2-Benzyloxybenzaldehyde
- Product Name
- 2-Benzyloxybenzaldehyde
- CAS No.
- 5896-17-3
- Chemical Name
- 2-Benzyloxybenzaldehyde
- Synonyms
- CCY1a;AKOS AU36-M26;ASISCHEM N43068;2-Benzyloxybenzaldeh;OTAVA-BB BB7018801948;2-BENZYLOXYBENZALDEHYDE;2-BENZYLOXY BEZALDEHYDE;O-(BENZYLOXY)BENZALDEHYDE;2- Benxyloxy benzaldehyde;2-Benzyloxybenzaldehyde,98%
- CBNumber
- CB4363211
- Molecular Formula
- C14H12O2
- Formula Weight
- 212.24
- MOL File
- 5896-17-3.mol
2-Benzyloxybenzaldehyde Property
- Melting point:
- 46-47°C
- Boiling point:
- 326 °C (lit.)
- Density
- 1.339 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.6(lit.)
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Chloroform, Methanol (Slightly)
- form
- Liquid
- Specific Gravity
- 1.339
- color
- Colorless to yellow
- Water Solubility
- Insoluble in water.
- Sensitive
- Air Sensitive
- BRN
- 780307
- InChI
- InChI=1S/C14H12O2/c15-10-13-8-4-5-9-14(13)16-11-12-6-2-1-3-7-12/h1-10H,11H2
- InChIKey
- PBEJTRAJWCNHRS-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC=CC=C1OCC1=CC=CC=C1
- CAS DataBase Reference
- 5896-17-3(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 499749
- Product name
- 2-Benzyloxybenzaldehyde
- Purity
- 98%
- Packaging
- 10ml
- Price
- $55.4
- Updated
- 2023/06/20
- Product number
- 499749
- Product name
- 2-Benzyloxybenzaldehyde
- Purity
- 98%
- Packaging
- 50ml
- Price
- $176
- Updated
- 2022/05/15
- Product number
- B1653
- Product name
- 2-Benzyloxybenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $25
- Updated
- 2025/07/31
- Product number
- B1653
- Product name
- 2-Benzyloxybenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $69
- Updated
- 2025/07/31
- Product number
- B411008
- Product name
- 2-(Benzyloxy)benzaldehyde
- Packaging
- 5g
- Price
- $70
- Updated
- 2021/12/16
2-Benzyloxybenzaldehyde Chemical Properties,Usage,Production
Chemical Properties
Clear pale yellow liquid
Uses
2-Benzyloxybenzaldehyde is used as an organic chemical synthesis intermediate.
Uses
2-Benzyloxybenzaldehyde may be used in the synthesis of:
- 2-benzyloxy-2′-hydroxy-3′,4′,6′-trimethoxychalcone
- N2-(2-benzyloxy)benzylidenyl isonicotinic acid hydrazide
- 2-hydroxy-2′-methoxybenzophenone
- 2′-hydroxy-5,6,7-trimethoxyflavone
General Description
2-Benzyloxybenzaldehyde is a benzaldehyde derivative. It undergoes enantioselective cyanoformylation with ethyl cyanoformate in the presence of a vanadium(V) chiral salen complex and imidazole to form the corresponding cyanohydrin carbonate.
Synthesis
100-44-7
90-02-8
5896-17-3
(Preparation of 2-benzyloxybenzaldehyde) 185 g of N,N-dimethylformamide (DMF) and 82.8 g (0.6 mol) of anhydrous potassium carbonate were added to a three-necked flask, and 61 g (0.5 mol) of salicylaldehyde was added slowly dropwise under stirring. Subsequently, the reaction system was warmed up to 50 °C, and 75.9 g (0.6 mol) of benzyl chloride was slowly added dropwise at this temperature for a controlled dropwise time of 1 hour. After the dropwise addition was completed, the reaction mixture was warmed up to 70 °C and the reaction was continued with stirring for 2 hours. Upon completion of the reaction, the mixture was transferred to a partition funnel and washed sequentially with 185 g of toluene and 330 g of water. The organic phases were combined and the solvent was removed by distillation under reduced pressure (internal temperature 90 °C, pressure 10 mmHg) to give 104.5 g of the brown liquid product 2-benzyloxybenzaldehyde, which was analyzed to have a purity of 97.9% and a yield of 96.5%.
References
[1] Organic and Biomolecular Chemistry, 2016, vol. 14, # 9, p. 2625 - 2636
[2] Patent: US6603029, 2003, B1
[3] Organic and Biomolecular Chemistry, 2017, vol. 15, # 17, p. 3648 - 3661
[4] Patent: CN108822095, 2018, A. Location in patent: Paragraph 0121; 0122; 0123
[5] Tetrahedron, 2015, vol. 71, # 33, p. 5217 - 5228
2-Benzyloxybenzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
2-Benzyloxybenzaldehyde Suppliers
- Tel
- 0519-82698292
- info@hhbhswkj.com
- Country
- China
- ProdList
- 133
- Advantage
- 58
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006356688 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 847-367-3680
- Fax
- 847-367-3681
- sales@arkpharminc.com
- Country
- United States
- ProdList
- 1670
- Advantage
- 56
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9310
- Advantage
- 66
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11035
- Advantage
- 64
View Lastest Price from 2-Benzyloxybenzaldehyde manufacturers
- Product
- 2-Benzyloxybenzaldehyde 5896-17-3
- Price
- US $0.00-0.00/g
- Min. Order
- 10mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-15
- Product
- 2-Benzyloxybenzaldehyde 5896-17-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 200kg
- Release date
- 2019-08-29