ChemicalBook > CAS DataBase List > 2,4-Difluoro-3-iodoaniline

2,4-Difluoro-3-iodoaniline

Product Name
2,4-Difluoro-3-iodoaniline
CAS No.
1437316-91-0
Chemical Name
2,4-Difluoro-3-iodoaniline
Synonyms
HE-CHEMICAL 0400806;2,4-Difluoro-3-iodoaniline;2, 6-dichloro-3-bromoaniline;Benzenamine, 2,4-difluoro-3-iodo-;2,4-difluoro-3-iodoaniline - [AC77843]
CBNumber
CB43367577
Molecular Formula
C6H4F2IN
Formula Weight
255
MOL File
1437316-91-0.mol
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2,4-Difluoro-3-iodoaniline Property

Boiling point:
266.7±40.0 °C(Predicted)
Density 
2.086±0.06 g/cm3(Predicted)
storage temp. 
2-8°C, protect from light
pka
2.30±0.10(Predicted)
Appearance
Off-white to light brown Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
D451708
Product name
2,​4-​Difluoro-​3-​iodoaniline
Packaging
1g
Price
$340
Updated
2021/12/16
AK Scientific
Product number
1804EB
Product name
2,4-Difluoro-3-iodoaniline
Packaging
1g
Price
$870
Updated
2021/12/16
Ark Pharm
Product number
AK362272
Product name
2,4-Difluoro-3-iodoaniline
Purity
97%
Packaging
1g
Price
$91
Updated
2021/12/16
Ambeed
Product number
A337360
Product name
2,4-Difluoro-3-iodoaniline
Purity
97%
Packaging
5g
Price
$273
Updated
2021/12/16
Ambeed
Product number
A337360
Product name
2,4-Difluoro-3-iodoaniline
Purity
97%
Packaging
250mg
Price
$35
Updated
2021/12/16
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2,4-Difluoro-3-iodoaniline Chemical Properties,Usage,Production

Uses

2,?4-?Difluoro-?3-?iodoaniline is used in the synthetic preparation of purine derivatives that are protein kinase modulators useful in treatment and prevention of protein kinase-mediated diseases.

Synthesis

1145881-54-4

1437316-91-0

General procedure for the synthesis of 2,4-difluoro-3-iodoaniline from 1,3-difluoro-2-iodo-4-nitrobenzene: To a solution of concentrated hydrochloric acid (4 mL) of 1,3-difluoro-2-iodo-4-nitrobenzene (1.14 g, 4 mmol) was added anhydrous stannous chloride (2.71 g, 12 mmol), and the reaction mixture was heated to 50°C and kept for 1 hour. After completion of the reaction, the mixture was diluted with water, neutralized with 5% aqueous sodium hydroxide solution to pH=9, and then extracted with dichloromethane. The organic phase was washed with saturated saline, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford the target product 2,4-difluoro-3-iodoaniline (0.93 g, 91% yield).1H NMR (CDCl3): δ 6.70-6.93 (2H, m), 6.65 (2H, br).

References

[1] Patent: WO2013/71865, 2013, A1. Location in patent: Page/Page column 57
[2] Patent: CN103102349, 2017, B. Location in patent: Paragraph 0501-0503

2,4-Difluoro-3-iodoaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4-Difluoro-3-iodoaniline Suppliers

BTC pharm India
Tel
+918790379245
Email
banny.janga@btcpharm.com
Country
India
ProdList
1262
Advantage
58

1437316-91-0, 2,4-Difluoro-3-iodoanilineRelated Search:


  • 2,4-Difluoro-3-iodoaniline
  • Benzenamine, 2,4-difluoro-3-iodo-
  • HE-CHEMICAL 0400806
  • 2,4-difluoro-3-iodoaniline - [AC77843]
  • 2, 6-dichloro-3-bromoaniline
  • 1437316-91-0