4-(Morpholinomethyl)phenylboronic acid

Product Name: 4-(Morpholinomethyl)phenylboronic acid
CAS No.: 279262-23-6
Chemical Name: 4-(Morpholinomethyl)phenylboronic acid
Synonyms: inomethyL;4-(MorphoL;4-(Morpholinomethyl)phenylboronic acid;4-(Morpholinylmethyl)phenylboronic acid;4-(Morpholinomethyl)benzeneboronic Acid;3)4-(MORPHOLINOMETHYL)PHENYLBORONIC ACID;4-(morpholin-4-ylmethyl)phenyl]boronicaci;[4-(morpholin-4-ylmethyl)phenyl]boronic acid;[4-(Morpholinomethyl)phenyl]boronic acid 98%;B-[4-(4-morpholinylmethyl)phenyl]Boronic acid
CBNumber: CB42470843
Molecular Formula: C11H16BNO3
Formula Weight: 221.06
MOL File: 279262-23-6.mol

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4-(Morpholinomethyl)phenylboronic acid Property

Melting point:: 85 °C
Boiling point:: 382.3±52.0 °C(Predicted)
Density: 1.20
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: powder to crystal
pka: 8.60±0.16(Predicted)
color: White to Light yellow to Light orange

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Safety

HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CDS012386
Product name: [4-(morpholinomethyl)phenyl]boronic acid
Purity: AldrichCPR
Packaging: 100MG
Price: $259
Updated: 2025/07/31

TCI Chemical

Product number: M3128
Product name: 4-(Morpholinomethyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $188
Updated: 2025/07/31

TCI Chemical

Product number: M3128
Product name: 4-(Morpholinomethyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $578
Updated: 2025/07/31

TRC

Product number: M733163
Product name: 4-(Morpholinylmethyl)phenylboronicAcid
Packaging: 50mg
Price: $45
Updated: 2021/12/16

AK Scientific

Product number: J94870
Product name: 4-(Morpholinylmethyl)phenylboronicacid
Packaging: 1g
Price: $75
Updated: 2021/12/16

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4-(Morpholinomethyl)phenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

4-(Morpholinomethyl)phenylboronic acid is a solid, it is extremely flammable in the presence of oxidizing materials.

Uses

4-(Morpholinomethyl)phenylboronic acid is commonly used in synthetic/analytical chemistry.

Synthesis

110-91-8

68162-47-0

279262-23-6

A) General procedure for the synthesis of 4-morpholinomethylphenylboronic acid: morpholine (0.304 mL) was added to a solution of acetonitrile (10 mL) containing 4-(bromomethyl)phenylboronic acid (500 mg) and potassium carbonate (643 mg). The reaction mixture was stirred at room temperature for 60 hours. Upon completion of the reaction, water was added to the mixture and extracted with ethyl acetate. The organic layer was washed with saturated brine and subsequently dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The resulting solid was washed with diisopropyl ether and ethyl acetate to give the final 4-morpholinomethylphenylboronic acid (449 mg). Mass spectrometry analysis (ESI+): [M + H]+ calculated value 222.1, measured value 222.2.

References

[1] Journal of Organic Chemistry, 2002, vol. 67, # 1, p. 3 - 15
[2] Patent: WO2004/81008, 2004, A1. Location in patent: Page 101-102
[3] Patent: EP2857400, 2015, A1. Location in patent: Paragraph 0843
[4] Patent: WO2017/137535, 2017, A1. Location in patent: Page/Page column 129
[5] Dyes and Pigments, 2018, vol. 149, p. 356 - 362

4-(Morpholinomethyl)phenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(Morpholinomethyl)phenylboronic acid Suppliers

Americas 1 China 101 Europe 1 Germany 2 India 3 Japan 1 United Kingdom 3 United States 14 Global 126

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TOKYO CHEMICAL INDUSTRY CO., LTD.

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View Lastest Price from 4-(Morpholinomethyl)phenylboronic acid manufacturers

Career Henan Chemical Co

Product: 4-(Morpholinomethyl)phenylboronic acid 279262-23-6
Price: US $500.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2018-08-04

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279262-23-6

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