SPhos Pd G2

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Reactions

Product Name: SPhos Pd G2
CAS No.: 1375325-64-6
Chemical Name: SPhos Pd G2
Synonyms: RK1001022;SPhos Pd G2;SPhos Pd G2 catalyst;SPhos Palladacycle Gen.2;SPhos Pd G2 ISO 9001：2015 REACH;2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...;chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
CBNumber: CB52686111
Molecular Formula: C38H45ClNO2PPd
Formula Weight: 720.63
MOL File: 1375325-64-6.mol

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SPhos Pd G2 Property

Melting point:: 218°C (dec.)
form: Powder
color: white
InChI: InChI=1S/C26H35O2P.C12H9N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-6,8-9,13H;1H;/q;-2;;+2
InChIKey: PYMQIHHZINPLDV-UHFFFAOYSA-N
SMILES: P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 753009
Product name: SPhos Pd G2
Packaging: 1g
Price: $179
Updated: 2024/03/01

Sigma-Aldrich

Product number: 753009
Product name: SPhos Pd G2
Packaging: 5g
Price: $571
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0283
Product name: Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. 98% [SPhos Palladacycle Gen. 2]
Packaging: 250mg
Price: $39
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0283
Product name: Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. 98% [SPhos Palladacycle Gen. 2]
Packaging: 1g
Price: $122
Updated: 2024/03/01

Sigma-Aldrich

Product number: 753009
Product name: SPhos Pd G2
Packaging: 250mg
Price: $38.7
Updated: 2024/03/01

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SPhos Pd G2 Chemical Properties,Usage,Production

Reactions

Palladium precatalyst for Suzuki-Miyaura coupling reactions.

Uses

Application in Suzuki-Miyaura coupling:

Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
Suzuki–Miyaura coupling of [Ru(bpy)₂]⁺ with 4-carboxyphenylboronic acid.
Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

General Description

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

SPhos Pd G2 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from SPhos Pd G2 manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: SPhos Pd G2 1375325-64-6
Price: US $8.70/g
Min. Order: 10g
Purity: 99.95%
Supply Ability: 10000kg
Release date: 2024-08-20

Wuhan LPBchem Technology Co.,Ltd

Product: Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2 1375325-64-6
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50kg
Release date: 2020-09-27

Career Henan Chemical Co

Product: SPhos Pd G2 1375325-64-6
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: JD 500
Release date: 2019-09-01

1375325-64-6, SPhos Pd G2Related Search:

BrettPhos Pd G3 RuPhos Pd G1 Methyl t--Butyl Ether Adduct BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1 RuPhos Pd G3 Bis(diphenylphosphinophenyl)ether palladium (II) dichloride Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) BrettPhos Pd G4 XPhos Pd G2 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II), min. 98%

SPhos Pd G2

2nd Generation SPhos Precatalyst

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)

chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline

RK1001022

Chloro(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [SPhos Palladacycle]

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)MIN.98%[SPHOSPALLADACYCLEGEN.2]

SPhos Palladacycle Gen.2

SPhos Pd G2 catalyst

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2

SPhos Pd G2 ISO 9001：2015 REACH

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...

SPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (SPhos Pd G2)

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min.

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (SPhos Pd G2)

Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min.

1375325-64-6

C38H45ClNO2PPd

C26H35O2PC12H10ClNPd

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series