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D-Glucosamine hydrochloride

Product Name
D-Glucosamine hydrochloride
CAS No.
66-84-2
Chemical Name
D-Glucosamine hydrochloride
Synonyms
GLUCOSAMINE HYDROCHLORIDE;GLUCOSAMINE HCL;D-GLUCOSAMINE HCL;D-Glucosamine Salt;Glucosamine for system suitability CRS;2-amino-2-deoxy-D-glucose hydrochloride (1:1);cosamin;NSC 758;D-GLCN HCL;NSC 234443
CBNumber
CB2181059
Molecular Formula
C6H14ClNO5
Formula Weight
215.63
MOL File
66-84-2.mol
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D-Glucosamine hydrochloride Property

Melting point:
190-194 °C (dec.)(lit.)
alpha 
72.5 º (c=2, H2O, 5hrs.)
refractive index 
72 ° (C=1, H2O)
storage temp. 
2-8°C
solubility 
H2O: 0.1 g/mL, clear, colorless
form 
crystalline
color 
White
Water Solubility 
soluble
Merck 
14,4458
BRN 
4157370
Stability:
Stable. Incompatible with strong oxidizing agents. Combustible.
InChI
InChI=1/C6H13NO5.ClH/c7-3-5(10)4(9)2(1-8)12-6(3)11;/h2-6,8-11H,1,7H2;1H/t2-,3-,4-,5-,6?;/s3
InChIKey
QKPLRMLTKYXDST-LPRXMDNASA-N
SMILES
[C@H]1(CO)OC([C@H](N)[C@@H](O)[C@@H]1O)O.Cl |&1:0,5,7,9,r|
LogP
-2.375 (est)
CAS DataBase Reference
66-84-2(CAS DataBase Reference)
EPA Substance Registry System
D-Glucose, 2-amino-2-deoxy-, hydrochloride (66-84-2)
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Safety

Hazard Codes 
F,Xi,Xn
Risk Statements 
21-36/38-46-62-63
Safety Statements 
24/25-53-36/37-26-25
WGK Germany 
2
RTECS 
LZ6665000
3-10
Hazard Note 
Highly Flammable
TSCA 
Yes
HS Code 
29329985
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
G1514
Product name
D-(+)-Glucosamine hydrochloride
Purity
≥99%, BioReagent, suitable for cell culture
Packaging
100g
Price
$75.7
Updated
2023/01/07
Sigma-Aldrich
Product number
1294207
Product name
Glucosamine hydrochloride
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
200mg
Price
$361
Updated
2022/05/15
TCI Chemical
Product number
G0044
Product name
D-(+)-Glucosamine Hydrochloride
Purity
>98.0%(T)
Packaging
25g
Price
$24
Updated
2023/01/07
TCI Chemical
Product number
G0044
Product name
D-(+)-Glucosamine Hydrochloride
Purity
>98.0%(T)
Packaging
500g
Price
$136
Updated
2023/01/07
Alfa Aesar
Product number
A15532
Product name
D-Glucosamine hydrochloride, 98+%
Packaging
50g
Price
$33.81
Updated
2023/01/06
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D-Glucosamine hydrochloride Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

Novel application of D-Glucosamine hydrochloride to prepare medical agent for treating vertigo. Found in chitin, in mucoproteins, and in mucopolysaccharides. Antiarthritic. Recent studies show that its chondroprotective activity is related to its antiapoptic properties.

Uses

glucosamine hydrochloride (glucosamine HCl) is used to adjust the pH of a formulation. It also has anti-static and hair-conditioning properties.

Uses

Novel application of glucosamine is to prepare medical agent for treating vertigo. It is used as food ingredients and additives, raw material for anti cancer and antibiotic drugs.

General Description

Glucosamine, an amino sugar is generated form glucose and glutamine and is naturally produced in the body. Glucosamine, a endogenous amino monosaccharide is the major source of glucosamine-6-phosphate and n-acetylglucosamine.

Biochem/physiol Actions

Glucosamine is preferred as a nutritional supplement?for individuals with osteoarthritis. It is used as a building block for the production of proteoglycans?and?glycosaminoglycans.

Purification Methods

Crystallise the hydrochloride from 3M HCl, water, and finally water/EtOH/acetone as for galactosamine hydrochloride. [Purchase & Braun Org Synth 26 36 1946, Stacey & Webber Methods in Carbohydrate Chemistry I 228 1962, Academic Press.] The salt has also been purified by dissolving in the minimum volume of boiling H2O (charcoal), filtering and adding a large excess of 95% EtOH (~4 volumes) and stirring vigorously for several hours. Collect the crystals after 4-6hours to give  anomer which mutarotates ] D +100o to +72o (equilibrium, c 1, H2O). A large amount of the -anomer stays in solution. This can be precipitated from the filtrate by adding excess Et2O. The mixture of -plus -anomers has [] D +68.8o (c 4.75, H2O, mutarotating to +70.1o)[Leaback Biochemical Preparations 10 118 1963]. Note that if Et2NH is used instead of Et3N, conversion to the -anomer can be complete (see above). [Stacey et al. Methods in Carbohydrate Chemistry I 3061962, Academic Press; Beilstein 4 IV 2018.]

D-Glucosamine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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D-Glucosamine hydrochloride Suppliers

QINGDAO WANYUAN MOUNTAIN BIOTECH CO.,LTD
Tel
0532-0532-66720179 15092119928
Email
cuiningning@bionutrichem.com
Country
China
ProdList
112
Advantage
58
Wuhan Penglei Biological Technology Co., Ltd.
Tel
18672616696
Email
229092275@qq.com
Country
China
ProdList
703
Advantage
58
Shanghai Yingxin laboratory equipment Co., Ltd
Tel
021-59178156 17002132182
Email
359382369@qq.com
Country
China
ProdList
10401
Advantage
58
Hubei Hicks Biochemical Co., Ltd
Tel
17555092222
Email
17555092222@163.com
Country
China
ProdList
1293
Advantage
58
Shandong Aicai Biotechnology Co. , Ltd.
Tel
135-37016375 13573016375
Email
3358761976@qq.com
Country
China
ProdList
334
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
18621169107
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40242
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3577
Advantage
66
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15861
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30133
Advantage
84
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View Lastest Price from D-Glucosamine hydrochloride manufacturers

Hebei Dangtong Import and export Co LTD
Product
D-Glucosamine hydrochloride 66-84-2
Price
US $8.00-7.00/kg
Min. Order
10kg
Purity
99%
Supply Ability
100Tons
Release date
2023-03-03
Shanghai CRM New Material Technology Co., LTD
Product
D-Glucosamine hydrochloride 66-84-2
Price
US $10.00-15.00/g
Min. Order
10g
Purity
99%
Supply Ability
2546245
Release date
2022-11-03
Hebei Crovell Biotech Co Ltd
Product
Glucosamine Hydrochloride 66-84-2
Price
US $1.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2021-08-02

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