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SPhos Pd G2

Reactions
Product Name
SPhos Pd G2
CAS No.
1375325-64-6
Chemical Name
SPhos Pd G2
Synonyms
RK1001022;SPhos Pd G2;SPhos Pd G2 catalyst;SPhos Palladacycle Gen.2;SPhos Pd G2 ISO 9001：2015 REACH;2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...;chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
CBNumber
CB52686111
Molecular Formula
C38H45ClNO2PPd
Formula Weight
720.63
MOL File
1375325-64-6.mol
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SPhos Pd G2 Property

Melting point:
218°C (dec.)
form 
Powder
color 
white
InChI
InChI=1S/C26H35O2P.C12H9N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9,13H;1H;/q;-2;;+2
InChIKey
PYMQIHHZINPLDV-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
753009
Product name
SPhos Pd G2
Packaging
1g
Price
$179
Updated
2024/03/01
Sigma-Aldrich
Product number
753009
Product name
SPhos Pd G2
Packaging
5g
Price
$571
Updated
2024/03/01
Strem Chemicals
Product number
46-0283
Product name
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. 98% [SPhos Palladacycle Gen. 2]
Packaging
250mg
Price
$39
Updated
2024/03/01
Strem Chemicals
Product number
46-0283
Product name
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. 98% [SPhos Palladacycle Gen. 2]
Packaging
1g
Price
$122
Updated
2024/03/01
Sigma-Aldrich
Product number
753009
Product name
SPhos Pd G2
Packaging
250mg
Price
$38.7
Updated
2024/03/01
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SPhos Pd G2 Chemical Properties,Usage,Production

Reactions

Palladium precatalyst for Suzuki-Miyaura coupling reactions.

Uses

Application in Suzuki-Miyaura coupling:

  • Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
  • Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.
  • Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

General Description

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

SPhos Pd G2 Preparation Products And Raw materials

Raw materials

Preparation Products

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SPhos Pd G2 Suppliers

China 100 India 1 Switzerland 1 United States 8 Global 110
Biosynth AG
Tel
--
Fax
--
Email
welcome@biosynth.ch
Country
Switzerland
ProdList
3324
Advantage
72
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View Lastest Price from SPhos Pd G2 manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
SPhos Pd G2 1375325-64-6
Price
US $8.70/g
Min. Order
10g
Purity
99.95%
Supply Ability
10000kg
Release date
2024-08-20
Wuhan LPBchem Technology Co.,Ltd
Product
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2 1375325-64-6
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-27
Career Henan Chemical Co
Product
SPhos Pd G2 1375325-64-6
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
JD 500
Release date
2019-09-01

1375325-64-6, SPhos Pd G2Related Search:

BrettPhos Pd G3 RuPhos Pd G1 Methyl t--Butyl Ether Adduct BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1 RuPhos Pd G3 Bis(diphenylphosphinophenyl)ether palladium (II) dichloride Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) BrettPhos Pd G4 XPhos Pd G2 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II), min. 98%

  • SPhos Pd G2
  • 2nd Generation SPhos Precatalyst
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline
  • RK1001022
  • Chloro(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [SPhos Palladacycle]
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)MIN.98%[SPHOSPALLADACYCLEGEN.2]
  • SPhos Palladacycle Gen.2
  • SPhos Pd G2 catalyst
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2
  • SPhos Pd G2 ISO 9001：2015 REACH
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...
  • SPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (SPhos Pd G2)
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min.
  • Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)
  • 1375325-64-6
  • C38H45ClNO2PPd
  • C26H35O2PC12H10ClNPd
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd