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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

Product Name
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
CAS No.
983-81-3
Chemical Name
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
Synonyms
NSC 132587;trans-vinylenebis[diphenylphosphine];[(E)-Vinylene]bis(diphenylphosphine);(E)-1,2-Bis(diphenylphosphino)ethene;(E)-1,2-Bis(diphenylphosphanyl)ethene;TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE;[(E)-1,2-Ethenediyl]bis(diphenylphosphine);trans-1,2-Ethenediylbis(diphenylphosphine);[(E)-Ethene-1,2-diyl]bis(diphenylphosphine);trans-1,2-Bis(diphenylphosphino)ethylene,97%
CBNumber
CB4177436
Molecular Formula
C26H22P2
Formula Weight
396.4
MOL File
983-81-3.mol
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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Property

Melting point:
126-130 °C(lit.)
Boiling point:
546.8±33.0 °C(Predicted)
form 
Crystalline
color 
White to Almost white
Sensitive 
Air Sensitive
BRN 
757793
CAS DataBase Reference
983-81-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 3464 6.1/PG 2
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
287970
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
97%
Packaging
1g
Price
$29.04
Updated
2024/03/01
TCI Chemical
Product number
B2003
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
>96.0%(T)
Packaging
1g
Price
$70
Updated
2024/03/01
Alfa Aesar
Product number
L08508
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
98%
Packaging
1g
Price
$49.9
Updated
2023/06/20
Alfa Aesar
Product number
L08508
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
98%
Packaging
5g
Price
$150
Updated
2021/12/16
TRC
Product number
T705173
Product name
trans-1,2-bis(Diphenylphosphino)ethylene
Packaging
100mg
Price
$75
Updated
2021/12/16
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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Coupling of primary and secondary alkyl halides with aryl grignard reagents
  • Homogeneous hydrogenation of Carbon Dioxide mediated by Ruthenium

Reactant for:
  • Preparation of cyclopalladated derivatives of benzylidene
  • Preparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agents
  • Catalytic asymetric intramolecular hydroamination of alkynylamines

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59

983-81-3, TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENERelated Search:


  • TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
  • (E)-1,2-Bis(diphenylphosphino)ethene
  • [(E)-1,2-Ethenediyl]bis(diphenylphosphine)
  • [(E)-Ethene-1,2-diyl]bis(diphenylphosphine)
  • [(E)-Vinylene]bis(diphenylphosphine)
  • trans-vinylenebis[diphenylphosphine]
  • trans-1,2-Bis(diphenylphosphino)ethylene,97%
  • NSC 132587
  • trans-1,2-Ethenediylbis(diphenylphosphine)
  • (E)-1,2-Bis(diphenylphosphanyl)ethene
  • [(E)-2-diphenylphosphinoethenyl]-diphenylphosphine
  • trans-1,2-Bis(diphenylphosphino)ethylene &gt
  • Phosphine, 1,1'-(1E)-1,2-ethenediylbis[1,1-diphenyl-
  • [(E)-2-diphenylphosphanylethenyl]-diphenylphosphane
  • 983-81-3
  • C26H22P2
  • Phosphine Ligands
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
  • Ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands