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BRUCINE

Product Name
BRUCINE
CAS No.
5892-11-5
Chemical Name
BRUCINE
Synonyms
BRUCINE ALKALOID;BURCINETETRAHYDRATE;BRUCINE TETRAHYDRATE;BRUCINE HYDRATE, TECH.;2,3-DIMETHOXYSTRYCHNIDIN-10-ONE;STRYCHNIDIN-10-ONE,2,3-DIMETHOXY;Paper Chemicals Wet Strength Agent 12.5%;Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate;Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%
CBNumber
CB4208446
Molecular Formula
C23H26N2O4
Formula Weight
394.46
MOL File
5892-11-5.mol
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BRUCINE Property

Melting point:
175-178 °C (dec.)(lit.)
optical activity
[α]20/D 67°, c = 1.3 in ethanol
Water Solubility 
Soluble in methanol. Partially soluble Miscible with water.
CAS DataBase Reference
5892-11-5(CAS DataBase Reference)
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Safety

Hazard Codes 
T+
Risk Statements 
26/28-52/53-36/37/38-26/27/28
Safety Statements 
13-45-61-36/37-28
RIDADR 
UN 1570 6.1/PG 1
WGK Germany 
3
RTECS 
EH8925000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
367869
Product name
Brucine hydrate
Purity
technical grade
Packaging
100g
Price
$316.2
Updated
2024/03/01
Alfa Aesar
Product number
A16251
Product name
Brucine dihydrate, 98%
Packaging
10g
Price
$37.65
Updated
2024/03/01
Alfa Aesar
Product number
A16251
Product name
Brucine dihydrate, 98%
Packaging
50g
Price
$103.65
Updated
2024/03/01
Biosynth Carbosynth
Product number
FB31436
Product name
Brucine dihydrate
Packaging
100g
Price
$800
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB31436
Product name
Brucine dihydrate
Packaging
250g
Price
$1000
Updated
2021/12/16
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BRUCINE Chemical Properties,Usage,Production

Uses

Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids.

Purification Methods

Crystallise brucine once from water or aqueous Me2CO (as the tetrahydrate), then suspend it in CHCl3 and shake with anhydrous Na2SO4 (to dehydrate the brucine, which then dissolves). Precipitate it by pouring the solution into a large bulk of dry pet ether (b 40-60o), filter and heat to 120o in a high vacuum [Turner J Chem Soc 842 1951]. The tetrahydrate crystallises from a mixture of EtOH and H2O as colourless elongated needles [Eeles Acta Cryst 6 809 1953, Beilstein 27 III/IV 7875.] VERY POISONOUS

BRUCINE Preparation Products And Raw materials

Raw materials

Preparation Products

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BRUCINE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
Hubei xin bonus chemical co. LTD
Tel
86-13657291602
Fax
027-59338440
Email
linda@hubeijusheng.com
Country
CHINA
ProdList
22968
Advantage
58
Hubei Shishun Biotechnology Co. Ltd
Tel
027-59223025 15107168801
Fax
027-59223025
Email
1718480011@qq.com
Country
China
ProdList
9994
Advantage
58
Hubei Wande Chemical Co., Ltd
Tel
027-59210159 15377098680
Fax
027-59210159
Email
1148280011@qq.com
Country
China
ProdList
9994
Advantage
58
Shaanxi Dideu Medichem Co. Ltd
Tel
029-81124267 15229202216
Fax
029-88380327
Email
1073@dideu.com
Country
China
ProdList
10011
Advantage
58
ZHEJIANG JIUZHOU CHEM CO., LTD
Tel
+86-0576225566889 +86-13454675544
Email
admin@jiuzhou-chem.com;jamie@jiuzhou-chem.com;alice@jiuzhou-chem.com
Country
China
ProdList
20000
Advantage
58

5892-11-5, BRUCINERelated Search:


  • STRYCHNIDIN-10-ONE,2,3-DIMETHOXY
  • 2,3-DIMETHOXYSTRYCHNIDIN-10-ONE
  • BRUCINE HYDRATE, TECH.
  • Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate
  • BURCINETETRAHYDRATE
  • BRUCINE TETRAHYDRATE
  • BRUCINE ALKALOID
  • Paper Chemicals Wet Strength Agent 12.5%
  • Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%
  • 5892-11-5
  • C23H26N2O44H2O
  • Alkaloids
  • for Resolution of Acids
  • Optical Resolution
  • Indole Alkaloids
  • Asymmetric Synthesis
  • Chiral Resolution Reagents
  • Chiral Resolving Reagents
  • Chiral Resolving ReagentsAsymmetric Synthesis
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Chiral Resolution Reagents
  • Complex Molecules