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ChemicalBook > CAS DataBase List > CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

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Product Name
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
CAS No.
92390-26-6
Chemical Name
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
Synonyms
Cp*RuCl(cod);Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II);Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM;1,5-Cyclooctadiene, ruthenium complex;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
CBNumber
CB4405539
Molecular Formula
C18H27ClRu5*
Formula Weight
379.93
MOL File
92390-26-6.mol
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Property

Melting point:
143-147℃
storage temp. 
-20°C
color 
brown microxtls
Stability:
store cold
InChIKey
JBVMVFXUVNUNNG-ONEVTFJLSA-M
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Safety

Hazard Codes 
F
Risk Statements 
20/21/22-14/15
Safety Statements 
22-36/37/39-43
RIDADR 
UN 3395
WGK Germany 
3
TSCA 
No
HazardClass 
4.3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H261In contact with water releases flammable gas

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
667234
Product name
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Packaging
250mg
Price
$131
Updated
2024/03/01
Sigma-Aldrich
Product number
667234
Product name
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Packaging
1g
Price
$350
Updated
2024/03/01
Alfa Aesar
Product number
046803
Product name
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
Packaging
250mg
Price
$113.65
Updated
2024/03/01
Alfa Aesar
Product number
046803
Product name
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
Packaging
1g
Price
$394
Updated
2024/03/01
Strem Chemicals
Product number
44-0113
Product name
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%
Packaging
250mg
Price
$121
Updated
2024/03/01
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties,Usage,Production

Reactions

  1. Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
  2. Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
  3. Catalyst for ring closing enyne metathesis.
  4. Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
  5. Catalyst for hydrovinylation of ynamides with ethylene.
  6. Catalyst for C–H insertion reactions of carbenes. 

Uses

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

  • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
  • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
  • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
  • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
  • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Suppliers

China 112 Germany 2 Switzerland 1 United States 7 Global 122
Shanghai Incat Chemtech Co.,Ltd.
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China
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13275595566 15001012717
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View Lastest Price from CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

92390-26-6, CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)Related Search:

1,5-Cyclooctadiene Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro(1,5-cyclooctadiene)rhodium(I) dimer XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) SPhos Pd G2 Chloro(1,5-cyclooctadiene)iridium(I) dimer SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 XPhos Pd G1 Chloro(1,5-cyclooctadiene)methylpalladium(II) 97% Allylpalladium(II) Chloride Dimer CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) XantPhos-Pd-G2 cataCXium A-Pd-G2 Rubidium chloride

  • (1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride
  • Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%
  • Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
  • 1,5-Cyclooctadiene, ruthenium complex
  • Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium
  • Cp*RuCl(cod)
  • Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...
  • Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
  • Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM
  • Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM
  • CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&
  • CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
  • Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium(Ⅱ)
  • Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
  • Ruthenium, chloro[(1,?2,?5,?6-?η)?-?1,?5-?cyclooctadiene]?[(1,?2,?3,?4,?5-?η)?-?1,?2,?3,?4,?5-?pentamethyl-?2,?4-?cyclopentadien-?1-?yl]?-
  • 92390-26-6
  • C18H28ClRu
  • RuClC8H12C10H15
  • C18H27ClRu
  • Ru Catalysts
  • Catalysis and Inorganic Chemistry
  • Ru
  • organometallic complex