CHLOZOLINATE
- Product Name
- CHLOZOLINATE
- CAS No.
- 84332-86-5
- Chemical Name
- CHLOZOLINATE
- Synonyms
- SERINAL;Manderol;SDS 65311;Clozolinate;CHLOZOLINATE;Chlozolinate 1;Einecs 282-714-4;Chlozolinate [iso];Chlozolinate Standard;chlozolinate (bsi,iso)
- CBNumber
- CB4358743
- Molecular Formula
- C13H11Cl2NO5
- Formula Weight
- 332.14
- MOL File
- 84332-86-5.mol
CHLOZOLINATE Property
- Melting point:
- 110-114 °C
- Boiling point:
- 420.8±55.0 °C(Predicted)
- Density
- 1.479
- vapor pressure
- 1.3 x 10-5 Pa (25 °C)
- Flash point:
- 100 °C
- storage temp.
- 0-6°C
- pka
- -4.24±0.40(Predicted)
- Water Solubility
- 2 mg l-1 (25 °C)
Safety
- Hazard Codes
- Xn,N,F
- Risk Statements
- 40-51/53-67-65-50/53-38-11-20
- Safety Statements
- 36/37-61-62-60-33-25-16-9
- RIDADR
- UN3077 9/PG 3
- WGK Germany
- 2
- HS Code
- 29251900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H304May be fatal if swallowed and enters airways
H315Causes skin irritation
H336May cause drowsiness or dizziness
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331Do NOT induce vomiting.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 33743
- Product name
- Chlozolinate solution
- Purity
- 100μg/mL in cyclohexane, PESTANAL
- Packaging
- 2ml
- Price
- $74.5
- Updated
- 2022/05/15
- Product number
- C989138
- Product name
- Chlozolinate
- Packaging
- 25mg
- Price
- $880
- Updated
- 2021/12/16
- Product number
- C989138
- Product name
- Chlozolinate
- Packaging
- 50mg
- Price
- $1680
- Updated
- 2021/12/16
- Product number
- PST0000442
- Product name
- CHLOZOLINATE
- Purity
- 98.00%
- Packaging
- 10MG
- Price
- $924
- Updated
- 2021/12/16
- Product number
- CD11048026
- Product name
- Ethyl3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxooxazolidine-5-carboxylate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $972
- Updated
- 2021/12/16
CHLOZOLINATE Chemical Properties,Usage,Production
Uses
Chlozolinate controls fruit rot, downy mildew and brown rot in pome and stone fruits, vines, vegetables, strawberries and ornamentals caused by Botrytis, Monilia and Sclerotinia, efc.
Uses
Chlozolinate is a dicarboximide fungicide which is used primarily on grapes.
Definition
ChEBI: Ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate is the ethyl ester of 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylic acid. It is a dichlorobenzene, an oxazolidinone, a dicarboximide and an ethyl ester.
General Description
Chlozolinate is a systemic fungicide, used for the control of downy mildew, brown rot, and fruit rot in agricultural commodities.
Metabolic pathway
The fungicides, chlozolinate, vinclozolin, and procymidone, are added to wine after fermentation and the degradation products are isolated and identified. Chlozolinate undergoes a rapid hydrolytic loss of the ethoxycarbonyl substituent to give an oxazolidine that further undergoes hydrolytic cleavage to give 3' ,5' -dichloro-2-hydroxypropanilide. The oxazolidine ring of vinclozolin undergoes a similar hydrolysis reaction to give the corresponding anilide, 3' ,5'-dichloro-2-hydroxy-2-methylbut-3-eneanilide. Both of these anilides are stable in wine for 150 days. A different degradation behavior is observed with procymidone and leads to the formation of 3,5- dichloroaniline, which, in turn, breaks down in wine.
Degradation
Chlozolinate (1) hydrolysed rapidly at 25 °C in alkaline solution with DTm
values of 6 hours (pH 6.8) and 16 min (pH 8.3). Three hydrolytic degradation
reactions were observed. The first reaction involved the cleavage of
the ethyl ester to yield the corresponding carboxylic acid (2). Compound
2 underwent decarboxylation to yield 3-(3,5-dichlorophenyl)-5-methyloxazolidine-
2,4-dione (3). The third reaction involved the opening of the
oxazolidinedione ring to yield 3',5'-dichloro-2-hydroxypropanilide(4)
(Villedieu et al., 1994,1995).
Chlozolinate degraded rapidly in wine during the vinification process
(DT50 0.35 and 0.14 day at pH 3 and 4, respectively). Decarboxylation
resulted in the formation of compound 3 as the major product (Cabras et
al., 1984; Pirisi et al., 1986; Gennari et al., 1992).
CHLOZOLINATE Preparation Products And Raw materials
Raw materials
Preparation Products
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