ChemicalBook > CAS DataBase List > (4-BROMOTHIAZOL-5-YL)METHANOL

(4-BROMOTHIAZOL-5-YL)METHANOL

Product Name: (4-BROMOTHIAZOL-5-YL)METHANOL
CAS No.: 262444-15-5
Chemical Name: (4-BROMOTHIAZOL-5-YL)METHANOL
Synonyms: (4-Bromothiazol-5-yl);4-Bromothiazole-5-methanol;5-Thiazolemethanol, 4-bromo-;(4-BROMOTHIAZOL-5-YL)METHANOL;(4-broMo-1,3-thiazol-5-yl)Methanol;4,5-dihydro-7H-thieno[2,3-c]pyran-7-one
CBNumber: CB42452801
Molecular Formula: C4H4BrNOS
Formula Weight: 194.05
MOL File: 262444-15-5.mol

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(4-BROMOTHIAZOL-5-YL)METHANOL Property

Boiling point:: 314.4±27.0 °C(Predicted)
Density: 1.899±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 12.89±0.10(Predicted)
Appearance: Light yellow to yellow Solid

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Safety

HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H320Causes eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B699775
Product name: (4-Bromothiazol-5-yl)methanol
Packaging: 500mg
Price: $175
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB144270
Product name: (4-Bromothiazol-5-yl)methanol
Packaging: 250mg
Price: $115
Updated: 2021/12/16

AK Scientific

Product number: W4969
Product name: (4-Bromothiazol-5-yl)methanol
Packaging: 100mg
Price: $128
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB144270
Product name: (4-Bromothiazol-5-yl)methanol
Packaging: 100mg
Price: $58
Updated: 2021/12/16

Ark Pharm

Product number: P000106034
Product name: (4-Bromothiazol-5-yl)methanol
Purity: 95%
Packaging: 100mg
Price: $62
Updated: 2021/12/16

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(4-BROMOTHIAZOL-5-YL)METHANOL Chemical Properties,Usage,Production

Uses

(4-Bromothiazol-5-yl)methanol is a useful research reactant for the syntehsis of ubstituted pyrazoles and imidazoles.

Synthesis

170232-68-5

262444-15-5

At room temperature, 2,4-dibromothiazole-5-methanol (15.0 g, 54.9 mmol) was dissolved in methanol (400 mL) and 10% Pd/C catalyst (1.12 g) and sodium carbonate (13.0 g) were added. The reaction mixture was subjected to 60 psi hydrogen pressure and hydrogenated at room temperature for 2 days. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was washed with ethyl acetate and subsequently concentrated. The concentrated residue was purified by column chromatography (eluent: 30% petroleum ether solution of ethyl acetate) to give 9.3 g of 4-bromo-5-hydroxymethylthiazole as a yellow liquid product.

References

[1] Journal of Labelled Compounds and Radiopharmaceuticals, 2009, vol. 52, # 4, p. 110 - 113
[2] Patent: WO2016/193551, 2016, A1. Location in patent: Page/Page column 32

(4-BROMOTHIAZOL-5-YL)METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (4-BROMOTHIAZOL-5-YL)METHANOL manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: (4-BROMOTHIAZOL-5-YL)METHANOL 262444-15-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 1000KGS
Release date: 2025-11-14

Zhuozhou Wenxi import and Export Co., Ltd

Product: (4-BROMOTHIAZOL-5-YL)METHANOL 262444-15-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: (4-BROMOTHIAZOL-5-YL)METHANOL 262444-15-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

262444-15-5, (4-BROMOTHIAZOL-5-YL)METHANOLRelated Search:

5-Hydroxymethylthiazole 5-Thiazolecarboxylic acid, 4-bromo-, ethyl ester 5-Thiazolecarboxylic acid, 2,4-dibromo- 2,4-Dibromothiazole-5-methanol (4-BROMOTHIAZOL-5-YL)METHANOL Methyl4-bromo-2-chlorothiazole-5-carboxylate Methyl 4-bromo-2-(octadecylamino)thiazole-5- Methyl 4-bromo-2-(2,4- Methyl 4-bromo-2-(4-butylphenyl)thiazole-5- Methyl 2-(benzylamino)-4-bromo-thiazole-5- Methyl 4-bromo-2-(2-chlorobenzylamino)thiazole-5- Methyl 4-bromo-2-(diethylamino)thiazole-5- Methyl 4-bromo-2-(3-chlorophenoxy)thiazole-5- Methyl 4-bromo-2-(thiophen-2-ylsulfonyl)thiazole- Methyl 4-bromo-2-(3-tert- Phenyl 4-bromo-2-(4-chlorophenylthio)thiazole-5- Phenyl 4-bromo-2-(4-methylphenylsulfonyl)thiazole- Methyl 4-bromo-2-(4-chlorophenylsulfonyl)thiazole-

(4-Bromothiazol-5-yl)

(4-BROMOTHIAZOL-5-YL)METHANOL

(4-broMo-1,3-thiazol-5-yl)Methanol

4,5-dihydro-7H-thieno[2,3-c]pyran-7-one

5-Thiazolemethanol, 4-bromo-

4-Bromothiazole-5-methanol

262444-15-5