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SALCOMINE

Product Name
SALCOMINE
CAS No.
14167-18-1
Chemical Name
SALCOMINE
Synonyms
o’)-o;SALEN-CO;Salcomin;Nsc32965;(sp-4-2)-;SALCOMINE;N,N&priMe;Co(salen);N,N′CO(SALEN)2
CBNumber
CB4223164
Molecular Formula
C16H14CoN2O2
Formula Weight
325.23
MOL File
14167-18-1.mol
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SALCOMINE Property

Melting point:
>300 °C
storage temp. 
Inert atmosphere,Room Temperature
Water Solubility 
Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Stability:
Stable. Incompatible with strong acids, strong oxidizing agents.
EPA Substance Registry System
Salcomine (14167-18-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
GG0590000
10
TSCA 
Yes
HS Code 
29349990
Hazardous Substances Data
14167-18-1(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P262Do not get in eyes, on skin, or on clothing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
274712
Product name
N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
Purity
99%
Packaging
1g
Price
$76.8
Updated
2021/03/22
Sigma-Aldrich
Product number
274712
Product name
N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
Purity
99%
Packaging
5g
Price
$268
Updated
2021/03/22
TCI Chemical
Product number
S0318
Product name
Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
Purity
>95.0%(T)
Packaging
25g
Price
$93
Updated
2021/03/22
TCI Chemical
Product number
S0318
Product name
Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
Purity
>95.0%(T)
Packaging
100g
Price
$245
Updated
2021/03/22
Alfa Aesar
Product number
043174
Product name
N,N'-Bis(salicylidene)ethylenediaminecobalt(II), 96%
Packaging
1g
Price
$15.7
Updated
2021/03/22
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SALCOMINE Chemical Properties,Usage,Production

Chemical Properties

black crystalline powder

General Description

A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.

Reactivity Profile

SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.

Purification Methods

The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]

SALCOMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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SALCOMINE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3579
Advantage
66
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30159
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12283
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078;021-50426030
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
10006
Advantage
60
Nanjing Chemlin Chemical Co., Ltd
Tel
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19997
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202- ; ;
Email
jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com
Country
China
ProdList
43255
Advantage
64
Hunan Hui Bai Shi Biotechnology Co., Ltd.
Tel
0731-85526065-
Email
3002732518@qq.com
Country
China
ProdList
3500
Advantage
62
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View Lastest Price from SALCOMINE manufacturers

career henan chemical co
Product
SALCOMINE 14167-18-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-03

14167-18-1, SALCOMINERelated Search:


  • N,N'-DISALICYLALETHYLENEDIAMINE COBALT(II)
  • N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)COBALT(II)
  • SALCOMINE
  • SALEN-CO
  • ((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n-cobal
  • ((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-cobal
  • (N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)
  • (N,N'-Ethylenebis(salicylideniminato))cobalt
  • (sp-4-2)-
  • a13-30876[qr]
  • Bis(salicylaldehyde)ethylenediimine cobalt(ii)
  • bis(salicylaldehyde)ethylenediiminecobalt(ii)
  • Cobalt, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-
  • Cobalt, ((alpha,alpha'-(ethylenedinitrilo)di-o-cresolato)(2-))-
  • Cobalt, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
  • Cobalt, N,N'-ethylenebis(salicylideneiminato)-
  • cobalt,((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n
  • cobalt,((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-[qr]
  • cobalt,[[2,2’-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-n,n’,
  • n,n’-bis(salicylidene)ethylenediaminecobalt(ii)salthyd.
  • n,n’-bis(salicylidene)ethylenediamino
  • n,n’-ethylenebis(salicylideneiminato)-cobal
  • N,N'-Ethylenebis(salicylideneiminato)cobalt
  • n,n-ethylenebis(salicylideneiminato)cobaltii[qr]
  • N,N'-Ethylenebis(salicylideniminato)cobalt(II)
  • o,o’)-(sp-4-2)-[qr]
  • o’)-o
  • Salcomin
  • CO(SALEN)2
  • Salcomine: (bis(Salicylaldehyde)ethylenediimine cobalt(II))
  • N,N'-Bis(salicylidene)ethylenediamine cobalt salt
  • Co(SALEN)2, Ethylenebis(salicylimine) cobalt(II) salt, Salcomine, N,Nμ-Disalicylidene-ethylenediamine cobalt(II) salt
  • [2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II)
  • [Bis(salicylidene)ethylenediaminato]cobalt
  • [Bis(salicylidene)ethylenediamine]cobalt
  • [N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II)
  • [N,N'-Bis(salicylidene)ethylenediaminato]cobalt
  • [N,N'-Disalicylideneethylenediamine]cobalt
  • N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II)
  • N,N'-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(II)
  • N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINOCOBALT(II)
  • Ethylenebis(salicylimine) cobalt(II) salt
  • N,N'-Bis(salicylidene)ethylenediaminecobalt(Ⅱ)
  • Salcomine, N,N'-Disalicylidene-ethylenediamine cobalt(II) salt
  • N,N'-Bis(salicyliden)ethylenediaminocobalt (ii)
  • Nsc32965
  • N,N'-Bis(salicylidene)ethylenediiminocobalt(II) N,N'-Disalicylalethylenediamine Cobalt(II) N,N'-Ethylenebis(salicylideneiminato)cobalt(II)
  • SalcoMine&nbsp
  • -Bis(salicylidene)ethylenediaMinocobalt(II)
  • N,N&priMe
  • The twosalicylaldehydeethylenediaMinecobalt
  • Co(salen)
  • <i>N,N'</i>-Bis(salicylidene)ethylenediaminocobalt(II)
  • 2,2'-((1Z,3Z)-2,3-Diaminobuta-1,3-diene-1,4-diyl)diphenol, cobalt salt
  • N,N&#8242
  • -Bis(3-aminopropyl)-1,3-propanediamine-d24
  • -Disuccinimidyl Carbonate (Technical Grade)
  • -Bis(3-aminopropyl)-1,3-propanediamine