rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

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rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

Stability Storage

Product Name: rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
CAS No.: 100163-29-9
Chemical Name: rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
Synonyms: Rac-EthyL;enebis(tetrahydroindenyL;(ethylene bis-tetrahydroindenyl)zirconium dichloride;Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM;rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichl...;Rac-[ethylenebis(4,5,6,7-tetrahydroindenyl)]zirconium dichloride;(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
CBNumber: CB4202015
Molecular Formula: C20H24Cl2Zr10*
Formula Weight: 426.53
MOL File: 100163-29-9.mol

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rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Property

Melting point:: 267-271 °C(lit.)
form: Powder
color: white to pale yellow
Sensitive: moisture sensitive

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Safety

Hazard Codes: C,Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39-45-36
RIDADR: UN 3261 8/PG 2
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 532126
Product name: Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)
Purity: 97%
Packaging: 500mg
Price: $164
Updated: 2024/03/01

Strem Chemicals

Product number: 40-1400
Product name: rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride
Packaging: 100mg
Price: $130
Updated: 2024/03/01

Strem Chemicals

Product number: 40-1400
Product name: rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride
Packaging: 500mg
Price: $417
Updated: 2024/03/01

TRC

Product number: E923668
Product name: Rac-Ethylenebis(tetrahydroindenyl)zirconiumDichloride
Packaging: 10mg
Price: $55
Updated: 2021/12/16

TRC

Product number: E923668
Product name: Rac-Ethylenebis(tetrahydroindenyl)zirconiumDichloride
Packaging: 50mg
Price: $195
Updated: 2021/12/16

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rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Chemical Properties,Usage,Production

Stability

Stable under normal temperature and pressure, avoid contact with water and oxidants.

Storage

sealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources.

Chemical Properties

White to pale yellow powder,it can carry out catalytic reaction.

Uses

Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.

Uses

Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines

reaction suitability

core: zirconium
reagent type: catalyst

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride manufacturers

WUXI HONOR SHINE CHEMICAL CO.,LTD

Product: Ethylenebis (tetrahydroindenyl) zirconium dichloride 100163-29-9
Price: US $0.00/g/Bag
Min. Order: 100g/Bag
Purity: 98%
Supply Ability: 2tons
Release date: 2021-12-28

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100163-29-9

C2H4C9H102ZrCl2

C20H26Cl2Zr

C20H24Cl2Zr

Chiral Catalysts, Ligands, and Reagents

Other Chiral Catalysts

Zirconium

Asymmetric Synthesis

Catalysis and Inorganic Chemistry

metallocene

Catalysis and Inorganic Chemistry

Chemical Synthesis

Zirconium