t-BuXphos Palladacycle Gen. 4
Reaction- Product Name
- t-BuXphos Palladacycle Gen. 4
- CAS No.
- 1599466-89-3
- Chemical Name
- t-BuXphos Palladacycle Gen. 4
- Synonyms
- t-BuXphos Pd G4;T-BUTYLXPHOS PD G4;T-BUTYLXPHOS PD G4E;[T-BUXPHOS PALLADACYCLE GEN. 4];t-BuXphos Palladacycle Gen. 4 ISO 9001:2015 REACH;Ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl...;Methanesulfonato(2-Di-t-butylphosphino-2,4,6-tri-i-propyl-1,1-biphenyl)(2-methylamino-1,1-biphenyl-2-yl)palladium(II);Methanesulfonato(2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);DITERT-BUTYL-[2-[2,4,6-TRI(PROPAN-2-YL)PHENYL]PHENYL]PHOSPHANE;DICHLOROMETHANE;METHANESULFONATE;N-METHYL-2-PHENYLANILINE;PALLADIUM(2+)
- CBNumber
- CB43159040
- Molecular Formula
- C44H62Cl2NO3PPdS
- Formula Weight
- 893.332741
- MOL File
- 1599466-89-3.mol
t-BuXphos Palladacycle Gen. 4 Property
- form
- Powder
- color
- off-white to gray
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 46-0330
- Product name
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4]
- Packaging
- 250mg
- Price
- $110
- Updated
- 2024/03/01
- Product number
- 46-0330
- Product name
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4]
- Packaging
- 1g
- Price
- $328
- Updated
- 2024/03/01
- Product number
- 46-0330
- Product name
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4]
- Packaging
- 5g
- Price
- $1309
- Updated
- 2024/03/01
- Product number
- A627722
- Product name
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)dichloromethaneadduct
- Purity
- 98%
- Packaging
- 5g
- Price
- $632
- Updated
- 2021/12/16
- Product number
- A627722
- Product name
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)dichloromethaneadduct
- Purity
- 98%
- Packaging
- 1g
- Price
- $168
- Updated
- 2021/12/16
t-BuXphos Palladacycle Gen. 4 Chemical Properties,Usage,Production
Reaction
Alternative N-methyl catalyst for mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media.
Uses
t-BuXphos Palladacycle Gen. 4 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.
Forms and nomenclature
Off-white to gray powder
t-BuXphos Palladacycle Gen. 4 Preparation Products And Raw materials
Raw materials
Preparation Products
t-BuXphos Palladacycle Gen. 4 Suppliers
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View Lastest Price from t-BuXphos Palladacycle Gen. 4 manufacturers
- Product
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / t-ButylXPhos Pd G4 1599466-89-3
- Price
- US $10.00-10.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 50kg
- Release date
- 2020-09-27