Reaction
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RuPhos Pd G3

Reaction
Product Name
RuPhos Pd G3
CAS No.
1445085-77-7
Chemical Name
RuPhos Pd G3
Synonyms
RuPhos-Pd-G3;RuPhos Palladacycle Gen.3;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);RuPhos Pd G3;RuPhos Pd G3 95%;RuPhos-G3-Palladacycle;RuPhos Pd G3 ISO 9001：2015 REACH;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-...;Methanesulfonato(2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
CBNumber
CB02686116
Molecular Formula
C43H57NO5PPdS-
Formula Weight
837.375141
MOL File
1445085-77-7.mol
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RuPhos Pd G3 Property

Melting point:
188-196°C (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
white
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
CAS DataBase Reference
1445085-77-7
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-61
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
763403
Product name
RuPhos Pd G3
Purity
95%
Packaging
1g
Price
$248
Updated
2024/03/01
Sigma-Aldrich
Product number
763403
Product name
RuPhos Pd G3
Purity
95%
Packaging
5g
Price
$1000
Updated
2024/03/01
Strem Chemicals
Product number
46-0314
Product name
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]
Packaging
250mg
Price
$64
Updated
2024/03/01
Strem Chemicals
Product number
46-0314
Product name
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]
Packaging
1g
Price
$209
Updated
2024/03/01
Sigma-Aldrich
Product number
763403
Product name
RuPhos Pd G3
Purity
95%
Packaging
250mg
Price
$88.4
Updated
2024/03/01
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RuPhos Pd G3 Chemical Properties,Usage,Production

Reaction

  1. Palladium catalyst used for facile, C-N cross-coupling reactions.
  2. A practical synthesis of indoles via a Pd-catalyzed C-N ring formation.

Uses

RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:

  • Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
  • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
  • Suzuki-Miyaura-cross-coupling of aminothiophenes.

General Description

RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

RuPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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RuPhos Pd G3 Suppliers

China 127 United States 10 Global 137
Henan Runfeng Catalyst Co. LTD
Tel
15560227177
Fax
0373-7759608
Email
sales@runcatalysts.cn
Country
China
ProdList
111
Advantage
58
WuHan Taiyukaishang Chemical Co., Ltd.
Tel
027-87680032 18963957250
Fax
027-87680032 -8016
Email
355723431@qq.com
Country
China
ProdList
108
Advantage
55
Beijing Guofang Dingsheng Technology Co., Ltd.
Tel
18610472091 18610472091
Fax
010-59092859
Email
gfdskj@163.com
Country
China
ProdList
494
Advantage
58
Wu Han Lbpchem Chemical Co., Ltd.
Tel
02763499399 13797220777
Email
lpbchem@163.com
Country
China
ProdList
99
Advantage
58
Wuhan Jiade Ruifeng New Materials Co., Ltd
Tel
18271874579
Email
2176439072@qq.com
Country
China
ProdList
198
Advantage
58
Wuhan phosphine biologic Pharmaceutical Co., LTD
Tel
15102702255 15102702255
Email
35729423@qq.com
Country
China
ProdList
106
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
950
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
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View Lastest Price from RuPhos Pd G3 manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1445085-77-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-17
Wuhan LPBchem Technology Co.,Ltd
Product
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / RuPhos Pd G3 1445085-77-7
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-11-25
Longyan Tianhua Biological Technology Co., Ltd
Product
RuPhos Pd G3 1445085-77-7
Price
US $65.00/KG
Min. Order
1KG
Purity
99
Supply Ability
10000KG
Release date
2020-11-10

1445085-77-7, RuPhos Pd G3Related Search:

cataCXium A Pd G3 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1

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  • Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP](methanesulfonato-κO)-
  • RuPhos Pd G3 ISO 9001：2015 REACH
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-...
  • RuPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • (2'-Amino-2-biphenylyl)(methanesulfonato-κO)palladium - dicyclohexyl(2',6'-diisopropoxy-2-biphenylyl)phosphine (1:1)
  • Methanesulfonato(2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
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  • 1445085-77-7
  • C43H56NO5PPdS
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  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd