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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

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Product Name
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
CAS No.
12289-94-0
Chemical Name
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
Synonyms
Ru(Me-allyl)2(COD);Bis(2-methylallyl);-1,5-cyclooctadieneruthenium (II);BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&;BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&;Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium;(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium;(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)
CBNumber
CB4264385
Molecular Formula
C16H18Ru
Formula Weight
311.39
MOL File
12289-94-0.mol
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Property

Melting point:
81-85 °C
Boiling point:
100°C/0.05mmHg
storage temp. 
-20°C
form 
Powder
color 
tan to brown
Water Solubility 
It is soluble in water.
Sensitive 
Air & Moisture Sensitive
Stability:
store cold
InChIKey
KMYRLYRRLMVJNK-XMWBDPRZSA-N
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Safety

Hazard Codes 
Xn,F
Risk Statements 
20/21/22-15
Safety Statements 
36/37-43
RIDADR 
UN3395
WGK Germany 
3
TSCA 
No
HazardClass 
4.3
PackingGroup 
III
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H261In contact with water releases flammable gas

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P402+P404Store in a dry place. Store in a closed container.

P422Store contents under …

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N-Bromosuccinimide Price

Alfa Aesar
Product number
H26891
Product name
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)
Packaging
1g
Price
$159
Updated
2024/03/01
Strem Chemicals
Product number
44-0046
Product name
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging
250mg
Price
$54
Updated
2024/03/01
Strem Chemicals
Product number
44-0046
Product name
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging
1g
Price
$156
Updated
2024/03/01
Strem Chemicals
Product number
44-0046
Product name
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging
5g
Price
$624
Updated
2024/03/01
TRC
Product number
M287223
Product name
Bis(2-methylallyl)-1,5-cyclooctadieneruthenium(ii)
Packaging
100mg
Price
$140
Updated
2021/12/16
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Chemical Properties,Usage,Production

Reaction

  1. Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
  2. β-ketoester reduction.
  3. Anti-Markovnikov addition of amides to alkynes.
  4. Anti-Markovnikov hydroamination of vinylarenes.
  5. Catalyst for the addition of amides to alkynes.

Chemical Properties

tan/brown powder

Uses

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

This product has been enhanced for catalytic efficiency.

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Preparation Products And Raw materials

Raw materials

Preparation Products

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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Suppliers

Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19172
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6134
Advantage
55
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View Lastest Price from RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) manufacturers

Career Henan Chemical Co
Product
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) 12289-94-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

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