ChemicalBook > CAS DataBase List > 2-hydroxy-6-methyl-1H-quinolin-4-one

2-hydroxy-6-methyl-1H-quinolin-4-one

Product Name
2-hydroxy-6-methyl-1H-quinolin-4-one
CAS No.
1677-44-7
Chemical Name
2-hydroxy-6-methyl-1H-quinolin-4-one
Synonyms
6-Methylquinoline-2,4-diol;4-Hydroxy-6-methyl-2-quinolone;6-Methyl-2,4-dihydroxyquinoline;4,6-Dihydroxy-2-methylquinoline;2-hydroxy-6-methyl-1H-quinolin-4-one;4-Hydroxy-6-methyl-1H-quinolin-2-one;2(1H)-Quinolinone, 4-hydroxy-6-methyl-
CBNumber
CB41456167
Molecular Formula
C10H9NO2
Formula Weight
175.18
MOL File
1677-44-7.mol
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2-hydroxy-6-methyl-1H-quinolin-4-one Property

Melting point:
342 ºC
Boiling point:
404.0±45.0 °C(Predicted)
Density 
1.313
storage temp. 
Sealed in dry,Room Temperature
pka
4.50±1.00(Predicted)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M341805
Product name
6-Methylquinoline-2,4-diol
Packaging
100mg
Price
$90
Updated
2021/12/16
TRC
Product number
M341805
Product name
6-Methylquinoline-2,4-diol
Packaging
50mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
073413
Product name
6-Methyl-2,4-dihydroxyquinoline
Purity
95+%
Packaging
1g
Price
$838
Updated
2021/12/16
Matrix Scientific
Product number
073413
Product name
6-Methyl-2,4-dihydroxyquinoline
Purity
95+%
Packaging
5g
Price
$2250
Updated
2021/12/16
AK Scientific
Product number
W3646
Product name
6-Methyl-2,4-dihydroxyquinoline
Packaging
250mg
Price
$298
Updated
2021/12/16
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2-hydroxy-6-methyl-1H-quinolin-4-one Chemical Properties,Usage,Production

Synthesis

106-49-0

105-53-3

1677-44-7

In a dry three-necked flask, p-toluidine (5.0 g, 46.7 mmol), diethyl malonate (14 mL, 93.3 mmol) and polyphosphoric acid (22.5 mL, 140 mmol) were added sequentially. The reaction mixture was stirred at 150 °C for 3 hours. Upon completion of the reaction, the reaction system was cooled to room temperature, 500 mL of ice water was slowly added, and the pH was adjusted to 5-6 with alkali. the resulting yellow solid product was collected by filtration. The solid was dissolved in an appropriate amount of sodium hydroxide solution and filtered again to yield 7.5 g of 6-methyl-2,4-dihydroxyquinoline as a yellow solid in 92% yield.

References

[1] Patent: CN107098901, 2017, A. Location in patent: Paragraph 0082; 0083; 0084; 0085
[2] British Journal of Pharmacology, 2015, vol. 172, # 5, p. 1195 - 1221
[3] European Journal of Medicinal Chemistry, 2010, vol. 45, # 10, p. 4467 - 4472

2-hydroxy-6-methyl-1H-quinolin-4-one Preparation Products And Raw materials

Raw materials

Preparation Products

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1677-44-7, 2-hydroxy-6-methyl-1H-quinolin-4-oneRelated Search:


  • 2-hydroxy-6-methyl-1H-quinolin-4-one
  • 4,6-Dihydroxy-2-methylquinoline
  • 6-Methyl-2,4-dihydroxyquinoline
  • 4-Hydroxy-6-methyl-2-quinolone
  • 6-Methylquinoline-2,4-diol
  • 4-Hydroxy-6-methyl-1H-quinolin-2-one
  • 2(1H)-Quinolinone, 4-hydroxy-6-methyl-
  • 1677-44-7