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SPhos Pd G2

Reactions
Product Name
SPhos Pd G2
CAS No.
1375325-64-6
Chemical Name
SPhos Pd G2
Synonyms
RK1001022;SPhos Pd G2;SPhos Pd G2 catalyst;SPhos Palladacycle Gen.2;SPhos Pd G2 ISO 9001:2015 REACH;2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...;chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
CBNumber
CB52686111
Molecular Formula
C38H45ClNO2PPd
Formula Weight
720.63
MOL File
1375325-64-6.mol
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SPhos Pd G2 Property

Melting point:
218°C (dec.)
form 
Powder
color 
white
InChI
InChI=1S/C26H35O2P.C12H9N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9,13H;1H;/q;-2;;+2
InChIKey
PYMQIHHZINPLDV-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
753009
Product name
SPhos Pd G2
Packaging
1g
Price
$179
Updated
2024/03/01
Sigma-Aldrich
Product number
753009
Product name
SPhos Pd G2
Packaging
5g
Price
$571
Updated
2024/03/01
Strem Chemicals
Product number
46-0283
Product name
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. 98% [SPhos Palladacycle Gen. 2]
Packaging
250mg
Price
$39
Updated
2024/03/01
Strem Chemicals
Product number
46-0283
Product name
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. 98% [SPhos Palladacycle Gen. 2]
Packaging
1g
Price
$122
Updated
2024/03/01
Sigma-Aldrich
Product number
753009
Product name
SPhos Pd G2
Packaging
250mg
Price
$38.7
Updated
2024/03/01
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SPhos Pd G2 Chemical Properties,Usage,Production

Reactions

Palladium precatalyst for Suzuki-Miyaura coupling reactions.

Uses

Application in Suzuki-Miyaura coupling:

  • Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
  • Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.
  • Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

General Description

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

SPhos Pd G2 Preparation Products And Raw materials

Raw materials

Preparation Products

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SPhos Pd G2 Suppliers

Henan Runfeng Catalyst Co. LTD
Tel
15560227177
Fax
0373-7759608
Email
sales@runcatalysts.cn
Country
China
ProdList
111
Advantage
58
WuHan Taiyukaishang Chemical Co., Ltd.
Tel
027-87680032 18963957250
Fax
027-87680032 -8016
Email
355723431@qq.com
Country
China
ProdList
108
Advantage
55
Beijing Guofang Dingsheng Technology Co., Ltd.
Tel
18610472091 18610472091
Fax
010-59092859
Email
gfdskj@163.com
Country
China
ProdList
494
Advantage
58
Wu Han Lbpchem Chemical Co., Ltd.
Tel
02763499399 13797220777
Email
lpbchem@163.com
Country
China
ProdList
99
Advantage
58
Wuhan phosphine biologic Pharmaceutical Co., LTD
Tel
15102702255 15102702255
Email
35729423@qq.com
Country
China
ProdList
106
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
950
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
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View Lastest Price from SPhos Pd G2 manufacturers

Hebei Guanlang Biotechnology Co,.LTD
Product
SPhos Pd G2 1375325-64-6
Price
US $8.70/g
Min. Order
10g
Purity
99.95%
Supply Ability
10000kg
Release date
2021-07-16
Shaanxi Dideu Medichem Co. Ltd
Product
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) 1375325-64-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-17
Wuhan LPBchem Technology Co.,Ltd
Product
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2 1375325-64-6
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-27

1375325-64-6, SPhos Pd G2Related Search:


  • SPhos Pd G2
  • 2nd Generation SPhos Precatalyst
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline
  • RK1001022
  • Chloro(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [SPhos Palladacycle]
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)MIN.98%[SPHOSPALLADACYCLEGEN.2]
  • SPhos Palladacycle Gen.2
  • SPhos Pd G2 catalyst
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2
  • SPhos Pd G2 ISO 9001:2015 REACH
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...
  • SPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (SPhos Pd G2)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min.
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • 1375325-64-6
  • C38H45ClNO2PPd
  • C26H35O2PC12H10ClNPd
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd