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TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0)

Product Name
TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0)
CAS No.
14221-00-2
Chemical Name
TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0)
Synonyms
[(PhO)3P]4Ni;nickel,triphenylphosphite;Tetrakis(triphenyl phosphite)nickel;Tetrakis(triphenoxyphosphine)nickel;Nickel tetrakis(triphenoxyphosphine);tetrakis(triphenyl phosphite)nickel(O);TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0);Tetrakis(triphenyl phosphite)nickel(0),95%;Tetrakis(triphenyl phosphite)nickel(0), 95% 1GR;TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) ISO 9001:2015 REACH
CBNumber
CB4288127
Molecular Formula
C72H60NiO12P4
Formula Weight
1299.83
MOL File
14221-00-2.mol
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TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Property

Melting point:
145 °C (dec.)(lit.)
storage temp. 
2-8°C
solubility 
sol THF, toluene.
form 
solid
InChI
InChI=1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;/h4*1-15H;
InChIKey
PGXCIAAANFTEKX-UHFFFAOYSA-N
EPA Substance Registry System
Nickel, tetrakis(triphenyl phosphite-.kappa.P)-, (T-4)- (14221-00-2)
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-40-43
Safety Statements 
26-36/37
WGK Germany 
3
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
288063
Product name
Tetrakis(triphenylphosphite)nickel(0)
Packaging
1g
Price
$131.56
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
OGM0000891
Product name
TETRAKIS(TRIPHENYLPHOSPHITE)NICKEL(0)
Purity
95.00%
Packaging
1G
Price
$656.1
Updated
2021/12/16
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TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Chemical Properties,Usage,Production

Chemical Properties

white to off-white powder

Uses

Catalyst for alkene and alkyne hydrocyanation and styrenedimerization

Preparation

Tetrakis(triphenyl phosphite)nickel(0) can be prepared by treating Nickel(II) Acetylacetonate with Sodium Borohydride and Triphenyl Phosphite.[1]

reaction suitability

core: nickel
reagent type: catalyst

storage

Tetrakis(triphenyl phosphite)nickel(0) is a cancer suspect agent; is air sensitive and should be handled using Schlenk or glove-box techniques.

References

1. McLaughlin, J. R. Inorg. Nucl. Chem. Lett. 1973, 9, 565.

TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) Suppliers

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14221-00-2, TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0)Related Search:


  • [(PhO)3P]4Ni
  • Nickel tetrakis(triphenoxyphosphine)
  • Tetrakis(triphenoxyphosphine)nickel
  • Tetrakis(triphenyl phosphite)nickel
  • TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0)
  • tetrakis(triphenyl phosphite)nickel(O)
  • Tetrakis(triphenyl phosphite)nickel(0),95%
  • TETRAKIS(TRIPHENYL PHOSPHITE)NICKEL(0) ISO 9001:2015 REACH
  • nickel,triphenylphosphite
  • Tetrakis(triphenyl phosphite)nickel(0), 95% 1GR
  • 14221-00-2
  • C72H60NiO12P4
  • C6H5O3P4Ni
  • Catalysis and Inorganic Chemistry
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis