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MN(TMHD)3

Product Name
MN(TMHD)3
CAS No.
14324-99-3
Chemical Name
MN(TMHD)3
Synonyms
Mn(dpm)3;Tris(dipivaloylmethanato)manganese;Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese;MN(TMHD)3;anese(III);-3,5-heptanedionato)mang;Tris(2,2,6,6-tetramethyL;Shenvi Hydrogenation Catalyst;-3,5-heptanedionato)manganese(III);Tris(tetramethylheptanedionato)manganese
CBNumber
CB4241944
Molecular Formula
C33H57MnO6
Formula Weight
604.74
MOL File
14324-99-3.mol
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MN(TMHD)3 Property

Melting point:
165°C
Boiling point:
255°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
black
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
InChIKey
ORZPLLPBZHORSD-LWTKGLMZSA-K
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
700223
Product name
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)
Purity
97%
Packaging
1g
Price
$58.1
Updated
2024/03/01
Strem Chemicals
Product number
25-5000
Product name
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3]
Packaging
1g
Price
$55
Updated
2024/03/01
Strem Chemicals
Product number
25-5000
Product name
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3]
Packaging
5g
Price
$218
Updated
2024/03/01
Strem Chemicals
Product number
25-5000
Product name
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 99% [Mn(TMHD)3]
Packaging
25g
Price
$869
Updated
2024/03/01
TRC
Product number
T897683
Product name
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Manganese(Iii)
Packaging
100mg
Price
$175
Updated
2021/12/16
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MN(TMHD)3 Chemical Properties,Usage,Production

Uses

Catalyst for:

  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol

reaction suitability

core: manganese
reagent type: catalyst

MN(TMHD)3 Preparation Products And Raw materials

Raw materials

Preparation Products

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MN(TMHD)3 Suppliers

China 67 Germany 3 India 3 Russia 1 Switzerland 1 United Kingdom 1 United States 10 Global 86
Alfa Chemistry
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Ereztech LLC
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Anvia Chemicals, LLC
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14324-99-3, MN(TMHD)3Related Search:

RU(TMHD)3 GD(TMHD)3 TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)ALUMINUM INDIUM (2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) ERBIUM TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)THULIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)COBALT (III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)YTTRIUM(III) PR(TMHD)3 TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)SCANDIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)YTTERBIUM TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)SAMARIUM(III) ND(TMHD)3 3-HEPTENOIC ACID MN(TMHD)3 MANGANESE(II) ACETYLACETONATE Manganic acetylacetonate

  • MN(TMHD)3
  • TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III)
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese (III), (Mn(TMHD)3)
  • TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III) 99% [MN(TMHD)3]
  • Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(II)
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) manganese (III)
  • Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(III)
  • Tris(2,2,6,6tetramethyl-3,5-heptanedionato)manganese(Ⅲ)
  • Manganese tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese
  • Tris(dipivaloylmethanato)manganese
  • Tris(tetramethylheptanedionato)manganese
  • Tris-(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O'')-manganese
  • 2,2,6,6-TetraMethyl-3,5-heptanedionate(III)Manganese
  • MANGANESE(lll) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE
  • Mn(dpm)3
  • Shenvi Hydrogenation Catalyst
  • Manganese(III)tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
  • tris(((Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-yl)oxy)manganese
  • MANGANESE(III) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE
  • -3,5-heptanedionato)mang
  • anese(III)
  • Tris(2,2,6,6-tetramethyL
  • Tris[(2,2,6,6-tetramethyl-5-oxo-3-hepten-3-yl)oxy]manganese
  • -3,5-heptanedionato)manganese(III)
  • manganese(3+) ion tris(2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate)
  • Manganese,tris(2,2,6,6-tetramethyl-3,5-heptanedionato-kO3,kO5)-, (OC-6-11)-
  • Tris (2,2,6,6- tetramethyl -3,5- heptanedioic acid) manganese
  • Manganese tetramethylheptanedionate(Mn(thd)3)
  • manganic tris(2,2,6,6-tetramethylheptane-3,5-dione)
  • 14324-99-3
  • MnCH33CCOCHCOCCH333
  • C33H57MnO6
  • MnC11H19O23
  • ALD Precursors
  • metal beta-diketonate complexes