ChemicalBook > CAS DataBase List > TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

Product Name
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
CAS No.
983-81-3
Chemical Name
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
Synonyms
NSC 132587;trans-vinylenebis[diphenylphosphine];[(E)-Vinylene]bis(diphenylphosphine);(E)-1,2-Bis(diphenylphosphino)ethene;(E)-1,2-Bis(diphenylphosphanyl)ethene;TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE;[(E)-1,2-Ethenediyl]bis(diphenylphosphine);trans-1,2-Ethenediylbis(diphenylphosphine);[(E)-Ethene-1,2-diyl]bis(diphenylphosphine);trans-1,2-Bis(diphenylphosphino)ethylene,97%
CBNumber
CB4177436
Molecular Formula
C26H22P2
Formula Weight
396.4
MOL File
983-81-3.mol
More
Less

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Property

Melting point:
126-130 °C(lit.)
Boiling point:
546.8±33.0 °C(Predicted)
form 
Crystalline
color 
White to Almost white
Sensitive 
Air Sensitive
BRN 
757793
CAS DataBase Reference
983-81-3(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 3464 6.1/PG 2
WGK Germany 
3
HS Code 
29310099
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
287970
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
97%
Packaging
1g
Price
$29.04
Updated
2024/03/01
TCI Chemical
Product number
B2003
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
>96.0%(T)
Packaging
1g
Price
$70
Updated
2024/03/01
Alfa Aesar
Product number
L08508
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
98%
Packaging
1g
Price
$49.9
Updated
2023/06/20
Alfa Aesar
Product number
L08508
Product name
trans-1,2-Bis(diphenylphosphino)ethylene
Purity
98%
Packaging
5g
Price
$150
Updated
2021/12/16
TRC
Product number
T705173
Product name
trans-1,2-bis(Diphenylphosphino)ethylene
Packaging
100mg
Price
$75
Updated
2021/12/16
More
Less

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Coupling of primary and secondary alkyl halides with aryl grignard reagents
  • Homogeneous hydrogenation of Carbon Dioxide mediated by Ruthenium

Reactant for:
  • Preparation of cyclopalladated derivatives of benzylidene
  • Preparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agents
  • Catalytic asymetric intramolecular hydroamination of alkynylamines

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59

983-81-3, TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENERelated Search:


  • TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
  • (E)-1,2-Bis(diphenylphosphino)ethene
  • [(E)-1,2-Ethenediyl]bis(diphenylphosphine)
  • [(E)-Ethene-1,2-diyl]bis(diphenylphosphine)
  • [(E)-Vinylene]bis(diphenylphosphine)
  • trans-vinylenebis[diphenylphosphine]
  • trans-1,2-Bis(diphenylphosphino)ethylene,97%
  • NSC 132587
  • trans-1,2-Ethenediylbis(diphenylphosphine)
  • (E)-1,2-Bis(diphenylphosphanyl)ethene
  • [(E)-2-diphenylphosphinoethenyl]-diphenylphosphine
  • trans-1,2-Bis(diphenylphosphino)ethylene &gt
  • Phosphine, 1,1'-(1E)-1,2-ethenediylbis[1,1-diphenyl-
  • [(E)-2-diphenylphosphanylethenyl]-diphenylphosphane
  • 983-81-3
  • C26H22P2
  • Phosphine Ligands
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
  • Ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands