ChemicalBook > CAS DataBase List > TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

Product Name
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
CAS No.
983-81-3
Chemical Name
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
Synonyms
NSC 132587;trans-vinylenebis[diphenylphosphine];[(E)-Vinylene]bis(diphenylphosphine);(E)-1,2-Bis(diphenylphosphino)ethene;(E)-1,2-Bis(diphenylphosphanyl)ethene;TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE;[(E)-1,2-Ethenediyl]bis(diphenylphosphine);trans-1,2-Ethenediylbis(diphenylphosphine);[(E)-Ethene-1,2-diyl]bis(diphenylphosphine);trans-1,2-Bis(diphenylphosphino)ethylene,97%
CBNumber
CB4177436
Molecular Formula
C26H22P2
Formula Weight
396.4
MOL File
983-81-3.mol
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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Property

Melting point:
126-130 °C(lit.)
Boiling point:
546.8±33.0 °C(Predicted)
form 
Crystalline
color 
White to Almost white
Sensitive 
Air Sensitive
BRN 
757793
CAS DataBase Reference
983-81-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 3464 6.1/PG 2
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
287970
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
97%
Packaging
1g
Price
$29.04
Updated
2024/03/01
TCI Chemical
Product number
B2003
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
>96.0%(T)
Packaging
1g
Price
$70
Updated
2024/03/01
Alfa Aesar
Product number
L08508
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
98%
Packaging
1g
Price
$49.9
Updated
2023/06/20
Alfa Aesar
Product number
L08508
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
98%
Packaging
5g
Price
$150
Updated
2021/12/16
TRC
Product number
T705173
Product name
trans-1,2-bis(Diphenylphosphino)ethylene
Packaging
100mg
Price
$75
Updated
2021/12/16
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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Coupling of primary and secondary alkyl halides with aryl grignard reagents
  • Homogeneous hydrogenation of Carbon Dioxide mediated by Ruthenium

Reactant for:
  • Preparation of cyclopalladated derivatives of benzylidene
  • Preparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agents
  • Catalytic asymetric intramolecular hydroamination of alkynylamines

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Suppliers

Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
TCI EUROPE N.V.
Tel
--
Fax
--
Email
sales@tcieurope.be
Country
Belgium
ProdList
2200
Advantage
66

983-81-3, TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENERelated Search:


  • TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
  • (E)-1,2-Bis(diphenylphosphino)ethene
  • [(E)-1,2-Ethenediyl]bis(diphenylphosphine)
  • [(E)-Ethene-1,2-diyl]bis(diphenylphosphine)
  • [(E)-Vinylene]bis(diphenylphosphine)
  • trans-vinylenebis[diphenylphosphine]
  • trans-1,2-Bis(diphenylphosphino)ethylene,97%
  • NSC 132587
  • trans-1,2-Ethenediylbis(diphenylphosphine)
  • (E)-1,2-Bis(diphenylphosphanyl)ethene
  • [(E)-2-diphenylphosphinoethenyl]-diphenylphosphine
  • trans-1,2-Bis(diphenylphosphino)ethylene &gt
  • Phosphine, 1,1'-(1E)-1,2-ethenediylbis[1,1-diphenyl-
  • [(E)-2-diphenylphosphanylethenyl]-diphenylphosphane
  • 983-81-3
  • C26H22P2
  • Phosphine Ligands
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
  • Ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands