Reaction
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Xantphos Pd G3

Reaction
Product Name
Xantphos Pd G3
CAS No.
1445085-97-1
Chemical Name
Xantphos Pd G3
Synonyms
XantPhos Pd G3;Pd Catalysts XantPhos-Pd-G3;Xantphos Palladacycle Gen. 3;XantPhos Pd G3[XantPhos Pd G3;Xantphos Palladacycle Gen. 3 ISO 9001:2015 REACH;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I;Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II);Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II);methanesulfonato[9,9-dime-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphen]pd(ii) ch2cl2 adduct
CBNumber
CB62709871
Molecular Formula
C52H46NO4P2PdS-
Formula Weight
949.358462
MOL File
1445085-97-1.mol
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Xantphos Pd G3 Property

Melting point:
164-167 °C (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
pale yellow
InChI
InChI=1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
InChIKey
JIMOHYWEUIAPAA-UHFFFAOYSA-N
SMILES
[Pd].S(C([H])([H])[H])(=O)(=O)O[H].P(C1C([H])=C([H])C([H])=C([H])C=1[H])(C1C([H])=C([H])C([H])=C([H])C=1[H])C1=C([H])C([H])=C([H])C2=C1OC1C(=C([H])C([H])=C([H])C=1C2(C([H])([H])[H])C([H])([H])[H])P(C1C([H])=C([H])C([H])=C([H])C=1[H])C1C([H])=C([H])C([H])=C([H])C=1[H].N([H])([H])C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([H])C([H])=[C-]1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
763039
Product name
XantPhos Pd G3
Purity
95%
Packaging
250MG
Price
$54.2
Updated
2023/06/20
Sigma-Aldrich
Product number
763039
Product name
XantPhos Pd G3
Purity
95%
Packaging
1G
Price
$164
Updated
2023/06/20
Sigma-Aldrich
Product number
932213
Product name
XantPhos Pd G3 ChemBeads
Packaging
1G
Price
$276
Updated
2023/06/20
Sigma-Aldrich
Product number
763039
Product name
XantPhos Pd G3
Purity
95%
Packaging
5G
Price
$678
Updated
2023/06/20
Strem Chemicals
Product number
46-0957
Product name
Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3]
Packaging
500mg
Price
$85
Updated
2024/03/01
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Xantphos Pd G3 Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents.
  2. Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose.
  3. Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters.

Uses

Xantphos Pd G3 is used as a catalyst in many reactions. It is a third generation (G3) Buchwald precatalyst. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions.

General Description

XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Xantphos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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Xantphos Pd G3 Suppliers

Wu Han Lbpchem Chemical Co., Ltd.
Tel
02763499399 13797220777
Email
lpbchem@163.com
Country
China
ProdList
99
Advantage
58
Wuhan phosphine biologic Pharmaceutical Co., LTD
Tel
15102702255 15102702255
Email
35729423@qq.com
Country
China
ProdList
106
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
953
Advantage
55
BeiJing Greenchem Technology Co.,Ltd.
Tel
131-21959385 15640741633
Fax
010-62925455
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
269
Advantage
58
xinxiang runyu material co.,Ltd
Tel
15690792173 15690792173
Fax
0373-7759608
Email
sales@runvmat.com
Country
China
ProdList
213
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
335
Advantage
62
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View Lastest Price from Xantphos Pd G3 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Xantphos Palladacycle Gen. 3 1445085-97-1
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-29
Hebei Chuanghai Biotechnology Co,.LTD
Product
Pd Catalysts XantPhos-Pd-G3 1445085-97-1
Price
US $8.70/g
Min. Order
10g
Purity
99%
Supply Ability
10000kg
Release date
2024-08-09
Wuhan LPBchem Technology Co.,Ltd
Product
Xantphos Pd G3 1445085-97-1
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-12-01

1445085-97-1, Xantphos Pd G3Related Search:


  • Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%
  • Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II)
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I
  • METHANESULFONATO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE][2'-AMINO-1,1'-BIPHENYL]PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XANTPHOSPALLADACYCLEGEN.3]
  • Xantphos Palladacycle Gen. 3
  • Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2-amino-1,1-biphenyl-2-yl)palladium(II)
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct,[Xantphos Palladacycle Gen. 3]
  • Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct
  • 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene][2’-amino-2-biphenylyl][(methylsulfonyl)oxy]palladium(II)
  • methanesulfonato[9,9-dime-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphen]pd(ii) ch2cl2 adduct
  • Xantphos Palladacycle Gen. 3 ISO 9001:2015 REACH
  • Pd Catalysts XantPhos-Pd-G3
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II) (Xantphos Pd G3)
  • [(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate/XantPhosPdG3
  • XantPhos Pd G3[XantPhos Pd G3
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)palladium
  • XantPhos Pd G3
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II)
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)palladium
  • Methanesulfonato [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene] (2'-amino-1,1'-biphenyl-2-yl)palladium(II),R-Binap Pd G3
  • Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • [4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene][2’-amino-2-biphenylyl][(methylsulfonyl)oxy]palladium(II)
  • Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II) (Xantphos Pd G3)
  • 1445085-97-1
  • C52H45NO4P2PdS
  • C39H32OP2C13H13NO3PdS
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd