4-(Methylsulfonyl)phenylhydrazine hydrochloride

Product Name: 4-(Methylsulfonyl)phenylhydrazine hydrochloride
CAS No.: 17852-67-4
Chemical Name: 4-(Methylsulfonyl)phenylhydrazine hydrochloride
Synonyms: TIMTEC-BB SBB003335;4-Hydrazino-1-(methylsulphonyl)benzene;4-METHYLSULPHONYLPHENYLHYDRAZINE HYDROCHLORIDE;4-(Methylsulfonyl)phenylhydrazine hydrochloride;5-(4-methylsulfonylphenyl)-2-furancarboxylic acid;(4-Methanesulfonyl-phenyl)-hydrazine hydrochloride;4-(Methylsulfonyl)phenylhydrazine hydrochloride,95%;4-Hydrazino-1-(methylsulfonyl)benzene hydrochloride;4-Hydrazino-1-(methylsulphonyl)benzene hydrochloride;4-(Methylsulfonyl)phenylhydrazine hydrochloride, 95% 2.5GR
CBNumber: CB4273462
Molecular Formula: C7H11ClN2O2S
Formula Weight: 222.69
MOL File: 17852-67-4.mol

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4-(Methylsulfonyl)phenylhydrazine hydrochloride Property

Melting point:: 202 °C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Crystalline Powder
color: Off-white to light yellow
Water Solubility: SOLUBLE

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Safety

Safety Statements: 22-24/25
HS Code: 29280000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC

Product number: M339205
Product name: (4-(Methylsulfonyl)phenyl)hydrazineHydrochloride
Packaging: 100mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: W3890
Product name: [4-(Methylsulfonyl)phenyl]hydrazinehydrochloride
Packaging: 25g
Price: $87
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8663-5-X4
Product name: 4-Hydrazino-1-(methylsulfonyl)benzene hydrochloride
Purity: 98%
Packaging: 25g
Price: $104
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK252528
Product name: 4-Methylsulfonylphenylhydrazinehydrochloride
Purity: 95%
Packaging: 1g
Price: $72
Updated: 2021/12/16

AK Scientific

Product number: W3890
Product name: [4-(Methylsulfonyl)phenyl]hydrazinehydrochloride
Packaging: 1g
Price: $14
Updated: 2021/12/16

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4-(Methylsulfonyl)phenylhydrazine hydrochloride Chemical Properties,Usage,Production

Chemical Properties

off-white to light yellow crystalline powder

Synthesis

5470-49-5

17852-67-4

General procedure for the synthesis of 4-(methylsulfonyl)phenylhydrazine hydrochloride from 4-methylsulfonylaniline: 100 mL of hydrochloric acid was added to a 500 mL four-necked flask, and the temperature inside the flask was cooled to -10 °C or lower by passing the flask through an ice-water bath and ensuring that the temperature did not exceed -10 °C. Subsequently, 10.27 g (0.06 mol) of 4-(methylsulfonyl)aniline was added and dissolved. After the exothermic reaction ceased, 4.47 g (0.065 mol) of sodium nitrite was slowly added and 30 g of distilled water was added dropwise over a period of 1 hour while keeping the temperature of the flask below -10°C. After completion of the addition, the addition of 67.7 g (0.30 mol) of tin chloride dihydrate dissolved in 60 mL of hydrochloric acid was continued dropwise over 1 h while the reaction temperature was strictly controlled at -10 °C or lower. Upon completion of the reaction, the solid product was collected by filtration and dried at 60 °C for 12 h using a vacuum drier to afford 4-(methylsulfonyl)phenylhydrazine hydrochloride (Intermediate G1). This step was based on a 67.9 mol% yield of 4-(methylsulfonyl)phenylhydrazine.

References

[1] Patent: JP2018/95798, 2018, A. Location in patent: Paragraph 0081; 0084

4-(Methylsulfonyl)phenylhydrazine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(Methylsulfonyl)phenylhydrazine hydrochloride Suppliers

Belgium 1 China 47 France 1 Germany 2 India 4 Japan 1 Switzerland 1 United Kingdom 4 United States 16 Global 77

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Shanghai Jovan Biochemical Technology Co. Ltd.

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View Lastest Price from 4-(Methylsulfonyl)phenylhydrazine hydrochloride manufacturers

Career Henan Chemica Co

Product: 4-(Methylsulfonyl)phenylhydrazine hydrochloride 17852-67-4
Price: US $1.80-0.80/IU
Min. Order: 1KG
Purity: 95%~99.99%
Supply Ability: 10 MT/ Month
Release date: 2020-11-06

17852-67-4, 4-(Methylsulfonyl)phenylhydrazine hydrochlorideRelated Search:

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4-METHYLSULPHONYLPHENYLHYDRAZINE HYDROCHLORIDE

TIMTEC-BB SBB003335

4-(Methylsulfonyl)phenylhydrazine hydrochloride,95%

4-(Methylsulfonyl)phenylhydrazine hydrochloride

4-Hydrazino-1-(methylsulphonyl)benzene

4-Hydrazino-1-(methylsulphonyl)benzene hydrochloride

4-(Methylsulfonyl)phenylhydrazine hydrochloride, 95% 2.5GR

(4-Methanesulfonyl-phenyl)-hydrazine hydrochloride

1-Hydrazino-4-(methylsulphonyl)benzene hydrochloride, 4-Hydrazinophenyl methyl sulphone hydrochloride

4-Hydrazino-1-(methylsulfonyl)benzene hydrochloride

5-(4-methylsulfonylphenyl)-2-furancarboxylic acid

Hydrazine, [4-(methylsulfonyl)phenyl]-, hydrochloride (1:1)

(4-(Methylsulfonyl)phenyl)hydrazine hydrochloride - [M46468]

17852-67-4

C7H10N2O2SHCl