meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

Uses

Product Name: meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
CAS No.: 97739-46-3
Chemical Name: meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
Synonyms: meCgPPh;1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamante;1,3,5,7-TetramethyL;-6-phenyL;-2,4,8-trioxa-6-phosphaadamantane;1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantan;1,3,5,7-TETRAMETHYL-6-PHENYL-2,4,8-TRIOXA-6-PHOSPHADAMANTANE;1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane;1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane;1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane
CBNumber: CB42099477
Molecular Formula: C16H21O3P
Formula Weight: 292.31
MOL File: 97739-46-3.mol

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meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Property

Melting point:: 106-111 °C
Boiling point:: 363.4±42.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: white
Sensitive: air sensitive, moisture sensitive
InChI: InChI=1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3
InChIKey: AVVSJWUWBATQBX-UHFFFAOYSA-N
SMILES: C12(C)CC3(C)OC(C)(CC(C)(O3)O1)P2C1=CC=CC=C1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-37
WGK Germany: 3
TSCA: No

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 695459
Product name: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane
Purity: 97%
Packaging: 500mg
Price: $86.1
Updated: 2025/07/31

Sigma-Aldrich

Product number: 695459
Product name: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane
Purity: 97%
Packaging: 2g
Price: $316.48
Updated: 2025/07/31

TCI Chemical

Product number: T4047
Product name: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane
Packaging: 200MG
Price: $85
Updated: 2025/07/31

TCI Chemical

Product number: T4047
Product name: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane
Packaging: 1G
Price: $254
Updated: 2025/07/31

Strem Chemicals

Product number: 15-5355
Product name: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh
Packaging: 500mg
Price: $100
Updated: 2024/03/01

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meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Chemical Properties,Usage,Production

Uses

A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts.

Uses

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:

As a ligand to synthesize complexes for hydroformylation catalysis.
To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Preparation Products And Raw materials

Raw materials

Preparation Products

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meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Suppliers

China 60 Switzerland 1 United States 4 Global 65

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View Lastest Price from meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane manufacturers

Shanghai Wish Pharma Co., Ltd

Product: meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane 97739-46-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: Minimum 98%
Supply Ability: 80kg
Release date: 2025-11-06

Henan Fengda Chemical Co., Ltd

Product: meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane 97739-46-3
Price: US $101.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-28

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 97% 97739-46-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

97739-46-3, meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decaneRelated Search:

Methyl methacrylate meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane 2,6-dimethyl-1,3-dioxan-4-ol BIS(HYDROXYMETHYL)PHENYLPHOSPHINE

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamante

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1,3,5,7-TetraMethyl-8-phenyl-2,4,6-trioxa-8-phosphaadaMantane, 99% MeCgPPh

1,3,5,7-TetraMethyl-2,4,8-trioxa-6-phenyl-6-phosphaadaMantane, 98% (MeCgPPh)

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meCgPPh

1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane

1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane, (MeCgPPh)

1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane, 99%

1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantan

1,3,5,7-TetramethyL

-2,4,8-trioxa-6-phosphaadamantane

2,4,6-Trioxa-8-phosphatricyclo[3.3.1.13,7]decane, 1,3,5,7-tetramethyl-8-phenyl-

-6-phenyL

1,3,5,7-TETRAMETHYL-6-PHENYL-2,4,8-TRIOXA-6-PHOSPHADAMANTANE

1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantan...

(1R,3S,5S,7R)-1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.1,3,7]decane

97739-46-3

C16H21O3P

organophosphine ligand

Achiral Phosphine

Aryl Phosphine