SALCOMINE
- Product Name
- SALCOMINE
- CAS No.
- 14167-18-1
- Chemical Name
- SALCOMINE
- Synonyms
- o’)-o;SALEN-CO;Salcomin;Nsc32965;(sp-4-2)-;SALCOMINE;N,N&priMe;Co(salen);CO(SALEN)2;salcomin[qr]
- CBNumber
- CB4223164
- Molecular Formula
- C16H14CoN2O2
- Formula Weight
- 325.23
- MOL File
- 14167-18-1.mol
SALCOMINE Property
- Melting point:
- >300 °C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- Orange to Amber to Dark red
- Water Solubility
- Insoluble in water. Soluble in benzene, chloroform, and pyridine.
- Stability:
- Stable. Incompatible with strong acids, strong oxidizing agents.
- EPA Substance Registry System
- Salcomine (14167-18-1)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 2
- RTECS
- GG0590000
- F
- 10
- TSCA
- Yes
- HS Code
- 29349990
- Hazardous Substances Data
- 14167-18-1(Hazardous Substances Data)
- Toxicity
- mouse,LCLo,inhalation,390mg/m3/5.5H (390mg/m3),LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHILUNGS, THORAX, OR RESPIRATION: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA,Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 274712
- Product name
- N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
- Purity
- 99%
- Packaging
- 1g
- Price
- $117
- Updated
- 2024/03/01
- Product number
- 274712
- Product name
- N,N′-Bis(salicylidene)ethylenediaminocobalt(II)
- Purity
- 99%
- Packaging
- 5g
- Price
- $404
- Updated
- 2024/03/01
- Product number
- S0318
- Product name
- Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
- Purity
- >95.0%(T)
- Packaging
- 25g
- Price
- $99
- Updated
- 2024/03/01
- Product number
- S0318
- Product name
- Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
- Purity
- >95.0%(T)
- Packaging
- 100g
- Price
- $250
- Updated
- 2024/03/01
- Product number
- 043174
- Product name
- N,N'-Bis(salicylidene)ethylenediaminecobalt(II), 96%
- Packaging
- 1g
- Price
- $17.65
- Updated
- 2024/03/01
SALCOMINE Chemical Properties,Usage,Production
Chemical Properties
black crystalline powder
Uses
Salcomine catalyzes the oxidation of 2,6-disubstituted phenols by dioxygen. Experimental inhibitor of human cytμloviris proteinase activity. Metal complex dyes used as redox catalysts.
General Description
A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.
Reactivity Profile
SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.
Purification Methods
The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]
SALCOMINE Preparation Products And Raw materials
Raw materials
Preparation Products
SALCOMINE Suppliers
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View Lastest Price from SALCOMINE manufacturers
- Product
- SALCOMINE 14167-18-1
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-29
- Product
- SALCOMINE 14167-18-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-07-03