BRUCINE

Product Name: BRUCINE
CAS No.: 5892-11-5
Chemical Name: BRUCINE
Synonyms: BRUCINE ALKALOID;BURCINETETRAHYDRATE;BRUCINE TETRAHYDRATE;BRUCINE HYDRATE, TECH.;2,3-DIMETHOXYSTRYCHNIDIN-10-ONE;STRYCHNIDIN-10-ONE,2,3-DIMETHOXY;Paper Chemicals Wet Strength Agent 12.5%;Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate;Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%
CBNumber: CB4208446
Molecular Formula: C23H26N2O4
Formula Weight: 394.46
MOL File: 5892-11-5.mol

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BRUCINE Property

Melting point:: 175-178 °C (dec.)(lit.)
optical activity: [α]20/D 67°, c = 1.3 in ethanol
Water Solubility: Soluble in methanol. Partially soluble Miscible with water.
CAS DataBase Reference: 5892-11-5(CAS DataBase Reference)

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Safety

Hazard Codes: T+
Risk Statements: 26/28-52/53-36/37/38-26/27/28
Safety Statements: 13-45-61-36/37-28
RIDADR: UN 1570 6.1/PG 1
WGK Germany: 3
RTECS: EH8925000
TSCA: Yes
HazardClass: 6.1
PackingGroup: I

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H412Harmful to aquatic life with long lasting effects
Precautionary statements: P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 367869
Product name: Brucine hydrate
Purity: technical grade
Packaging: 100g
Price: $316.2
Updated: 2024/03/01

Alfa Aesar

Product number: A16251
Product name: Brucine dihydrate, 98%
Packaging: 10g
Price: $37.65
Updated: 2024/03/01

Alfa Aesar

Product number: A16251
Product name: Brucine dihydrate, 98%
Packaging: 50g
Price: $103.65
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FB31436
Product name: Brucine dihydrate
Packaging: 100g
Price: $800
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB31436
Product name: Brucine dihydrate
Packaging: 250g
Price: $1000
Updated: 2021/12/16

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BRUCINE Chemical Properties,Usage,Production

Uses

Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids.

Purification Methods

Crystallise brucine once from water or aqueous Me2CO (as the tetrahydrate), then suspend it in CHCl3 and shake with anhydrous Na2SO4 (to dehydrate the brucine, which then dissolves). Precipitate it by pouring the solution into a large bulk of dry pet ether (b 40-60o), filter and heat to 120o in a high vacuum [Turner J Chem Soc 842 1951]. The tetrahydrate crystallises from a mixture of EtOH and H2O as colourless elongated needles [Eeles Acta Cryst 6 809 1953, Beilstein 27 III/IV 7875.] VERY POISONOUS

BRUCINE Preparation Products And Raw materials

Raw materials

Preparation Products

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BRUCINE Suppliers

China 16 Germany 2 India 2 Japan 3 Switzerland 1 United Kingdom 4 United States 15 Global 43

Riedel-de Haen AG

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United States Biological

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HONEST JOY HOLDINGS LIMITED

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TimTec Corporation

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www.vwrsp.com

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Sciencelab.com, Inc.

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Pfaltz & Bauer, Inc.

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City Chemicals Corporation

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ChemPacific Corporation

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ChromaDex

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MP Biomedicals, Inc.

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5892-11-5, BRUCINERelated Search:

STRYCHNIDIN-10-ONE,2,3-DIMETHOXY

2,3-DIMETHOXYSTRYCHNIDIN-10-ONE

BRUCINE HYDRATE, TECH.

Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate

BURCINETETRAHYDRATE

BRUCINE TETRAHYDRATE

BRUCINE ALKALOID

Paper Chemicals Wet Strength Agent 12.5%

Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%

5892-11-5

C23H26N2O44H2O

Alkaloids

for Resolution of Acids

Optical Resolution

Indole Alkaloids

Asymmetric Synthesis

Chiral Resolution Reagents

Chiral Resolving Reagents

Chiral Resolving ReagentsAsymmetric Synthesis

Asymmetric Synthesis

Chiral Building Blocks

Chiral Resolution Reagents

Complex Molecules