RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

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Product Name: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
CAS No.: 12289-94-0
Chemical Name: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
Synonyms: Ru(Me-allyl)2(COD);Bis(2-methylallyl);-1,5-cyclooctadieneruthenium (II);BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&;BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&;Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium;(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium;(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene;Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)
CBNumber: CB4264385
Molecular Formula: C16H18Ru
Formula Weight: 311.39
MOL File: 12289-94-0.mol

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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Property

Melting point:: 81-85 °C
Boiling point:: 100°C/0.05mmHg
storage temp.: -20°C
form: Powder
color: tan to brown
Water Solubility: It is soluble in water.
Sensitive: Air & Moisture Sensitive
Stability:: store cold
InChIKey: KMYRLYRRLMVJNK-XMWBDPRZSA-N

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Safety

Hazard Codes: Xn,F
Risk Statements: 20/21/22-15
Safety Statements: 36/37-43
RIDADR: UN3395
WGK Germany: 3
TSCA: No
HazardClass: 4.3
PackingGroup: III
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H261In contact with water releases flammable gas

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P402+P404Store in a dry place. Store in a closed container.

P422Store contents under …

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N-Bromosuccinimide Price

Alfa Aesar

Product number: H26891
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)
Packaging: 1g
Price: $159
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0046
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging: 250mg
Price: $54
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0046
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging: 1g
Price: $156
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0046
Product name: Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
Packaging: 5g
Price: $624
Updated: 2024/03/01

TRC

Product number: M287223
Product name: Bis(2-methylallyl)-1,5-cyclooctadieneruthenium(ii)
Packaging: 100mg
Price: $140
Updated: 2021/12/16

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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Chemical Properties,Usage,Production

Reaction

Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
β-ketoester reduction.
Anti-Markovnikov addition of amides to alkynes.
Anti-Markovnikov hydroamination of vinylarenes.
Catalyst for the addition of amides to alkynes.

Chemical Properties

tan/brown powder

Uses

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

This product has been enhanced for catalytic efficiency.

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) manufacturers

Career Henan Chemical Co

Product: RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) 12289-94-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), 32% Ru, Product of Umicore

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) ISO 9001：2015 REACH

RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANED...

(1,2,5,6-η)-1,5-cyclooctadiene]bis[(1,2,3-η)-2-methyl-2-propenyl]-Ruthenium

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