6-AMINO-2,2'-BIPYRIDINE

Product Name: 6-AMINO-2,2'-BIPYRIDINE
CAS No.: 178039-84-4
Chemical Name: 6-AMINO-2,2'-BIPYRIDINE
Synonyms: 2,2-bipyridin-6-amine;6-Amine-2,2'-bipyridin;6-amino-2,2'-bipyridine;2,2'-bipyridin]-6-amine;6-amino-2,2'-bipyridine;6-pyridin-2-ylpyridin-2-amine
CBNumber: CB42446705
Molecular Formula: C10H9N3
Formula Weight: 171.2
MOL File: 178039-84-4.mol

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6-AMINO-2,2'-BIPYRIDINE Property

storage temp.: Keep in dark place,Inert atmosphere,Room temperature
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

ChemScene

Product number: CS-W018459
Product name: [2,2'-Bipyridin]-6-amine
Purity: >97.0%
Packaging: 100mg
Price: $111
Updated: 2021/12/16

ChemScene

Product number: CS-W018459
Product name: [2,2'-Bipyridin]-6-amine
Purity: >97.0%
Packaging: 250mg
Price: $177
Updated: 2021/12/16

AK Scientific

Product number: CS-W018459
Product name: [2,2'-Bipyridin]-6-amine
Packaging: 1g
Price: $442
Updated: 2021/12/16

ChemScene

Product number: CS-W018459
Product name: [2,2'-Bipyridin]-6-amine
Purity: >97.0%
Packaging: 1g
Price: $442
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0988382
Product name: 2-AMINO-6-(2-PYRIDYL)PYRIDINE
Purity: 95.00%
Packaging: 5MG
Price: $499.08
Updated: 2021/12/16

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6-AMINO-2,2'-BIPYRIDINE Chemical Properties,Usage,Production

Synthesis

10495-73-5

178039-84-4

The general procedure for the synthesis of 6-amino-2,2'-bipyridine from 6-bromo-2,2'-bipyridine was as follows: a mixture of 6-bromo-2,2'-bipyridine (3.0 mmol, 705 mg) and Cu2O (0.01 mmol, 1.0 mg) in ethylene glycol was added to an autoclave. The reaction system was charged with NH3 to 10 atm at a pressure of 110 atm. After completion of the reaction, the mixture was cooled to room temperature, water was added and the aqueous phase was extracted with dichloromethane (DCM). The organic layers were combined, washed with saturated brine and dried over anhydrous MgSO4. After evaporation of the solvent under reduced pressure, the crude product was purified by column chromatography using silica gel as stationary phase and hexane:ethyl acetate (1:1) as eluent to give a white solid product (437 mg, 85% yield). The structure of the product was confirmed by 1H NMR (500 MHz, CDCl3) and 13C NMR (125 MHz, CDCl3): 1H NMR (500 MHz, CDCl3, ppm): δ 8.65 (s, 1H), 8.25 (d, 1H, J = 7.9 Hz), 7.79-7.76 (m, 1H), 7.71- 7.70 (m, 1H), 7.57 (t, 1H, J = 7.1 Hz), 7.26 (t, 1H, J = 7.1 Hz), 6.65 (d, 1H, J = 7.9 Hz), 4.53 (br, 2H); 13C NMR (125 MHz, CDCl3, ppm): δ 157.97, 156.38, 154.57, 149.11, 138.58 149.11, 138.58, 136.73, 123.31, 120.94, 111.59, 108.87.

References

[1] Patent: US2012/323007, 2012, A1. Location in patent: Page/Page column 13
[2] Organometallics, 2014, vol. 33, # 15, p. 4152 - 4155
[3] Journal of the American Chemical Society, 2018, vol. 140, # 39, p. 12451 - 12456
[4] Journal of the Chemical Society, 1938, p. 1662,1669

6-AMINO-2,2'-BIPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-AMINO-2,2'-BIPYRIDINE Suppliers

China 55 India 1 United States 2 Global 58

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178039-84-4, 6-AMINO-2,2'-BIPYRIDINERelated Search:

4-CHLOROQUINAZOLIN-6-AMINE 1H-Pyrazolo[3,4-b]pyridin-6-aMine ethyl 6-aMino-2-MethyliMidazo[1,2-a]pyridine-3-carboxylate (6-AMINO-3-PYRIDINYL)METHANOL 4-(5-CYANO-[2,2']BIPYRIDINYL-6-YL)-PIPERAZINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER 5,6'-DIAMINO-2,2'-BIPYRIDINE 2-(6-AMINOPYRIDIN-2-YL)PYRIDIN-4-AMINE 6-AMINO-2,2'-BIPYRIDINE 6,6'-DIACETAMINO-2,2'-BIPYRIDINE 4-(5-CYANO-[2,2']BIPYRIDINYL-6-YL)-[1,4]DIAZEPANE-1-CARBOXYLIC ACID TERT-BUTYL ESTER 6,6''-AZOBIS(2,2'-BIPYRIDINE) 6-NITRO-2,2'-BIPYRIDINE 2-AMINO-3,4,5-TRICYANO-6-(2-PYRIDYL)PYRIDINE 2,2'-BIPYRIDINE-6,6'-DIAMINE

2,2-bipyridin-6-amine

6-pyridin-2-ylpyridin-2-amine

6-Amine-2,2'-bipyridin

6-amino-2,2'-bipyridine

2,2'-bipyridin]-6-amine

6-amino-2,2'-bipyridine

178039-84-4