Physical Properties Uses Preparation Toxicity
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Zirconium oxychloride

Physical Properties Uses Preparation Toxicity
Product Name
Zirconium oxychloride
CAS No.
7699-43-6
Chemical Name
Zirconium oxychloride
Synonyms
ZROCL2;ZIRCONIUM CHLORIDE;ZIRCONYL CHLORIDE;ZIRCONIUM DICHLORIDE OXIDE;nci-c60811;chlorozirconyl;JACS-7699-43-6;Dichlorooxozirconium;dichlorooxo-zirconiu;Zirconium oxychlorid
CBNumber
CB6470074
Molecular Formula
Cl2OZr
Formula Weight
178.13
MOL File
7699-43-6.mol
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Zirconium oxychloride Property

Melting point:
−15 °C
Density 
1.344 g/mL at 25 °C
solubility 
soluble in H2O, ethanol
form 
Liquid
color 
Clear colorless
Merck 
13,10237
Stability:
Stable. Incompatible with strong oxidizing agents, water, moisture, alkali metals.
CAS DataBase Reference
7699-43-6(CAS DataBase Reference)
EPA Substance Registry System
Zirconium, dichlorooxo- (7699-43-6)
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Safety

Hazard Codes 
C,Xn
Risk Statements 
23-34-37-20/21/22-36/38
Safety Statements 
26-36-45-36/37/39-36/37
RIDADR 
UN 1789
WGK Germany 
1
HazardClass 
8
PackingGroup 
III
Hazardous Substances Data
7699-43-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P234Keep only in original container.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
464198
Product name
Zirconyl chloride solution
Purity
30% in hydrochloric acid
Packaging
250ml
Price
$263
Updated
2023/06/20
American Custom Chemicals Corporation
Product number
ING0010511
Product name
ZIRCONIUM OXYCHLORIDE
Purity
95.00%
Packaging
10G
Price
$1097.25
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0010511
Product name
ZIRCONIUM OXYCHLORIDE
Purity
95.00%
Packaging
50G
Price
$2512.13
Updated
2021/12/16
Aaron Chemicals
Product number
AR005FXR
Product name
Zirconium,dichlorooxo-
Purity
36%
Packaging
25g
Price
$13
Updated
2021/12/16
Aaron Chemicals
Product number
AR005FXR
Product name
Zirconium,dichlorooxo-
Purity
36%
Packaging
100g
Price
$32
Updated
2021/12/16
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Zirconium oxychloride Chemical Properties,Usage,Production

Physical Properties

The octahydrate is a white silky solid; tetragonal crystals consisting of tetramers; effloresces; refractive index 1.552; loses six water molecules at 150°C; becomes anhydrous at 210°C; decomposes at 400°C; soluble in water; aqueous solution acidic; also soluble in alcohol and ether; slightly soluble in hydrochloric acid.

Uses

Zirconyl chloride is used to make pigment toners and improve properties of color lakes of acid and basic dyes. Also, it is used to prepare body deodorants and antiperspirant, water repellant, dye precipitant, catalysts, and many zirconium compounds.

Preparation

The compound is prepared by dissolving zirconium tetrachloride, ZrCl4, or sodium zirconate, Na4ZrO4, in hydrochloric acid solution followed by evaporation to obtain crystals of octahydrate.
Also, the compound can be prepared by reacting zirconium tetrachloride with chlorine oxide:
ZrCl4 + Cl2O → ZrOCl2 + 2Cl2

Toxicity

Moderately toxic by ingestion, intraperitoneal and subcutaneous routes.
LD50 (intraperitioneal) (rat): 400mg/kg

Chemical Properties

Zirconium oxychloride exists as white silky crystals, soluble in water and alcohol. With water, the octahydrate is formed as tetragonal white needles. It is extremely hygroscopic and decomposes to zirconium tetrachloride (ZrCl4) and zirconium oxide (ZrO2) at 250 C. It is also formed as the octahydrate [13520-92-8] as white, tetrahedral crystals that are very soluble in water, ethyl alcohol, ether, and methanol, among others, but only slightly soluble in hydrochloric acid. When heated to decomposition, it emits toxic fumes of hydrogen chloride.

Uses

Building block for a new series of mixed zirconium phosphonates which may have uses in catalysis, ion exchange or photophysics.

Uses

Textile, cosmetic and grease additive, antiperspirant, water repellents, chemical reagent, zirconium salts, in lakes and toners of acidic and basic dyes, oil-field acidizing aid.

Definition

ChEBI: Zirconyl chloride is a zirconium coordination entity consisting of zirconium(IV) bound to oxygen via a double bond and to two chlorines.

Reactivity Profile

Acidic salts, such as Zirconium oxychloride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.

Flammability and Explosibility

Not classified

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Cl-. Used as an antiperspirant. See also ZIRCONIUM COMPOUNDS and CHLORIDES.

Purification Methods

Crystallise it repeatedly from 8M HCl to give ZrOCl2.8H2O (see below). On drying, ZrOCl2.6H2O, m 150o, is formed. The product is not free from hafnium. [Blumenthal J Chem Ed 39 607 1962.]

Zirconium oxychloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Zirconium oxychloride Suppliers

Portail Substances Chimiques
Tel
--
Fax
--
Email
webmestre-substances@ineris.fr
Country
France
ProdList
6024
Advantage
58
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View Lastest Price from Zirconium oxychloride manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Zirconium oxychloride 7699-43-6
Price
US $100.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-04-28
Hebei Mojin Biotechnology Co.,Ltd
Product
Zirconium oxychloride 7699-43-6
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-09-25
Wuhan Boyuan Import & Export Co., LTD
Product
Zirconium oxychloride 7699-43-6
Price
US $25.00-18.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
50000tons
Release date
2024-04-10

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