BrettPhosPalladacycle
Reaction- Product Name
- BrettPhosPalladacycle
- CAS No.
- 1148148-01-9
- Chemical Name
- BrettPhosPalladacycle
- Synonyms
- BrettPhos Pd G1;BrettPhos precatalyst;BrettPhos Palladacycle;BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct;BrettPhos Pd G1 MTBE adduct;BrettPhos Palladacycle Gen. 1;chloro-(2-phenylethylamino)palladium;[2-(2-aminoethyl)phenyl]palladium(1+);(BrettPhos) palladium(II) phenethylamine chloride;Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...
- CBNumber
- CB52614378
- Molecular Formula
- C43H63ClNO2PPd
- Formula Weight
- 798.83
- MOL File
- 1148148-01-9.mol
BrettPhosPalladacycle Property
- Melting point:
- 198-204 °C
- form
- Powder
- color
- white
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 718750
- Product name
- BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity
- may contain up to 1 mole equivalent of MTBE, 97%
- Packaging
- 1g
- Price
- $533
- Updated
- 2024/03/01
- Product number
- 718750
- Product name
- BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity
- may contain up to 1 mole equivalent of MTBE, 97%
- Packaging
- 5g
- Price
- $1450
- Updated
- 2024/03/01
- Product number
- 46-0267
- Product name
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II), min. 98% [BrettPhos Palladacycle Gen. 1]
- Packaging
- 100mg
- Price
- $62
- Updated
- 2024/03/01
- Product number
- 46-0267
- Product name
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II), min. 98% [BrettPhos Palladacycle Gen. 1]
- Packaging
- 500mg
- Price
- $180
- Updated
- 2024/03/01
- Product number
- 718750
- Product name
- BrettPhos Pd G1, Methyl t-Butyl Ether Adduct
- Purity
- may contain up to 1 mole equivalent of MTBE, 97%
- Packaging
- 100mg
- Price
- $34.96
- Updated
- 2024/03/01
BrettPhosPalladacycle Chemical Properties,Usage,Production
Reaction
- Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines.
- Catalyst for rapid C-N bond-forming processes at low catalyst loading.
- Cross-coupling of 3-Bromo-2-aminopyridine with primary amines.
Uses
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for:
- C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
- Amination reaction
- N-arylation of aminophenols
General Description
BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.
BrettPhosPalladacycle Preparation Products And Raw materials
Raw materials
Preparation Products
BrettPhosPalladacycle Suppliers
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View Lastest Price from BrettPhosPalladacycle manufacturers
- Product
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) 1148148-01-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2020-04-21
- Product
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) /BrettPhos Pd G1 1148148-01-9
- Price
- US $10.00-10.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 50kg
- Release date
- 2020-09-27
- Product
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) 1148148-01-9
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- Min98%
- Supply Ability
- g/kg/ton
- Release date
- 2020-01-10