ChemicalBook > CAS DataBase List > ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID

ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID

Product Name
ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID
CAS No.
31842-01-0
Chemical Name
ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID
Synonyms
k4277;flosin;Praxis;flosint;Bor-ind;Reumofe;isindone;Reumofene;INDOPROFEN;Aids025462
CBNumber
CB4297426
Molecular Formula
C17H15NO3
Formula Weight
281.31
MOL File
31842-01-0.mol
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ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID Property

Melting point:
213-214°
Boiling point:
423.97°C (rough estimate)
Density 
1.1302 (rough estimate)
refractive index 
1.4500 (estimate)
storage temp. 
2-8°C
solubility 
Methanol (Slightly, Sonicated)
form 
Solid
pka
pKa 5.8 (Uncertain)
color 
White to off-white
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Safety

Hazard Codes 
T
Risk Statements 
25-40
Safety Statements 
22-36/37/39-45
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
RTECS 
MU6645000
Toxicity
LD50 in rats (mg/kg): 58.66 i.v.; 60.83 orally (Buttinoni)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I3132
Product name
Indoprofen
Purity
analytical standard
Packaging
1g
Price
$40.5
Updated
2022/05/15
TRC
Product number
I645000
Product name
Indoprofen
Packaging
10mg
Price
$110
Updated
2021/12/16
TRC
Product number
I645000
Product name
Indoprofen
Packaging
250mg
Price
$715
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
API0008560
Product name
INDOPROFEN
Purity
95.00%
Packaging
1G
Price
$525
Updated
2021/12/16
AK Scientific
Product number
X6838
Product name
Indoprofen
Packaging
100mg
Price
$495
Updated
2021/12/16
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ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID Chemical Properties,Usage,Production

Chemical Properties

ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID is Off-White Solid

Originator

Flosint,Carlo Erba,Italy,1976

Uses

ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID is a non-steroidal anti-inflammatory agent used for treatment of pain and inflammation

Uses

analgesic, antiinflammatory

Definition

ChEBI: A monocarboxylic acid that is propionic acid in which one of the hydrogens at position 2 is substituted by a 4-(1-oxo-1,3-dihydroisoindol-2-yl)phenyl group. Initially used as an anti-inflammatory and analgesic, it was withdrawn from the market due to causi g severe gastrointestinal bleeding. It has been subsequently found to increase production of the survival motor neuron protein.

Manufacturing Process

The mixture of 7.9 g of ethyl α-(4-aminophenyl)propionate and 8.3 g of ethyl 2-chloromethylbenzoate is refluxed under nitrogen for one hour. The residue is recrystallized from hexane, to yield the ethyl α-[4-(1-oxo-isoindolino)-phenyl]- propionate of the formulamelting at 104° to 106°C. The mixture of 4.5 g thereof, 1.6 g of potassiumhydroxide, 2 ml of water and 250 ml of ethanol is refluxed under nitrogen for 2 hours and evaporated under reduced pressure. The residue is taken up in water, the solution washed with chloroform, acidified with hydrochloric acid and extracted with ethyl acetate. The extract is dried, evaporated and the residue recrystallized from ethyl acetate, to yield the corresponding free acid melting at 208° to 210°C. (Procedure reported in US Patent 3,767,805.)

brand name

Endyne;Fenint;Flogosan;Flosine;Flosyn;K 4277;Miantor.

Therapeutic Function

Antiinflammatory

World Health Organization (WHO)

Indoprofen, a nonsteroidal anti-inflammatory agent, was introduced in 1976 for the treatment of rheumatic disorders. By 1983 its use had been associated with serious adverse effects, some of which were fatal. This led to its withdrawal in the United Kingdom and Cyprus. In 1984 reports of intestinal tumours in rats led to the drug's temporary withdrawal in Germany and Italy. This was followed immediately by the suspension of marketing worldwide by the major manufacturer.

ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID Suppliers

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View Lastest Price from ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID manufacturers

Career Henan Chemical Co
Product
ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID 31842-01-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-03-05

31842-01-0, ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACIDRelated Search:


  • ALPHA-METHYL-P-[1-OXO-2-ISOINDOLINYL]-BENZENEACETIC ACID
  • 1-oxo-2-(p-((alpha-methyl)carboxymethyl)phenyl)isoindoline
  • 2-(4-(1-carboxyethyl)phenyl)-1-isoindolinone
  • 2-(p-(1-oxo-2-isoindolinyl)phenyl)-propionicaci
  • 4-(1,3-dihydro-1-oxo-2h-isoindol-2-yl)-alpha-methyl-benzeneaceticaci
  • 4-(1,3-dihydro-1-oxo-2h-isoindol-2-yl)-alpha-methylbenzeneaceticacid
  • alpha-(4-(1-oxo-2-isoindolinyl)phenyl)-propionicaci
  • alpha-(4-(1-oxo-2-iso-indolinyl)-phenyl)-propionicacid
  • flosin
  • INDOPROFEN
  • flosint
  • isindone
  • k4277
  • p-(1-oxo-2-isoindolinyl)-hydratropicaci
  • p-(1-oxo-2-isoindolinyl)-hydratropicacid
  • α-methyl-p-(1-oxo-2-isoindolinyl)benzeneacetic acid
  • 1-Oxo-2-[p-[(a-methyl)carboxymethyl]phenyl]isoindoline
  • 2-[4-(1-Oxo-2-isoindolinyl)phenyl]propanoic Acid
  • 4-(1,3-Dihydro-1-oxo-2H-isoindol-2-yl)-a-methylbenzeneacetic Acid
  • Bor-ind
  • Praxis
  • Reumofe
  • (±)-Indoprofe
  • Indoprofen Solution, 100ppm
  • 2-[p-(1-Oxo-2-isoindolinyl)phenyl]propionic acid
  • 4-(1,3-Dihydro-1-oxo-2H-isoindol-2-yl)-α-methylbenzeneacetic acid
  • Aids025462
  • Aids-025462
  • Reumofene
  • Indoprofen,α-Methyl-p-(1-oxo-2-isoindolinyl)benzeneacetic acid
  • 2-(4-(1-oxoisoindolin-2-yl)phenyl)propanoic acid
  • (+/-) Indoprof
  • 1-Oxo-2-[p-[(α-Methyl)carboxyMethyl]phenyl]isoindoline
  • Benzeneacetic acid, 4-(1,3-dihydro-1-oxo-2H-isoindol-2-yl)-α-methyl-
  • inhibit,Indoprofen,Inhibitor
  • Indoprofen Indoprofen
  • 31842-01-0
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