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ChemicalBook > CAS DataBase List > CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)

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Product Name
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
CAS No.
578743-87-0
Chemical Name
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
Synonyms
[(iPr)CuCl];Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I);idene]copper(I);oro[1,3-bis(2,6-diisopropyL;Chloro[1,3-bis(2,6-diisopropylphenyl)iMidazol-2-ylidene]copp;Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copp...;1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-chloro-copper;[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride;CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I);[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) chloride
CBNumber
CB3501669
Molecular Formula
C27H36ClCuN2*-
Formula Weight
487.58714
MOL File
578743-87-0.mol
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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Property

Melting point:
>300 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
Sensitive 
air sensitive
InChIKey
JPUFNIIPFXQOCB-UHFFFAOYSA-M
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Safety

WGK Germany 
3
HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
696307
Product name
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
Packaging
250mg
Price
$62.4
Updated
2024/03/01
Sigma-Aldrich
Product number
696307
Product name
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
Packaging
1g
Price
$201
Updated
2024/03/01
TCI Chemical
Product number
C2304
Product name
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
Purity
>98.0%(T)
Packaging
1g
Price
$160
Updated
2024/03/01
TCI Chemical
Product number
C2304
Product name
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
Purity
>98.0%(T)
Packaging
200mg
Price
$59
Updated
2024/03/01
Strem Chemicals
Product number
29-4050
Product name
Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I), 98%
Packaging
500mg
Price
$103
Updated
2024/03/01
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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the aziridination of olefins.
  2. Mild catalyst, superior to CuCl, in the methylenetriphenylphosphorane methyleneation of aldehydes and ketones.
  3. Copper(I) catalyzed alkylation of aryl and alkenylsilanes.
  4. Copper-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide.
  5. Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide.
  6. Carboxylation of organoboronic esters with potassium methyl carbonate under copper catalysis.
  7. Catalytic anti-Markovnikov hydrobromination of alkynes.
  8. Copper-catalyzed borylative cross-coupling of allenes and imines.



Uses

"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes."

reaction suitability

core: copper
reagent type: catalyst

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Suppliers

ChemicalRIM Co., Ltd
Tel
15184345951
Email
chemicalRIM@gmail.com
Country
China
ProdList
45
Advantage
58
Panjin Greenchem Technology Co., Ltd.
Tel
13121959385 13121959385
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
220
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
291
Advantage
62
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View Lastest Price from CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) 578743-87-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Longyan Tianhua Biological Technology Co., Ltd
Product
CHLORO[1,3-BIS(2,6-DIISOPROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) 578743-87-0
Price
US $7.00/Kg/Bag
Min. Order
25Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2020-11-11

578743-87-0, CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)Related Search:


  • 1,3-Bis(2,6-diisopropylphenyl)-2,3-dihydro-2-imidazolyl]copper(I) Chloride
  • [1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](chloro)copper
  • [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride
  • Chloro[1,3-bis(2,6-diisopropylphenyl)iMidazol-2-ylidene]copp
  • [(iPr)CuCl]
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  • CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
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  • [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) chloride
  • Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
  • idene]copper(I)
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  • Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) &gt
  • Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copp...
  • (1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)copper(III) chloride
  • 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-chloro-copper
  • 1,3-Bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-imidazol-2-yl]copper(II) Chloride
  • 578743-87-0
  • C27H36ClCuN2
  • Cu
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Copper
  • organometallic complex