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ChemicalBook > CAS DataBase List > CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

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Product Name
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
CAS No.
92390-26-6
Chemical Name
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
Synonyms
Cp*RuCl(cod);Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II);Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM;1,5-Cyclooctadiene, ruthenium complex;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
CBNumber
CB4405539
Molecular Formula
C18H27ClRu5*
Formula Weight
379.93
MOL File
92390-26-6.mol
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Property

Melting point:
143-147℃
storage temp. 
-20°C
color 
brown microxtls
Stability:
store cold
InChI
InChI=1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChIKey
JBVMVFXUVNUNNG-ONEVTFJLSA-M
SMILES
[C]1(C)[C](C)[C]([C](C)[C]1C)C.C1CCC=CCCC=1.[Ru]Cl |c:13,17,^1:0,2,4,5,7|
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Safety

Hazard Codes 
F
Risk Statements 
20/21/22-14/15
Safety Statements 
22-36/37/39-43
RIDADR 
UN 3395
WGK Germany 
3
TSCA 
No
HazardClass 
4.3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H261In contact with water releases flammable gas

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
667234
Product name
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Packaging
250mg
Price
$124.2
Updated
2025/07/31
Sigma-Aldrich
Product number
667234
Product name
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Packaging
1g
Price
$332.12
Updated
2025/07/31
Strem Chemicals
Product number
44-0113
Product name
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%
Packaging
250mg
Price
$121
Updated
2024/03/01
Strem Chemicals
Product number
44-0113
Product name
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%
Packaging
1g
Price
$362
Updated
2024/03/01
TRC
Product number
C371378
Product name
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium
Packaging
250mg
Price
$125
Updated
2021/12/16
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties,Usage,Production

Reactions

  1. Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
  2. Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
  3. Catalyst for ring closing enyne metathesis.
  4. Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
  5. Catalyst for hydrovinylation of ynamides with ethylene.
  6. Catalyst for C–H insertion reactions of carbenes. 

Uses

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

  • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
  • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
  • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
  • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
  • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

reaction suitability

core: ruthenium
reagent type: catalyst

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Suppliers

China 124 Germany 2 Switzerland 1 United States 7 Global 134
Shanghai Incat Chemtech Co.,Ltd.
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China
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Shaanxi Rock New Materials Co., Ltd.
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0917-8888777, 3380777,18691786767; 15619786767
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China
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Panjin Greenchem Technology Co., Ltd.
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86-10-82849933
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956
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0573-85285100
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isenchem@163.com
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
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Nanjin Cynthia chemicals Technology Co.,Ltd
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0550-5618439 15951861180
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View Lastest Price from CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM 92390-26-6
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-07-29
Longyan Tianhua Biological Technology Co., Ltd
Product
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

92390-26-6, CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)Related Search:

1,5-Cyclooctadiene Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro(1,5-cyclooctadiene)rhodium(I) dimer XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) SPhos Pd G2 Chloro(1,5-cyclooctadiene)iridium(I) dimer SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 XPhos Pd G1 Chloro(1,5-cyclooctadiene)methylpalladium(II) 97% Allylpalladium(II) Chloride Dimer CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) cataCXium A-Pd-G2 XantPhos-Pd-G2 Rubidium chloride

  • (1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride
  • Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II),98%
  • Ruthenium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene][(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
  • 1,5-Cyclooctadiene, ruthenium complex
  • Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium
  • Cp*RuCl(cod)
  • Chloro(1，5-cyclooctadiene)(pentamethylcyclopent...
  • Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
  • Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM
  • Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM
  • CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&
  • CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
  • Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium(Ⅱ)
  • Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
  • Ruthenium, chloro[(1,?2,?5,?6-?η)?-?1,?5-?cyclooctadiene]?[(1,?2,?3,?4,?5-?η)?-?1,?2,?3,?4,?5-?pentamethyl-?2,?4-?cyclopentadien-?1-?yl]?-
  • chloro-[(1E,5Z)-cycloocta-1,5-dien-1-yl]ruthenium 1,2,3,4,5-pentamethylcyclopenta-1,3-diene
  • Chloro(pentamethylcyclopentadienyl)(1,5-cyclooctadiene)ruthenium(II)
  • 92390-26-6
  • C18H28ClRu
  • RuClC8H12C10H15
  • C18H27ClRu
  • Ru Catalysts
  • Catalysis and Inorganic Chemistry
  • Ru
  • organometallic complex