowish crystalline powder
Uses
1,4-Dithiane-2,5-diol is a hydroxylated dithiane derivative with phytogrowth-inhibitory and antibacterial activities.
Uses
1,4-Dithiane-2,5-diol was used in the synthesis of:
- substituted tetrahydrothiophene derivatives
- 2-amino-3-(arylsulfonyl)thiophenes, potential antiviral and antitumor agents
Definition
ChEBI: 1,4-Dithiane-2,5-diol is a member of dithianes.
Aroma threshold values
Aroma characteristics at 0.1% EtoH: sulfurous, grilled meaty, pungent, brothy, eggy, heavy and rich, toasted bread, tomato
Taste threshold values
Taste characteristics at 0.25 to 10 ppm: metallic, meaty savory chicken and beef, sulfurous, egg-yolk-like
Synthesis Reference(s)
Synthetic Communications, 14, p. 483, 1984 DOI: 10.1080/00397918408059569
General Description
1,4-Dithiane-2,5-diol undergoes bifunctional squaramide catalyzed sulfa-Michael/aldol cascade reaction with chalcones to afford trisubstituted tetrahydrothiophenes. It participates in diastereoselective [3+3] cycloaddition with azomethine imines catalyzed by 1,4-diazabicyclo[2.2.2]octane. It is a mercaptoacetaldehyde dimer and an efficient synthon for incorporating a thiol group to in situ generated nitroalkenes.
2,5-Dihydroxy-1,4-dithiane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,5-Dihydroxy-1,4-dithiane manufacturers
- Product
- 2,5-Dihydroxy-1,4-dithiane 40018-26-6
- Price
- US $35.00-1.10/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-19
- Product
- 2,5-Dihydroxy-1,4-dithiane/1,4-DITHIANE-2,5-DIOL 40018-26-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99.0%min
- Supply Ability
- 10000kg
- Release date
- 2023-06-09
- Product
- 3-Amino-5-mercapto-1,2,4-triazole 40018-26-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99.0%min
- Supply Ability
- 10000kg
- Release date
- 2023-06-09