Chloro(1,5-cyclooctadiene)iridium(I) dimer

ChemicalBook > CAS DataBase List > Chloro(1,5-cyclooctadiene)iridium(I) dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer

Reactions

Product Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer
CAS No.: 12112-67-3
Chemical Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer
Synonyms: BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE;[Ir(1,5-cod)Cl]2;IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER;Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2);Chloro(1;IRIDIUM COD CHLORIDE;Palladium pivalate(l);Chloro(1,5-cyclooctadiene;ooctadiene)diiridium(I) dichL;IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
CBNumber: CB4212508
Molecular Formula: C16H24Cl2Ir2
Formula Weight: 671.7
MOL File: 12112-67-3.mol

Less

Chloro(1,5-cyclooctadiene)iridium(I) dimer Property

Melting point:: 205 °C (dec.)(lit.)
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Powder
color: red to orange
Water Solubility: insoluble
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
InChIKey: XHOSESNLNGITPM-XRGHXPOKSA-L

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
F: 10
TSCA: No
HS Code: 28439000

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 683094
Product name: Bis(1,5-cyclooctadiene)diiridium(I) dichloride
Purity: 97%
Packaging: 500mg
Price: $164
Updated: 2024/03/01

Sigma-Aldrich

Product number: 683094
Product name: Bis(1,5-cyclooctadiene)diiridium(I) dichloride
Purity: 97%
Packaging: 2g
Price: $417
Updated: 2024/03/01

TCI Chemical

Product number: C1807
Product name: Chloro(1,5-cyclooctadiene)iridium(I) Dimer
Purity: >93.0%(T)
Packaging: 1g
Price: $581
Updated: 2024/03/01

TCI Chemical

Product number: C1807
Product name: Chloro(1,5-cyclooctadiene)iridium(I) Dimer
Purity: >93.0%(T)
Packaging: 250mg
Price: $224
Updated: 2024/03/01

Alfa Aesar

Product number: 012749
Product name: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
Packaging: 0.25g
Price: $105
Updated: 2023/06/20

Less

Chloro(1,5-cyclooctadiene)iridium(I) dimer Chemical Properties,Usage,Production

Reactions

1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.
2. Precursor to catalyst for enantioselective reduction of imines.
3. Precursor to catalyst for allylic alkylation.
4. Precursor to catalyst for allylic amination and etherification.
5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.
6. Ir-catalyzed addition of acid chlorides to terminal alkynes.
7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines.
8. Enantioselective [2+2] cycloaddition.
9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes.
10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates.
11. Transfer hydrogenative C-C coupling

Chemical Properties

red-orange solid

Uses

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

reaction suitability

core: iridium
reaction type: C-H Activation
reagent type: catalyst

Synthesis

A solution of 6 mL of 1,5-cyclooctadiene in 35 mL of ethanol and 20 mL of water is added to 2.0 g of IrCl3.3H2O in a round-bottomed flask. The mixture is refluxed under nitrogen for 24 h when an orange-red product precipitates from the solution. The mixture is cooled to rt, and Di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) (Chloro(1,5-cyclooctadiene)iridium(I) dimer) is collected by filtration, washed with cold methanol, and dried in vacuo at 25 °C for 8 h.

Chloro(1,5-cyclooctadiene)iridium(I) dimer Preparation Products And Raw materials

Raw materials

Hydrazinium hydroxide solution Hydroquinone Tetrahydrofuran Iridium(III) chloride hydrate 1,5-Cyclooctadiene Isopropyl alcohol

Preparation Products

Less

Chloro(1,5-cyclooctadiene)iridium(I) dimer Suppliers

Americas 1 Australia 1 Belgium 4 China 236 Europe 3 France 2 Germany 8 India 13 Japan 5 Singapore 1 South Korea 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 9 United States 51 Global 339

Shaanxi Rock New Materials Co., Ltd.

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com
Country: China
ProdList: 310
Advantage: 62

Sinocompound Catalysts Co., Ltd.

Tel: 0512-67216630 67216634
Fax: 0512-56316689
Email: sales@sinocompound.com
Country: China
ProdList: 280
Advantage: 64

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2309
Advantage: 58

Shanghai platinum raw metal material co., ltd.

Tel: 021-33360721 18601346310
Fax: 021-33360721
Email: mingbomail@163.com
Country: China
ProdList: 228
Advantage: 58

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 291
Advantage: 62

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12390
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9510
Advantage: 66

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 251
Advantage: 64

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11655
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9815
Advantage: 79

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 021-51613915-820 13611835272
Fax: 021 51613951
Email: mmwang@sunwaypharm.cn
Country: China
ProdList: 9734
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11707
Advantage: 57

Hangzhou Yuhao Chemical Technology Co., Ltd

Tel: 0571-82693216
Fax: +86-571-82880190
Email: info@yuhaochemical.com
Country: China
ProdList: 9387
Advantage: 52

Springchem New Material Technology Co.,Limited

Tel: +86-021-62885108 +8613917661608
Email: info@spring-chem.com
Country: China
ProdList: 2068
Advantage: 57

Wuhan Fortuna Chemical Co., Ltd

Tel: 027-59207852 13308628970
Fax: QQ3130921841
Email: buy@fortunachem.com
Country: China
ProdList: 2861
Advantage: 58

WuHan Taiyukaishang Chemical Co., Ltd.

Tel: 027-027-87680032 18963957250
Fax: 027-87680032 -8016
Email: taiyuchem@163.com
Country: China
ProdList: 108
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9478
Advantage: 58

Yurui (Shanghai) Chemical Co., Ltd.

Tel: 02150456736 18602143071
Fax: 021-50761379
Email: Jenny@riyngroup.com
Country: China
ProdList: 892
Advantage: 30

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

Shanghai Yolne Chemical Co., Ltd.

Tel: 021-62960152
Fax: 021-52212593
Email: 934678158@qq.com
Country: China
ProdList: 9899
Advantage: 55

Aloespharm Co., Ltd.

Tel: 021-20960837
Fax: 021-20960837
Email: market@aloespharm.com
Country: China
ProdList: 1302
Advantage: 55

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9978
Advantage: 55

Nanjing Pharmaluxury Co., Ltd.

Tel: 025-83726959 15851816062
Fax: 025-8666-0986
Email: goodsalejs@163.com
Country: China
ProdList: 128
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41462
Advantage: 60

Zhengzhou HongSheng Pharmaceutical Co., Ltd.

Tel: 0371-13526885213 15637198702
Fax: 0371-63709726
Email: xpkchem@163.com
Country: China
ProdList: 3980
Advantage: 58

Chengdu HuaXia Chemical Reagent Co. Ltd

Tel: 400-1166-196 13458535857
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 13350
Advantage: 58

Suzhou Laing Biological Technology Co., LTD

Tel: 0512-62968256 18550502935
Fax: 0512-62968256
Email: export@laingbiotec.com
Country: China
ProdList: 1114
Advantage: 58

Wuxi Zhongkun Biochemical Technology Co., Ltd.

Tel: 0510-85629785 18013409632
Fax: 051085625359
Email: sales@reading-chemicals.com
Country: China
ProdList: 15178
Advantage: 58

Finetech Industry Limited

Tel: 027-87465837 19945049750
Fax: 027-8777-2287
Email: sales@finetechnology-ind.com
Country: China
ProdList: 9648
Advantage: 58

Shanghai CanSpecsci Instrument Co., Ltd.

Tel: 400-6087598 15021221957
Fax: 4006087598-8012
Email: order@canspecsci.com
Country: China
ProdList: 2045
Advantage: 56

Credit-Chem Co., Ltd.

Tel: 400-821-5857 021-64326257
Fax: 021-64393586 QQ;2798200800
Email: credit-chem@foxmail.com
Country: China
ProdList: 5219
Advantage: 58

Shanghai YuLue Chemical Co., Ltd.

Tel: 021-60345187 13671753212
Fax: 021-34702061
Email: lzz841106@aliyun.com
Country: China
ProdList: 10274
Advantage: 55

Less

View Lastest Price from Chloro(1,5-cyclooctadiene)iridium(I) dimer manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer 12112-67-3
Price: US $0.00/G
Min. Order: 10G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-07

henan kanbei chemical co.,ltd

Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer 12112-67-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer 12112-67-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-11

12112-67-3, Chloro(1,5-cyclooctadiene)iridium(I) dimerRelated Search:

Iridium(III) chloride hydrate DILINOLEIC ACID Iridium 1,5-Cyclooctadiene POLYALUMINUM CHLORIDE POLYETHYLENE, CHLORINATED 1,3-CYCLOOCTADIENE Cobalt chloride Chloro(1,5-cyclooctadiene)rhodium(I) dimer BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 XPhos Pd G1 BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE

DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)]

DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM

CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER

CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER

IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER

IRIDIUM I CYCLOOCTADIENE CHLORIDE

IRIDIUM CHLORO-1,5-CYCLOOCTADIENE

IRIDIUM COD CHLORIDE

1,5-CYCLOOCTADIENE-IRIDIUM(I) CHLORIDE DIMER

chloro(1,5-cyclooctadiene)iridium(i)

BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE

BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC&

Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9%

Chloro(1,5-cyclooctadiene)iridium(I)dimere

di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium

Chloro-1,5-cyclooctadieneiridium(I)dimer,99%

CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR)

Chloro-(1,5-cyclooctadiene)-iridium dimer

Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%

Chloro(1,5-cyclooctadiene)iridium(I)dimer dec. 190

Chloro(1,5-cyclooctadiene)iridium(I) dimer ,98%

"Di-chloro bis(cycloocta-1,5-dienyl)iridium(I)"

Bis(1,5-cyclooctadiene)diiridium(I) dichloride,1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridiu

Chloro(1,5-cyclooctadiene)iridiuM(I) diMer 250MG

IridiuM, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-

Chloro(1,5-cyclooctadiene)iridiuM(I) diMer,98% [Ir(COD)Cl]2

IRIDIUM(I) CYCLOOCTADIENE CHLORIDE, diMer

Chloro(1,5-cyclooctadiene)iridium(Ⅰ) dimer

Chloro(1,5-cyclooctadiene)iridiuM(I) diMer,[Ir(COD)Cl]2

Bis(1,5-cyclooctadiene)diiridiuM(I) dichloride 97%

1,5-octadiene iridiuM chloride diMer

Dichloro(1,5-cyclooctadien)iridium(I) dimer

Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2)

Chloroiridium - cycloocta-1,5-diene (1:1)

[Ir(1,5-cod)Cl]2

5-cyclooctadiene)iridium(I) dimer

Chloro(1

Chloro(1,5-cyclooctadiene)iridium(I) Dimer &gt

ooctadiene)diiridium(I) dichL

Chloro(1,5-cyclooctadiene)iridium(I) dimer ISO 9001：2015 REACH

TIANFU CHEM Chloro(1,5-cyclooctadiene)iridium(I) dimer

Di( μ -chloro)bis(1,5-cyclooctadiene)diiridium(I)

Chloro-1,5-cyclooctadiene iridium(I) dimmer

Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium

Chloroiridium-cycloocta-1,5-diene

CHLORO(1,5-CYCLOOTADIENE)IRIDIUM(I) DIMER

Chloro(1,5-cyclooctadiene

Palladium pivalate(l)

12112-67-3

12112-67-2

C16H24Ir2Cl2

2C8H12IrCl2

IrClC8H122

C8H12IrCl2

IrCODCl2

C16H24Cl2Ir2

Iridium