ChemicalBook > CAS DataBase List > RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
Reaction- Product Name
- RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
- CAS No.
- 12289-94-0
- Chemical Name
- RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
- Synonyms
- Ru(Me-allyl)2(COD);Bis(2-methylallyl);-1,5-cyclooctadieneruthenium (II);BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&;BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&;Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium;(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium;(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)
- CBNumber
- CB4264385
- Molecular Formula
- C16H18Ru
- Formula Weight
- 311.39
- MOL File
- 12289-94-0.mol
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Property
- Melting point:
- 81-85 °C
- Boiling point:
- 100°C/0.05mmHg
- storage temp.
- -20°C
- form
- Powder
- color
- tan to brown
- Water Solubility
- It is soluble in water.
- Sensitive
- Air & Moisture Sensitive
- Stability:
- store cold
- InChIKey
- KMYRLYRRLMVJNK-XMWBDPRZSA-N
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Safety
- Hazard Codes
- Xn,F
- Risk Statements
- 20/21/22-15
- Safety Statements
- 36/37-43
- RIDADR
- UN3395
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 4.3
- PackingGroup
- III
- HS Code
- 28439000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H261In contact with water releases flammable gas
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P402+P404Store in a dry place. Store in a closed container.
P422Store contents under …
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N-Bromosuccinimide Price
Alfa Aesar
- Product number
- H26891
- Product name
- Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)
- Packaging
- 1g
- Price
- $159
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0046
- Product name
- Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
- Packaging
- 250mg
- Price
- $54
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0046
- Product name
- Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
- Packaging
- 1g
- Price
- $156
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0046
- Product name
- Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
- Packaging
- 5g
- Price
- $624
- Updated
- 2024/03/01
TRC
- Product number
- M287223
- Product name
- Bis(2-methylallyl)-1,5-cyclooctadieneruthenium(ii)
- Packaging
- 100mg
- Price
- $140
- Updated
- 2021/12/16
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Chemical Properties,Usage,Production
Reaction
- Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
- β-ketoester reduction.
- Anti-Markovnikov addition of amides to alkynes.
- Anti-Markovnikov hydroamination of vinylarenes.
- Catalyst for the addition of amides to alkynes.
Chemical Properties
tan/brown powder
Uses
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
General Description
This product has been enhanced for catalytic efficiency.
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Preparation Products And Raw materials
Raw materials
Preparation Products
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Suppliers
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View Lastest Price from RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) manufacturers
Career Henan Chemical Co
- Product
- RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) 12289-94-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-07-03
12289-94-0, RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)Related Search:
1,5-Cyclooctadiene
BIS(ETHYLCYCLOPENTADIENYL)RUTHENIUM(II)
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)