ChemicalBook > CAS DataBase List > CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
Reactions- Product Name
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
- CAS No.
- 92390-26-6
- Chemical Name
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
- Synonyms
- Cp*RuCl(cod);Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II);Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM;1,5-Cyclooctadiene, ruthenium complex;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;Chloro(1,5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
- CBNumber
- CB4405539
- Molecular Formula
- C18H27ClRu5*
- Formula Weight
- 379.93
- MOL File
- 92390-26-6.mol
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Property
- Melting point:
- 143-147℃
- storage temp.
- -20°C
- color
- brown microxtls
- Stability:
- store cold
- InChIKey
- JBVMVFXUVNUNNG-ONEVTFJLSA-M
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Safety
- Hazard Codes
- F
- Risk Statements
- 20/21/22-14/15
- Safety Statements
- 22-36/37/39-43
- RIDADR
- UN 3395
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 4.3
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 667234
- Product name
- Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
- Packaging
- 250mg
- Price
- $131
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 667234
- Product name
- Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
- Packaging
- 1g
- Price
- $350
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 046803
- Product name
- Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
- Packaging
- 250mg
- Price
- $113.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 046803
- Product name
- Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
- Packaging
- 1g
- Price
- $394
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0113
- Product name
- Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%
- Packaging
- 250mg
- Price
- $121
- Updated
- 2024/03/01
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CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties,Usage,Production
Reactions
- Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
- Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
- Catalyst for ring closing enyne metathesis.
- Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
- Catalyst for hydrovinylation of ynamides with ethylene.
- Catalyst for C–H insertion reactions of carbenes.
Uses
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:
- To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
- To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
- In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
- To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
- To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) manufacturers
Longyan Tianhua Biological Technology Co., Ltd
- Product
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11
Career Henan Chemical Co
- Product
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) 92390-26-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-07-03
92390-26-6, CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)Related Search:
1,5-Cyclooctadiene
Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
XPhos Pd G2
RuPhos Pd G1 Methyl t--Butyl Ether Adduct
CHLORO(INDENYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
SPhos Pd G2
Chloro(1,5-cyclooctadiene)iridium(I) dimer
SPhos Pd G1, Methyl t-Butyl Ether Adduct
RuPhos Pd G2
XPhos Pd G1
Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%
Allylpalladium(II) Chloride Dimer
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
XantPhos-Pd-G2
cataCXium A-Pd-G2
Rubidium chloride