Zirconium oxychloride
Physical Properties Uses Preparation Toxicity- Product Name
- Zirconium oxychloride
- CAS No.
- 7699-43-6
- Chemical Name
- Zirconium oxychloride
- Synonyms
- ZROCL2;ZIRCONIUM CHLORIDE;ZIRCONYL CHLORIDE;ZIRCONIUM DICHLORIDE OXIDE;nci-c60811;chlorozirconyl;JACS-7699-43-6;Dichlorooxozirconium;dichlorooxo-zirconiu;Zirconium oxychlorid
- CBNumber
- CB6470074
- Molecular Formula
- Cl2OZr
- Formula Weight
- 178.13
- MOL File
- 7699-43-6.mol
Zirconium oxychloride Property
- Melting point:
- −15 °C
- Density
- 1.344 g/mL at 25 °C
- solubility
- soluble in H2O, ethanol
- form
- Liquid
- color
- Clear colorless
- Merck
- 13,10237
- Stability:
- Stable. Incompatible with strong oxidizing agents, water, moisture, alkali metals.
- CAS DataBase Reference
- 7699-43-6(CAS DataBase Reference)
- EPA Substance Registry System
- Zirconium, dichlorooxo- (7699-43-6)
Safety
- Hazard Codes
- C,Xn
- Risk Statements
- 23-34-37-20/21/22-36/38
- Safety Statements
- 26-36-45-36/37/39-36/37
- RIDADR
- UN 1789
- WGK Germany
- 1
- HazardClass
- 8
- PackingGroup
- III
- Hazardous Substances Data
- 7699-43-6(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P234Keep only in original container.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 464198
- Product name
- Zirconyl chloride solution
- Purity
- 30% in hydrochloric acid
- Packaging
- 250ml
- Price
- $263
- Updated
- 2023/06/20
- Product number
- ING0010511
- Product name
- ZIRCONIUM OXYCHLORIDE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1097.25
- Updated
- 2021/12/16
- Product number
- ING0010511
- Product name
- ZIRCONIUM OXYCHLORIDE
- Purity
- 95.00%
- Packaging
- 50G
- Price
- $2512.13
- Updated
- 2021/12/16
- Product number
- AR005FXR
- Product name
- Zirconium,dichlorooxo-
- Purity
- 36%
- Packaging
- 25g
- Price
- $13
- Updated
- 2021/12/16
- Product number
- AR005FXR
- Product name
- Zirconium,dichlorooxo-
- Purity
- 36%
- Packaging
- 100g
- Price
- $32
- Updated
- 2021/12/16
Zirconium oxychloride Chemical Properties,Usage,Production
Physical Properties
The octahydrate is a white silky solid; tetragonal crystals consisting of tetramers; effloresces; refractive index 1.552; loses six water molecules at 150°C; becomes anhydrous at 210°C; decomposes at 400°C; soluble in water; aqueous solution acidic; also soluble in alcohol and ether; slightly soluble in hydrochloric acid.
Uses
Zirconyl chloride is used to make pigment toners and improve properties of color lakes of acid and basic dyes. Also, it is used to prepare body deodorants and antiperspirant, water repellant, dye precipitant, catalysts, and many zirconium compounds.
Preparation
The compound is prepared by dissolving zirconium tetrachloride, ZrCl4, or sodium zirconate, Na4ZrO4, in hydrochloric acid solution followed by evaporation to obtain crystals of octahydrate.
Also, the compound can be prepared by reacting zirconium tetrachloride with chlorine oxide:
ZrCl4 + Cl2O → ZrOCl2 + 2Cl2
Toxicity
Moderately toxic by ingestion, intraperitoneal and subcutaneous routes.
LD50 (intraperitioneal) (rat): 400mg/kg
Chemical Properties
Zirconium oxychloride exists as white silky crystals, soluble in water and alcohol. With water, the octahydrate is formed as tetragonal white needles. It is extremely hygroscopic and decomposes to zirconium tetrachloride (ZrCl4) and zirconium oxide (ZrO2) at 250 C. It is also formed as the octahydrate [13520-92-8] as white, tetrahedral crystals that are very soluble in water, ethyl alcohol, ether, and methanol, among others, but only slightly soluble in hydrochloric acid. When heated to decomposition, it emits toxic fumes of hydrogen chloride.
Uses
Building block for a new series of mixed zirconium phosphonates which may have uses in catalysis, ion exchange or photophysics.
Uses
Textile, cosmetic and grease additive, antiperspirant, water repellents, chemical reagent, zirconium salts, in lakes and toners of acidic and basic dyes, oil-field acidizing aid.
Definition
ChEBI: Zirconyl chloride is a zirconium coordination entity consisting of zirconium(IV) bound to oxygen via a double bond and to two chlorines.
Reactivity Profile
Acidic salts, such as Zirconium oxychloride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Health Hazard
Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.
Flammability and Explosibility
Not classified
Safety Profile
Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Cl-. Used as an antiperspirant. See also ZIRCONIUM COMPOUNDS and CHLORIDES.
Purification Methods
Crystallise it repeatedly from 8M HCl to give ZrOCl2.8H2O (see below). On drying, ZrOCl2.6H2O, m 150o, is formed. The product is not free from hafnium. [Blumenthal J Chem Ed 39 607 1962.]
Zirconium oxychloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Zirconium oxychloride manufacturers
- Product
- Zirconium oxychloride 7699-43-6
- Price
- US $100.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-04-28
- Product
- Zirconium oxychloride 7699-43-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2024-09-25
- Product
- Zirconium oxychloride 7699-43-6
- Price
- US $25.00-18.00/kg
- Min. Order
- 1kg
- Purity
- 99.9%
- Supply Ability
- 50000tons
- Release date
- 2024-04-10