Zirconium oxychloride

ChemicalBook > CAS DataBase List > Zirconium oxychloride

Zirconium oxychloride

Physical Properties Uses Preparation Toxicity

Product Name: Zirconium oxychloride
CAS No.: 7699-43-6
Chemical Name: Zirconium oxychloride
Synonyms: ZROCL2;ZIRCONIUM CHLORIDE;ZIRCONYL CHLORIDE;ZIRCONIUM DICHLORIDE OXIDE;nci-c60811;chlorozirconyl;JACS-7699-43-6;Dichlorooxozirconium;dichlorooxo-zirconiu;Zirconium oxychlorid
CBNumber: CB6470074
Molecular Formula: Cl2OZr
Formula Weight: 178.13
MOL File: 7699-43-6.mol

Less

Zirconium oxychloride Property

Melting point:: −15 °C
Density: 1.344 g/mL at 25 °C
solubility: soluble in H2O, ethanol
form: Liquid
color: Clear colorless
Merck: 13,10237
Stability:: Stable. Incompatible with strong oxidizing agents, water, moisture, alkali metals.
CAS DataBase Reference: 7699-43-6(CAS DataBase Reference)
EPA Substance Registry System: Zirconium, dichlorooxo- (7699-43-6)

Less

Safety

Hazard Codes: C,Xn
Risk Statements: 23-34-37-20/21/22-36/38
Safety Statements: 26-36-45-36/37/39-36/37
RIDADR: UN 1789
WGK Germany: 1
HazardClass: 8
PackingGroup: III
Hazardous Substances Data: 7699-43-6(Hazardous Substances Data)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P234Keep only in original container.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 464198
Product name: Zirconyl chloride solution
Purity: 30% in hydrochloric acid
Packaging: 250ml
Price: $263
Updated: 2023/06/20

American Custom Chemicals Corporation

Product number: ING0010511
Product name: ZIRCONIUM OXYCHLORIDE
Purity: 95.00%
Packaging: 10G
Price: $1097.25
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0010511
Product name: ZIRCONIUM OXYCHLORIDE
Purity: 95.00%
Packaging: 50G
Price: $2512.13
Updated: 2021/12/16

Aaron Chemicals

Product number: AR005FXR
Product name: Zirconium,dichlorooxo-
Purity: 36%
Packaging: 25g
Price: $13
Updated: 2021/12/16

Aaron Chemicals

Product number: AR005FXR
Product name: Zirconium,dichlorooxo-
Purity: 36%
Packaging: 100g
Price: $32
Updated: 2021/12/16

Less

Zirconium oxychloride Chemical Properties,Usage,Production

Physical Properties

The octahydrate is a white silky solid; tetragonal crystals consisting of tetramers; effloresces; refractive index 1.552; loses six water molecules at 150°C; becomes anhydrous at 210°C; decomposes at 400°C; soluble in water; aqueous solution acidic; also soluble in alcohol and ether; slightly soluble in hydrochloric acid.

Uses

Zirconyl chloride is used to make pigment toners and improve properties of color lakes of acid and basic dyes. Also, it is used to prepare body deodorants and antiperspirant, water repellant, dye precipitant, catalysts, and many zirconium compounds.

Preparation

The compound is prepared by dissolving zirconium tetrachloride, ZrCl4, or sodium zirconate, Na4ZrO4, in hydrochloric acid solution followed by evaporation to obtain crystals of octahydrate.
Also, the compound can be prepared by reacting zirconium tetrachloride with chlorine oxide:
ZrCl4 + Cl2O → ZrOCl2 + 2Cl2

Toxicity

Moderately toxic by ingestion, intraperitoneal and subcutaneous routes.
LD50 (intraperitioneal) (rat): 400mg/kg

Chemical Properties

Zirconium oxychloride exists as white silky crystals, soluble in water and alcohol. With water, the octahydrate is formed as tetragonal white needles. It is extremely hygroscopic and decomposes to zirconium tetrachloride (ZrCl4) and zirconium oxide (ZrO2) at 250 C. It is also formed as the octahydrate [13520-92-8] as white, tetrahedral crystals that are very soluble in water, ethyl alcohol, ether, and methanol, among others, but only slightly soluble in hydrochloric acid. When heated to decomposition, it emits toxic fumes of hydrogen chloride.

Uses

Building block for a new series of mixed zirconium phosphonates which may have uses in catalysis, ion exchange or photophysics.

Uses

Textile, cosmetic and grease additive, antiperspirant, water repellents, chemical reagent, zirconium salts, in lakes and toners of acidic and basic dyes, oil-field acidizing aid.

Definition

ChEBI: Zirconyl chloride is a zirconium coordination entity consisting of zirconium(IV) bound to oxygen via a double bond and to two chlorines.

Reactivity Profile

Acidic salts, such as Zirconium oxychloride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.

Flammability and Explosibility

Not classified

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Cl-. Used as an antiperspirant. See also ZIRCONIUM COMPOUNDS and CHLORIDES.

Purification Methods

Crystallise it repeatedly from 8M HCl to give ZrOCl2.8H2O (see below). On drying, ZrOCl2.6H2O, m 150o, is formed. The product is not free from hafnium. [Blumenthal J Chem Ed 39 607 1962.]

Zirconium oxychloride Preparation Products And Raw materials

Raw materials

Zirconyl chloride octahydrate

Preparation Products

Zirconium sulfate tetrahydrate Zirconium dioxide Zirconium acetate Zirconium dicarbonate

Less

Zirconium oxychloride Suppliers

Australia 1 China 170 Europe 2 France 1 Germany 2 India 10 Slovakia 1 Switzerland 1 United Kingdom 2 United States 23 Global 213

Jinan Wald Chemical Co., Ltd.

Tel: 0531-88773586 13210588999
Fax: 053188773586
Email: 304264064@qq.com
Country: China
ProdList: 193
Advantage: 58

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8415
Advantage: 55

Secco work (Beijing) chemical technology co., LTD

Tel: 0566-8928158
Fax: 010-69755668
Email: 343367102@QQ.COM
Country: China
ProdList: 360
Advantage: 54

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18738
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Country: China
ProdList: 2930
Advantage: 58

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 16166
Advantage: 55

SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.

Tel: 021-69106960 13701823733
Fax: 021-69106780
Email: 13701823733@163.com
Country: China
ProdList: 4767
Advantage: 60

Beijing Xinsavi Chemical Technology Co., Ltd.

Tel: 010-56218822 13717722232
Fax: 010-56218800
Email: xinsavichem@163.com
Country: China
ProdList: 3201
Advantage: 56

Shanghai Kaisai Chemical Co., Ltd

Tel: 021-33516722 13701817765
Fax: 021-33516776
Email: kaisaichem@163.com
Country: China
ProdList: 4741
Advantage: 58

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 13096311329 028-88469284 616445927
Fax: 028-88469284
Email: 616445927@qq.com
Country: China
ProdList: 2874
Advantage: 50

Beijing HuaYangZhicheng Technology Co., Ltd.

Tel: 13716033033
Fax: 010-56276266
Email: hanchochem@163.com
Country: China
ProdList: 2960
Advantage: 50

Shanghai Rolead Chemical Technology Co., Ltd.

Tel: 021-69992220 13701886816
Fax: 021-69992237
Email: roleadchem@163.com
Country: China
ProdList: 4749
Advantage: 50

Hubei Jusheng Technology Co.,Ltd

Tel: 027-59599241 18871490274
Fax: 027-59599241
Email: 1400878000@qq.com
Country: China
ProdList: 9958
Advantage: 58

Chizhou Kailong Import and Export Trade Co., Ltd.

Tel
Fax: -
Email: xg01_gj@163.com
Country: China
ProdList: 9484
Advantage: 50

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 551-65418679 15837135945
Fax: 0551-65418697
Email: info@tnjchem.com
Country: China
ProdList: 1889
Advantage: 62

Chengdu JingXin Technology Co., Ltd.

Tel: 028-85005297 13980656781
Fax: 028-85005529
Email: jingxin73730@163.com
Country: China
ProdList: 3280
Advantage: 50

Nanjing Vital Chemical Co., Ltd.

Tel: 025-87193546 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 9021
Advantage: 60

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20806
Advantage: 60

WG reagent

Tel: 13391486464
Fax: QQ:14748090
Email: samwjf@163.com
Country: China
ProdList: 3086
Advantage: 55

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-0371-55629727 13323845623
Fax: 037155629727
Email: 2885676761@qq.com
Country: China
ProdList: 10011
Advantage: 58

Shanghai Orgchem Co.,Ltd.

Tel: +86-21-5877 1921
Fax: +86-21-5877 1925
Email: info@chemofchina.com
Country: China
ProdList: 9653
Advantage: 55

JinJin Le Chemical Co., Ltd

Tel: 10106090
Email: jjlchem2@163.com
Country: China
ProdList: 9981
Advantage: 58

Aikon International Limited

Tel: 025-66028182 18112977050
Fax: (3)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 15818
Advantage: 58

Rhawn Reagent

Tel: 400-400-1332688 18019345275
Fax: 400-133-2688
Email: amy@rhawn.cn
Country: China
ProdList: 15497
Advantage: 58

Shanghai ChuCheng Trade Co., Ltd.

Tel: 021-5983532 15201998618
Fax: 021-59833275
Email: 3002724020@qq.com
Country: China
ProdList: 4616
Advantage: 58

Hubei xin embellish DE chemical co., LTD

Tel: 027-51837617 15871472056
Fax: 027-51837617
Email: 1659622278@qq.com
Country: China
ProdList: 417
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2815688 13927872512
Fax: 0751-8963795
Email: 3007421951@qq.com
Country: China
ProdList: 10058
Advantage: 58

Beijing Minruida Technology Co., Ltd.

Tel: 010-82387566 18001021521;
Fax: 82387566-801
Email: sales@mreda.com.cn
Country: China
ProdList: 10789
Advantage: 58

Shanghai bike new material technology co., LTD

Tel: 021-34790086 17317635738
Fax: 021-34790236
Email: 17317635738@163.com
Country: China
ProdList: 490
Advantage: 58

ANHUI WITOP BIOTECH CO., LTD

Tel: +8615255079626
Email: eric@witopchemical.com
Country: China
ProdList: 23541
Advantage: 58

Hebei Mojin Biotechnology Co., Ltd

Tel: +86 13288715578 +8613288715578
Email: sales@hbmojin.com
Country: China
ProdList: 12837
Advantage: 58

Zhengzhou Alfa Chemical Co.,Ltd

Tel: +8618530059196
Email: sale04@alfachem.cn
Country: China
ProdList: 13502
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418671 +8618949823763
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34553
Advantage: 58

Shandong Zhishang New Material Co., Ltd.

Tel: +8617653113209
Email: sales002@sdzschem.com
Country: China
ProdList: 3049
Advantage: 58

Hebei Zhanyao Biotechnology Co. Ltd

Tel: 15369953316 +8615369953316
Email: admin@zhanyaobio.com
Country: China
ProdList: 2123
Advantage: 58

Zhuoer Chemical Co., Ltd

Tel: 02120970332; +8613524231522
Fax: +86-21-58816016
Email: sales@zhuoerchem.com
Country: China
ProdList: 2904
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52849
Advantage: 58

Hebei Binshare New Material Co. Ltd

Tel: +8618633865755
Email: china01@hbbinshare.com
Country: CHINA
ProdList: 955
Advantage: 58

SIMAGCHEM CORP

Tel: +86-13806087780
Email: sale@simagchem.com
Country: China
ProdList: 17365
Advantage: 58

Henan Weituxi Chemical Technology Co., Ltd.

Tel: 0371-63284658 18135795563
Fax: QQ:2885349392
Email: 2885349392@qq.com
Country: China
ProdList: 10077
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23912
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28172
Advantage: 58

Jining Tianyi New Material Co., Ltd.

Tel: 15563776673
Fax: 0537-2968388
Email: 2099828473@qq.com
Country: China
ProdList: 103
Advantage: 58

Hebei Weibang Biotechnology Co., Ltd

Tel: +8615531157085
Fax: whatapp+8619930503282
Email: abby@weibangbio.com
Country: China
ProdList: 8817
Advantage: 58

Hubei xin bonus chemical co. LTD

Tel: 86-13657291602
Fax: 027-59338440
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 22963
Advantage: 58

Shandong chuangyingchemical Co., Ltd.

Tel: 18853181302
Email: sale@chuangyingchem.com
Country: CHINA
ProdList: 5906
Advantage: 58

Wuhan xinyangruihe Chemical Technology Co., Ltd.

Tel: 153-07155313 15307155313
Fax: QQ：2274366233
Email: 2274366233@qq.com
Country: China
ProdList: 5084
Advantage: 58

Less

View Lastest Price from Zirconium oxychloride manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Zirconium oxychloride 7699-43-6
Price: US $100.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-04-28

Hebei Mojin Biotechnology Co.,Ltd

Product: Zirconium oxychloride 7699-43-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-09-25

Wuhan Boyuan Import & Export Co., LTD

Product: Zirconium oxychloride 7699-43-6
Price: US $25.00-18.00/kg
Min. Order: 1kg
Purity: 99.9%
Supply Ability: 50000tons
Release date: 2024-04-10

7699-43-6, Zirconium oxychlorideRelated Search:

Boron oxide Benzyl chloride Zinc oxide Cobalt chloride Zirconium tetrachloride Choline chloride Zirconium dioxide Acetyl chloride Calcium chloride ETHYLENE OXIDE Sodium chloride Zirconium sulphate Ammonium chloride Polyvinyl chloride Potassium chloride Zirconyl chloride octahydrate COPPER IRON OXIDE NANOPOWDER 98.5% Yttrium oxide Zirconyl Chloride

ZIRCONIUM DICHLORIDE OXIDE

ZIRCONIUM CHLORIDE

ZIRCONYL CHLORIDE

ZIRCONIUM OXYCHLORIDE

ZIRCONIUM ICP STANDARD

ZROCL2

basiczirconiumchloride

chlorozirconyl

Dichlorooxozirconium

Zirconyl chloride solution

ZIRCONYL CHLORIDE, 30% SOLUTION IN HYDRO -CHLORIC ACID

Zirconium, dichlorooxo-

ZIRCONYLCHLORIDE20%SOLUTION

Zirconiumdichloridoxid

JACS-7699-43-6

Oxygen zirconium chloride

dichlorooxo-zirconiu

nci-c60811

zirconiumchlorideoxide

zirconiumchlorideoxide(zrcl2o)

zirconiumoxidechloride(zrocl2)

zirconiumoxydichloride

zirconylchloride(zrocl2)

Oxozirconium(IV) dichloride

Zirconium(IV) oxidedichloride

Zirconium oxychlorid

Zirconium oxide chloride

Zirconyl chloride solution 30% in hydrochloric acid

Zirconium Oxychloride Series (ZOC)

Zirconium oxide dichloride

Oxozirconium(IV) chloride

Zirconium chloride [eight waters

Zirconium Oxychloride Solution

Zirconia oxychloride

7699-43-6

ZrCl2O

Zirconium Salts

Solvent

Metal and Ceramic Science

Salts

Inorganics

bc0001