(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE

Reaction

Product Name: (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE
CAS No.: 142184-30-3
Chemical Name: (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE
Synonyms: (S,S)-ET-DUPHOS-RH;[((SS)-Et-DuPhos)Rh(COD)]OTf;(+)-1,2-Bis((2S,5S)-2,5-diethyL;(+)-1,2-Bis((2S,5S)-diethylphospholano)benzene(cyclooctadien...;(+)-1,2-Bis((2S,5S)-diethylphospholano)benzene(cyclooctadiene)rhodium(I) triflate;(+)-1,2-Bis[(2S,5S)-diethylphospholano)benzene(cyclooctadiene]rhodium(I) triflate,98%;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfona;(+)-1,2-BIS(2S,5S)-2,5-(DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANSULFONATE;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate;1，2-Bis[(2S，5S)-2，5-diethylphospholano]benzene(1，5-cyclooctadiene)rhodium(I) trifluoromethanesulfonat
CBNumber: CB4372136
Molecular Formula: C31H48F3O3P2RhS
Formula Weight: 722.62
MOL File: 142184-30-3.mol

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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Property

storage temp.: Inert atmosphere,2-8°C
form: crystal
color: orange
Sensitive: Air & Moisture Sensitive

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 24/25-26
WGK Germany: 3
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 698407
Product name: 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging: 50mg
Price: $122
Updated: 2023/01/07

Sigma-Aldrich

Product number: 698407
Product name: 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging: 250mg
Price: $432
Updated: 2023/01/07

Strem Chemicals

Product number: 45-0151
Product name: (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (S,S)-Et-DUPHOS-Rh
Packaging: 100mg
Price: $131
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0151
Product name: (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (S,S)-Et-DUPHOS-Rh
Packaging: 500mg
Price: $558
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0151
Product name: (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (S,S)-Et-DUPHOS-Rh
Packaging: 2g
Price: $1811
Updated: 2024/03/01

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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production

Reaction

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Forms superior catalysts for asymmetric reductive aminations.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
Palladium catalyzed asymmetric phosphination.

Chemical Properties

orange to red-orange crystals

Uses

(S,S)-Et-DUPHOS-Rh may be used as an efficient catalyst in the synthesis of (S)-2-quinolylalanine via asymmetric hydrogenation.

General Description

1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is an electron-rich C₂ symmetric bis(phospholane) ligand for enantioselective catalytic reactions.

(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE Suppliers

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View Lastest Price from (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE manufacturers

Career Henan Chemical Co

Product: 2-amino-5-bromo-4-methylpridine 142184-30-3
Price: US $9.80/KG
Min. Order: 1g
Purity: ＞98%
Supply Ability: 20 tons
Release date: 2020-02-10

142184-30-3, (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATERelated Search:

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Benzene Rhodium ETHYLPHOSPHONIC ACID (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE 1,3-CYCLOOCTADIENE Trifluoromethanesulfonic acid (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

(+)-1,2-Bis[(2S,5S)-diethylphospholano)benzene(cyclooctadiene]rhodium(I) triflate,98%

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (S,S)-Et-DUPHOS-Rh

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate (S,S)-Et-DUPHOS-Rh

(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE,98+%(S,S)-ET-DUPHOS-RH

(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE

(+)-1,2-BIS(2S,5S)-2,5-(DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANSULFONATE

(S,S)-ET-DUPHOS-RH

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)trifluoromethanesulfonate,98+%(S,S)-Et-DUPHOS-Rh

1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfona

(+)-1,2-Bis((2S,5S)-2,5-diethyL

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

(+)-1,2-Bis((2S,5S)-diethylphospholano)benzene(cyclooctadien...

[((SS)-Et-DuPhos)Rh(COD)]OTf

(+)-1,2-Bis((2S,5S)-diethylphospholano)benzene(cyclooctadiene)rhodium(I) triflate

1，2-Bis[(2S，5S)-2，5-diethylphospholano]benzene(1，5-cyclooctadiene)rhodium(I) trifluoromethanesulfonat

Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2S,2′S,5S,5′S)-1,1′-(1,2-phenylene)bis[2,5-diethylphospholane-κP]]-, salt with trifluoromethanesulfonic acid (1:1)

1,2-Bis[(2<i>S</i>,5<i>S</i>)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

(+)-1,2-BIS((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium (I) trifluoromethanesulfonate

142184-30-3

C31H48P2F3O3Rh

RhC8H12C22H36P2CF3SO3

organometallic complex