RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

Reaction

Product Name: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
CAS No.: 12289-94-0
Chemical Name: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
Synonyms: Ru(Me-allyl)2(COD);Bis(2-methylallyl);-1,5-cyclooctadieneruthenium (II);BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&;BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&;Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium;(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium;(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)
CBNumber: CB4264385
Molecular Formula: C16H18Ru
Formula Weight: 311.39
MOL File: 12289-94-0.mol

More

Less

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Property

Melting point:: 81-85 °C
Boiling point:: 100°C/0.05mmHg
storage temp.: -20°C
form: Powder
color: tan to brown
Water Solubility: It is soluble in water.
Sensitive: Air & Moisture Sensitive
Stability:: store cold
InChI: InChI=1S/C8H8.2C4H5.Ru/c1-2-4-6-8-7-5-3-1;2*1-4(2)3;/h1-2,7-8H2;2*1-2H,3H3;/q;2*-1;+2
InChIKey: KMYRLYRRLMVJNK-XMWBDPRZSA-N
SMILES: CC12=C[Ru+2]345671(C=C3(C)[CH-]4)(C1CCC5=C6CCC7=1)[CH-]2

More

Less

Safety

Hazard Codes: Xn,F
Risk Statements: 20/21/22-15
Safety Statements: 36/37-43
RIDADR: UN3395
WGK Germany: 3
TSCA: No
HazardClass: 4.3
PackingGroup: III
HS Code: 28439000
Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications: Water-react 3

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H261In contact with water releases flammable gas

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P402+P404Store in a dry place. Store in a closed container.

P422Store contents under …

More

Less

N-Bromosuccinimide Price

Strem Chemicals

Product number: 44-0046
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging: 250mg
Price: $54
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0046
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging: 1g
Price: $156
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0046
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging: 5g
Price: $624
Updated: 2024/03/01

TRC

Product number: M287223
Product name: Bis(2-methylallyl)-1,5-cyclooctadieneruthenium(ii)
Packaging: 100mg
Price: $140
Updated: 2021/12/16

AK Scientific

Product number: 4421AA
Product name: Bis(2-methylallyl)-1,5-cyclooctadieneruthenium(II)
Packaging: 1g
Price: $447
Updated: 2021/12/16

More

Less

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Chemical Properties,Usage,Production

Reaction

Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
β-ketoester reduction.
Anti-Markovnikov addition of amides to alkynes.
Anti-Markovnikov hydroamination of vinylarenes.
Catalyst for the addition of amides to alkynes.

Chemical Properties

tan/brown powder

Uses

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

This product has been enhanced for catalytic efficiency.

reaction suitability

core: ruthenium
reagent type: catalyst

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Suppliers

Belgium 2 China 98 Europe 2 France 1 Germany 2 Italy 1 Japan 1 Singapore 1 Switzerland 1 United States 12 Global 121

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9815
Advantage: 79

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 291
Advantage: 62

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

More

Less

View Lastest Price from RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) 12289-94-0
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

Career Henan Chemical Co

Product: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) 12289-94-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

12289-94-0, RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)Related Search:

1,5-Cyclooctadiene BIS(ETHYLCYCLOPENTADIENYL)RUTHENIUM(II) RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)RUTHENIUM(II)

BIS-(2-METHYLALLYL)CYCLOOCTA-1,5-DIENE RUTHENIUM (II) COMPLEX

BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&

BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&

RutheniumCyclooctadieneBis(2,2,6,6-Tetramethylheptanedionate)

bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(ii),min.

Bis-(2-methylallyl)cycloocta-1,5-diene ruthenium(II) complex, 30-32% Ru

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II),min.97%

Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium

Bis-(2-Methylallyl)cycloocta-1,5-diene rutheniuM(II) coMplex, 30-32% Ru 250MG

Bis(2-Methylallyl)(1,5-cyclooctadiene)rutheniuM(II),97%

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)

Bis(2-Methylallyl)(1,5-cyclooctadiene)rutheniuM(Ⅱ), 32% Ru, Product of UMicore

RutheniuM, [(1,2,5,6-η)-1,5-cyclooctadiene]bis[(1,2,3-η)-2-Methyl-2-propenyl]-(9CI)

RutheniuM, [(1,2,5,6-h)-1,5-cyclooctadiene]bis[(1,2,3-h)-2-Methyl-2-propenyl]- (9CI)

(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium

Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium

Ru(Me-allyl)2(COD)

(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene

-1,5-cyclooctadieneruthenium (II)

Bis(2-methylallyl)

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), 32% Ru, Product of Umicore

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) ISO 9001：2015 REACH

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANED...

(1,2,5,6-η)-1,5-cyclooctadiene]bis[(1,2,3-η)-2-methyl-2-propenyl]-Ruthenium

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(ll)

12289-94-0

C16H26Ru

Rumethylallyl2COD

C4H72C8H12Ru

New Products for Chemical Synthesis May/June 2007

Ru Catalysts

Catalysis and Inorganic Chemistry

organometallic complex

Ru