Uses
ChemicalBook > CAS DataBase List > meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

Uses
Product Name
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
CAS No.
97739-46-3
Chemical Name
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
Synonyms
meCgPPh;1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamante;1,3,5,7-TetramethyL;-6-phenyL;-2,4,8-trioxa-6-phosphaadamantane;1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantan;1,3,5,7-TETRAMETHYL-6-PHENYL-2,4,8-TRIOXA-6-PHOSPHADAMANTANE;1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane;1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane;1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantan...
CBNumber
CB42099477
Molecular Formula
C16H21O3P
Formula Weight
292.31
MOL File
97739-46-3.mol
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meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Property

Melting point:
106-111 °C
Boiling point:
363.4±42.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
white
Sensitive 
air sensitive, moisture sensitive
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-37
WGK Germany 
3
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
695459
Product name
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane
Purity
97%
Packaging
500mg
Price
$119
Updated
2024/03/01
Sigma-Aldrich
Product number
695459
Product name
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane
Purity
97%
Packaging
2g
Price
$334
Updated
2024/03/01
Strem Chemicals
Product number
15-5355
Product name
1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh
Packaging
500mg
Price
$100
Updated
2024/03/01
Strem Chemicals
Product number
15-5355
Product name
1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh
Packaging
2g
Price
$299
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OPC0001005
Product name
1,3,5,7-TETRAMETHYL-6-PHENYL-2,4,8-TRIOXA-6-PHOSPHAADAMANTANE
Purity
95.00%
Packaging
5MG
Price
$496.8
Updated
2021/12/16
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meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Chemical Properties,Usage,Production

Uses

A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts.

Uses

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:

  • As a ligand to synthesize complexes for hydroformylation catalysis.
  • To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane manufacturers

Henan Fengda Chemical Co., Ltd
Product
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane 97739-46-3
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Zhuozhou Wenxi import and Export Co., Ltd
Product
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 97% 97739-46-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

97739-46-3, meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decaneRelated Search:


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  • meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
  • 1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane,99%
  • 1,3,5,7-TetraMethyl-8-phenyl-2,4,6-trioxa-8-phosphaadaMantane, 99% MeCgPPh
  • 1,3,5,7-TetraMethyl-2,4,8-trioxa-6-phenyl-6-phosphaadaMantane, 98% (MeCgPPh)
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  • meCgPPh
  • 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane
  • 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane, (MeCgPPh)
  • 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane
  • 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane, 99%
  • 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantan
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  • 2,4,6-Trioxa-8-phosphatricyclo[3.3.1.13,7]decane, 1,3,5,7-tetramethyl-8-phenyl-
  • -6-phenyL
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  • 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantan...
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  • 97739-46-3
  • C16H21O3P
  • organophosphine ligand
  • Achiral Phosphine
  • Aryl Phosphine