BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID

Product Name: BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID
CAS No.: 151215-34-8
Chemical Name: BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID
Synonyms: Boc-(S)-(2-bromoallyl)glycine;(S)-N-BOC-(2-BROMOALLYL)-GLYCINE;BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID;(S)-2-(Boc-amino)-4-bromo-4-pentenoic acid;BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID USP/EP/BP;(Tert-Butoxy)Carbonyl L-2-Amino-4-bromo-4-pentenoic acid;(S)-2-[(t-Butoxycarbonyl)amino]-4-bromo-4-pentenoic acid;(S)-4-BroMo-2-((tert-butoxycarbonyl)aMino)pent-4-enoic acid;(2S)-4-bromo-2-{[(tert-butoxy)carbonyl]amino}pent-4-enoic acid;Boc-L-2-amino-4-bromo-4-pentenoic acid≥ 99% (HPLC, Chiral purity)
CBNumber: CB4354811
Molecular Formula: C10H16BrNO4
Formula Weight: 294.14
MOL File: 151215-34-8.mol

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BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID Property

Boiling point:: 396.7±42.0 °C(Predicted)
Density: 1.407±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 3.81±0.10(Predicted)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P330Rinse mouth.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: B603085
Product name: Boc-L-2-amino-4-bromo-4-pentenoicAcid
Packaging: 50mg
Price: $85
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB50628
Product name: Boc-L-2-amino-4-bromo-4-pentenoic acid
Packaging: 100mg
Price: $100
Updated: 2021/12/16

AK Scientific

Product number: 7583AA
Product name: (S)-4-Bromo-2-((tert-butoxycarbonyl)amino)pent-4-enoicacid
Packaging: 100mg
Price: $110
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB50628
Product name: Boc-L-2-amino-4-bromo-4-pentenoic acid
Packaging: 250mg
Price: $150
Updated: 2021/12/16

Activate Scientific

Product number: AS113472
Product name: (S)-4-Bromo-2-((tert-butoxycarbonyl)amino)pent-4-enoic acid
Purity: 98+% ee
Packaging: 250mg
Price: $176
Updated: 2021/12/16

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BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Synthesis

24424-99-5

151144-96-6

151215-34-8

4.3: After completion of the separation, the reaction mixture was extracted with ethyl acetate to remove the D-isomer to give L-2-amino-4-bromo-4-pentenoic acid. Subsequently, an aqueous solution of 5 L of acetone and 120 g of di-tert-butyl dicarbonate was added to the reaction system and the alkaline environment of the aqueous sodium carbonate solution was maintained. After the reaction was carried out for 5 hours, the reaction mixture was acidified with 3M hydrochloric acid and the product was extracted with ethyl acetate. The organic phase was dried and purified by crystallization to give 64 g of (S)-4-bromo-2-((tert-butoxycarbonyl)amino)pent-4-enoic acid as a solid. The purity of the product was 98.84% and the overall yield was 43.5% by HPLC analysis.

References

[1] Patent: CN107827767, 2018, A. Location in patent: Paragraph 0030; 0036
[2] Tetrahedron Letters, 1993, vol. 34, # 28, p. 4485 - 4488

BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID Suppliers

China 29 India 1 United Kingdom 2 United States 10 Global 42

Suzhou haiyu Biochem Industrial Co., LTD

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Shanghai GL Peptide Ltd.

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Amatek Scientific Co. Ltd.

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Aikon International Limited

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Shanghai Jizhi Biochemical Technology Co. Ltd.

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Kanghua (Shanghai) New Drug Development Co., Ltd.

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151215-34-8, BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACIDRelated Search:

L-2-AMINO-4-BROMO-4-PENTENOIC ACID 2-AMINO-4-BROMOBUTANOIC ACID 4-Bromobutyric acid L-Allylglycine BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID 2-(Tert-Butoxycarbonylamino)Pent-4-Enoic Acid 4-BROMO-PENT-4-ENAL tert-Butyl 3-bromopropylcarbamate (S)-2-AMINO-4-BROMOBUTANOIC ACID Boc-L-2-allylglycine dicyclohexylamine salt BOC-2-AMINO-4-BROMOBUTANOIC ACID

(S)-N-BOC-(2-BROMOALLYL)-GLYCINE

BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID

(2S)-4-bromo-2-{[(tert-butoxy)carbonyl]amino}pent-4-enoic acid

(2S)-4-bromo-2-[(2-methylpropan-2-yl)oxycarbonylamino]pent-4-enoic acid

(S)-4-BroMo-2-((tert-butoxycarbonyl)aMino)pent-4-enoic acid

Boc-(S)-(2-bromoallyl)glycine

Boc-L-2-amino-4-bromo-4-pentenoic acid≥ 99% (HPLC, Chiral purity)

(Tert-Butoxy)Carbonyl L-2-Amino-4-bromo-4-pentenoic acid

4-Pentenoic acid, 4-bromo-2-[[(1,1-dimethylethoxy)carbonyl]amino]-, (2S)-

(2S)-4-bromo-2-[(2-methylpropan-2-yl)oxycarbonylamino]pent-4-enoicaci

BOC-L-2-AMINO-4-BROMO-4-PENTENOIC ACID USP/EP/BP

(S)-2-[(t-Butoxycarbonyl)amino]-4-bromo-4-pentenoic acid

(S)-2-(Boc-amino)-4-bromo-4-pentenoic acid

151215-34-8

Unusual amino acids