Reaction
ChemicalBook > CAS DataBase List > t-BuXphos Palladacycle Gen. 4

t-BuXphos Palladacycle Gen. 4

Reaction
Product Name
t-BuXphos Palladacycle Gen. 4
CAS No.
1599466-89-3
Chemical Name
t-BuXphos Palladacycle Gen. 4
Synonyms
t-BuXphos Pd G4;T-BUTYLXPHOS PD G4;T-BUTYLXPHOS PD G4E;[T-BUXPHOS PALLADACYCLE GEN. 4];t-BuXphos Palladacycle Gen. 4 ISO 9001:2015 REACH;Ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl...;Methanesulfonato(2-Di-t-butylphosphino-2,4,6-tri-i-propyl-1,1-biphenyl)(2-methylamino-1,1-biphenyl-2-yl)palladium(II);Methanesulfonato(2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);DITERT-BUTYL-[2-[2,4,6-TRI(PROPAN-2-YL)PHENYL]PHENYL]PHOSPHANE;DICHLOROMETHANE;METHANESULFONATE;N-METHYL-2-PHENYLANILINE;PALLADIUM(2+)
CBNumber
CB43159040
Molecular Formula
C44H62Cl2NO3PPdS
Formula Weight
893.332741
MOL File
1599466-89-3.mol
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t-BuXphos Palladacycle Gen. 4 Property

form 
Powder
color 
off-white to gray
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
46-0330
Product name
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4]
Packaging
250mg
Price
$110
Updated
2024/03/01
Strem Chemicals
Product number
46-0330
Product name
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4]
Packaging
1g
Price
$328
Updated
2024/03/01
Strem Chemicals
Product number
46-0330
Product name
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuXphos Palladacycle Gen. 4]
Packaging
5g
Price
$1309
Updated
2024/03/01
Ambeed
Product number
A627722
Product name
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)dichloromethaneadduct
Purity
98%
Packaging
5g
Price
$632
Updated
2021/12/16
Ambeed
Product number
A627722
Product name
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)dichloromethaneadduct
Purity
98%
Packaging
1g
Price
$168
Updated
2021/12/16
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t-BuXphos Palladacycle Gen. 4 Chemical Properties,Usage,Production

Reaction

Alternative N-methyl catalyst for mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media.

Uses

t-BuXphos Palladacycle Gen. 4 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

Forms and nomenclature

Off-white to gray powder

t-BuXphos Palladacycle Gen. 4 Preparation Products And Raw materials

Raw materials

Preparation Products

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t-BuXphos Palladacycle Gen. 4 Suppliers

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View Lastest Price from t-BuXphos Palladacycle Gen. 4 manufacturers

Wuhan LPBchem Technology Co.,Ltd
Product
Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / t-ButylXPhos Pd G4 1599466-89-3
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-27

1599466-89-3, t-BuXphos Palladacycle Gen. 4Related Search:


  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min
  • [T-BUXPHOS PALLADACYCLE GEN. 4]
  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct
  • Methanesulfonato(2-Di-t-butylphosphino-2,4,6-tri-i-propyl-1,1-biphenyl)(2-methylamino-1,1-biphenyl-2-yl)palladium(II)
  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, [t-BuXphos Palladacycle Gen. 4]
  • METHANESULFONATO(2-DI-T-BUTYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[T-BUXPHOSPALLADACYCLEGEN.4]
  • T-BUTYLXPHOS PD G4E
  • Ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
  • DITERT-BUTYL-[2-[2,4,6-TRI(PROPAN-2-YL)PHENYL]PHENYL]PHOSPHANE;DICHLOROMETHANE;METHANESULFONATE;N-METHYL-2-PHENYLANILINE;PALLADIUM(2+)
  • T-BUTYLXPHOS PD G4
  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / t-ButylXPhos Pd G4
  • t-BuXphos Palladacycle Gen. 4 ISO 9001:2015 REACH
  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),t-BuXphos Palladacycle Gen. 4
  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl...
  • t-BuBrettPhos Pd G3 / Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • t-BuXphos Pd G4
  • Methanesulfonato(2-DI-t-butylphosphino-2',4',6'-tri-I-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-YL)palladium(II) (T-buxphos PD g4)
  • Methanesulfonato(2-di-t-butylphosphino-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-methylamino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct
  • Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct
  • Methanesulfonato(2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • 1599466-89-3
  • C43H60NO3PPdS
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd