4-Methanesulfonyl-piperidine
- Product Name
- 4-Methanesulfonyl-piperidine
- CAS No.
- 290328-55-1
- Chemical Name
- 4-Methanesulfonyl-piperidine
- Synonyms
- EOS-61037;4-Methanesulfonyl-piperidine;4-(Methylsulfonyl)piperid...;Piperidine, 4-(Methylsulfonyl)-;4-Methanesulfonylpiperidine hydrochloride;4-(methylsulfonyl)piperidine hydrochloride
- CBNumber
- CB41559581
- Molecular Formula
- C6H13NO2S
- Formula Weight
- 163.24
- MOL File
- 290328-55-1.mol
4-Methanesulfonyl-piperidine Property
- Boiling point:
- 336.9±31.0 °C(Predicted)
- Density
- 1.18±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- pka
- 9.22±0.10(Predicted)
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- B486215
- Product name
- 4-(Methylsulfonyl)piperidine
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 2920AB
- Product name
- 4-(Methylsulfonyl)piperidine
- Packaging
- 250mg
- Price
- $91
- Updated
- 2021/12/16
- Product number
- 068512
- Product name
- 4-Methylsulfonylpiperidine
- Purity
- >95%
- Packaging
- 500mg
- Price
- $93
- Updated
- 2021/12/16
- Product number
- 068512
- Product name
- 4-Methylsulfonylpiperidine
- Purity
- >95%
- Packaging
- 1g
- Price
- $143
- Updated
- 2021/12/16
- Product number
- BP-11900
- Product name
- 4-(methylsulfonyl)piperidine
- Packaging
- 100mg
- Price
- $180
- Updated
- 2021/12/16
4-Methanesulfonyl-piperidine Chemical Properties,Usage,Production
Synthesis
189205-49-0
290328-55-1
General procedure for the synthesis of 4-methylsulfonylpiperidine from tert-butyl 4-(methylsulfonyl)piperidine-1-carboxylate (Step 4): tert-butyl 4-(methylsulfonyl)piperidine-1-carboxylate obtained in Step 3 of Reference Example 12 was dissolved in ethyl acetate (16 mL), followed by the addition of a 4.0 mol/L dioxane solution of hydrogen chloride (12 mL). The reaction mixture was stirred at room temperature for 3 hours. Upon completion of the reaction, the precipitated solid was collected by filtration to afford the target product 4-(methylsulfonyl)piperidine (1.4 g, 76% yield). The structure of the product was confirmed by 1H-NMR (DMSO-d6, 270 MHz) with the following chemical shifts δ (ppm): 3.41-3.31 (m, 3H), 2.97 (s, 3H), 2.97-2.82 (m, 2H), 2.18-2.13 (m, 2H), 1.92-1.73 (m, 2H).
References
[1] Patent: EP1642880, 2006, A1. Location in patent: Page/Page column 112
[2] Patent: US2003/100567, 2003, A1
4-Methanesulfonyl-piperidine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Methanesulfonyl-piperidine manufacturers
- Product
- 4-Methanesulfonyl-piperidine 290328-55-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-24